Citation: SUN Zhi-Kang, LEI Han-Min, WEN Wu-Qiang, DU Zhi-Ping. Syntheses, Crystal Structures and Properties of Copper(Ⅰ) and Copper(Ⅱ) Complexes with 2,9-Dimethyl-1,10-phenanthroline[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(1): 149-155. doi: 10.11862/CJIC.2017.008 shu

Syntheses, Crystal Structures and Properties of Copper(Ⅰ) and Copper(Ⅱ) Complexes with 2,9-Dimethyl-1,10-phenanthroline

Hubei Key Laboratory of Novel Reactor & Green Chemical Technology, Key Laboratory for Green Chemical Process of Ministry of Education, Wuhan Institute of Technology, Wuhan 430073, China

Corresponding author: DU Zhi-Ping, dzpxyhry@163.com
Received Date: 20 July 2016
Revised Date: 14 November 2016

Figures(6)

Two novel complexes,[Cu(Ⅰ)(dmphen)(SCN)]_n (1) and [Cu(Ⅱ)(dmphen)(DMF)(NCS)₂] (2) (dmphen=2,9-dimethyl-1,10-phenanthroline, DMF=N,N-dimethylformamide), have been obtained by the precipitation reaction and DMF recrystallization with cupric chloride dihydrate, dmphen and ammonium thiocyanate as reactants, and characterized by elemental analysis, FTIR, UV-Vis and single crystal X-ray diffraction analysis. Their thermal stabilities and fluorescence properties have also been investigated. The results show that 1 belongs to monoclinic system, space group P2₁/n with a=1.211 1(4) nm, b=0.826 2(2) nm, c=1.367 5(4) nm, β=96.502(5)°, V=1.359 5(7) nm³, and Z=4. 1 features one-dimensional zigzag chains with Cu atoms bridged by thiocyanate groups. 2 crystallizes in the triclinic system, space group P1 with a=0.943 6(2) nm, b=1.010 9(2) nm, c=1.219 0(3) nm, α=95.628(4)°, β=103.114(4)°, γ=107.087(4)°, V=1.065 4(4) nm³, and Z=2; the three-dimensional supramolecular framework of 2 is constructed by C-H…S hydrogen bonds and π-π stacking interactions. TG and fluorescence analysis show the thermal stability of 1 is higher than of 2, and 1 has the maximum emission band of the fluorescence at 603 nm. CCDC:1063354, 1; 1448398, 2.
- 2,9-dimethyl-1,10-phenanthroline,
- fluorescence,
- crystal structure,
- π-π interactions
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