Citation: WANG Zan, MI Xiao-Yun, XIE Ling-Jie, PAN Xiao-Ying, ZHOU Hong-Yan, CHEN Shu-Yi, ZHANG Xi-Yan, BAI Zhao-Hui. Preparation and Luminescent Properties of Ca₉Y(PO₄)₇: Ce³⁺,Tb³⁺ Nano-phosphors[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(12): 2136-2142. doi: 10.11862/CJIC.2016.284 shu

Preparation and Luminescent Properties of Ca₉Y(PO₄)₇: Ce³⁺,Tb³⁺ Nano-phosphors

1.
School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022, China

Corresponding author: MI Xiao-Yun,
Received Date: 7 July 2016
Available Online: 2 November 2016
Fund Project:

Ca₉Y(PO₄)₇:Ce³⁺,Tb³⁺ nano-phosphors were synthesized by hydrothermal method. X-ray diffraction (XRD), Scanning electron microscope (SEM) and Photoluminescence (PL) spectra and so on were used to characterize the samples. The effects of Ce³⁺ and Tb³⁺ on the luminescence properties of Ca₉Y(PO₄)₇:Ce³⁺,Tb³⁺ was studied in detail. The result indicates that the luminescence color of Ca₉Y(PO₄)₇:Tb³⁺ can be tuned through adjusting the concentration of Tb³⁺, which is attributed to the energy cross relaxation of Tb³⁺. And the energy transfer mechanism of Ce³⁺-Tb³⁺ was dipole-quadrupole mechanism of electric multipole interactional, the biggest energy transfer efficiency was 55.6%. The emission color of Ca₉Y(PO₄)₇:Ce³⁺,Tb³⁺ can be tuned by the energy transfer of ions and the total emission of activators. SEM showed that the samples had good dispersion, and the particle size of phosphors was about 100 nm.
- Ca₉Y(PO₄)₇:Ce³⁺,Tb³⁺;hydrothermal method;cross relaxation;energy transfer
1. [1]
  [1] Zhang Y, Geng D L, Kang X J, et al. Inorg. Chem., 2013,52:12986-12994
2. [2]
  [2] Wang T, Hu Y H, Chen L, et al. Appl. Phys. A, 2015,120(1):301-308
3. [3]
  [3] Xu M J, Wang L X, Jia D Z, et al. J. Chem. Phys, 2015,17:28802-28808
4. [4]
  [4] Mi X Y, Shi H, Wang Z, et al. J. Mater. Sci, 2016,51:3545-3554
5. [5]
  [5] Bao A, Yang H, Tao C Y. Curr. Appl. Phys., 2009,9:1252-1256
6. [6]
  [6] Wen D W, Dong Z Y, Shi J S, et al. ECS J. Solid State Sci. Technol., 2013,2(9):R178-R185
7. [7]
  [7] Zhang J, Wang Y H, Huang Y. Opt. Mater., 2011,33:1325-1330
8. [8]
  [8] Wen F S, Chen J S, Moon J H, et al. J. Solid State Chem., 2004,177:3114-3118
9. [9]
  [9] Huang C H, Kuo T W, Chen T M, et al. ACS Appl. Mater. Interfaces, 2010,2(5):1395-1399
10. [10]
  [10] Blasse G, Bril A. Philips Res. Rep., 1967,22:481-504
11. [11]
  [11] Sohn K, Choi Y, Park H, et al. J. Electrochem. Soc., 2000, 147:2375-2379
12. [12]
  [12] Reisfeld R, Greenber E, Velapold R, et al. J. Chem. Phys., 1972,56:1698-1705
13. [13]
  [13] WU Jiang(吴疆), ZHANG Ping(张萍), JIANG Chun-Dong(蒋春东). Chinese J. Inorg. Chem.(无机化学学报), 2015,31(6):1201-1206
14. [14]
