Citation: HUANG Miao-Ling, WU Wen-Shi, CHEN Wan-Zhen. Syntheses, Crystal Structures and Fluorescent Properties of One-Dimensional Coordination Polymers with N-p-Tolylsulfonyl-5-aminoisophthalic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2017, 33(1): 66-72. doi: 10.11862/CJIC.2017.005 shu

Syntheses, Crystal Structures and Fluorescent Properties of One-Dimensional Coordination Polymers with N-p-Tolylsulfonyl-5-aminoisophthalic Acid

1.
College of Materials Science and Engineering, Huaqiao University, Xiamen, Fujian 361000, China
2.
College of Chemical Engineering and Materials, Quanzhou Normal University, Quanzhou, Fujian 362000, China

Corresponding author: WU Wen-Shi, wws@hqu.edu.cn
Received Date: 8 July 2016
Revised Date: 2 November 2016

Figures(5)

Two metal-organic coordination polymers, {[Cu(Ts-5-AIPA)(phen)(H₂O)]·H₂O}_n (1) and [Cd(Ts-5-AIPA)(phen)]_n (2) (Ts-5-AIPA=N-p-tolylsulfonyl-5-aminoisophthalic acid radical, phen=phenanthroline), were synthesized using common solution method and hydrothermally method, respectively. Their crystal structures were determined by IR, TG and single-crystal X-ray diffraction. Two complexes crystalize in monoclinic system, space group P2₁/c for complex 1 and C2/c for complex 2. They are one-dimensional chain structure, and further extended into a three-dimensional supramolecular structure through hydrogen bonds and π-π interactions. In addition, fluorescent properties of two complexes were investigated. CCDC:839135, 1; 1472441, 2.
- coordination polymer,
- N-p-tolylsulfonyl-5-aminoisophthalic acid,
- crystal structure,
- fluorescent
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沈阳化工大学材料科学与工程学院沈阳 110142