  [14] Liu X, Lin J. J. Mater. Chem., 2008,18:221-228
15. [15]
  [15] Xue Y, Xiao F, Zhang Q. Spectrochim. Acta, Part A, 2011, 78:1445-1448
16. [16]
  [16] LUO Yi(罗懿), XIA Zhi-Guo(夏志国). Chinese J. Inorg. Chem.(无机化学学报), 2013,29(4):665-670
17. [17]
  [17] Van U. J. Lumines, 1984,29:1-9
18. [18]
  [18] Zhao C, Yin X, Wang Y, et al. J. Lumin., 2012,132(3):617-621
19. [19]
  [19] Mi X Y, Sun J C, Zhou P, et al. J. Mater. Chem., 2015,3(17):4471-4481
20. [20]
  [20] Li G G, Geng D L, Shang M M, et al. J. Phys. Chem. C, 2011,115:21882-21892
21. [21]
  [21] Li K, Zhang Y, Li X, et al. Dalton Trans, 2015,44(10):4683-4692
22. [22]
  [22] Paulose P I, Jose G, Thomas V, et al. J. Phys. Chem. Solids, 2003,64(5):841-846
23. [23]
  [23] Dexter D L, Schulman J H. J. Chem. Phys., 1954,22(6):1063-1070
24. [24]
  [24] Blasse G. Philips Res. Rep., 1969,24:131-144
25. [25]
  [25] Liu C C, Liu R S, Tang Y S, et al. J. Electronchem. Soc., 2008,155(9):248-251
26. [26]
  [26] Kuo T W, Chen T M. J. Electronchem. Soc., 2010,157(6):216-220
27. [27]
  [27] Shi S K, Li J L, Zhang X J, et al. J. Lumin., 2016,180:214-218
1. [1]
  Shuting Zhuang , Lida Zhao . Teaching through Research: A Comprehensive Experiment on Carbon Quantum Dots from Microplastic Waste. University Chemistry, 2025, 40(10): 217-224. doi: 10.12461/PKU.DXHX202412010
2. [2]
  Haoying ZHAI , Lanzong WEN , Wenjie LIAO , Qin LI , Wenjun ZHOU , Kun CAO . Metal-organic framework-derived sulfur-doped iron-cobalt tannate nanorods for efficient oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 1037-1048. doi: 10.11862/CJIC.20240320
3. [3]
  Huiying ZHANG , Ping LI , Weixia DONG , Zhiwen HU , Qifu BAO , Qizheng DONG , Mingmin BAI , Wenqi LI . Photocatalytic performance of spheroidal nano Bi₄Ti₃O₁₂ prepared by surfactant-assisted hydrothermal reaction. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 551-561. doi: 10.11862/CJIC.20250269
4. [4]
  Min Hu , Yinghuan Li , Yanhong Bai , Yanping Ren , Juanjuan Song , Yongxian Fan , Dongcheng Liu , Xiuqiong Zeng , Faqiong Zhao , Wenwei Zhang , Mei Shi , Wan Li , Xiuyun Wang , Weihong Li , Xiaohang Qiu , Yong Fan , Jianrong Zhang , Shuyong Zhang . Suggestions on the Method of Hydrothermal-Solventthermal Synthesis and Their Operation Standards. University Chemistry, 2026, 41(3): 208-215. doi: 10.12461/PKU.DXHX202507034
5. [5]
  Gregorio F. Ortiz . Some facets of the Mg/Na₃VCr_0.5Fe_0.5(PO₄)₃ battery. Chinese Chemical Letters, 2024, 35(10): 109391-. doi: 10.1016/j.cclet.2023.109391
6. [6]
  Zheng Li , Fangkun Li , Xijun Xu , Jun Zeng , Hangyu Zhang , Lei Xi , Yiwen Wu , Linwei Zhao , Jiahe Chen , Jun Liu , Yanping Huo , Shaomin Ji . A scalable approach to Na₄Fe₃(PO₄)₂P₂O₇@carbon/expanded graphite as cathode for ultralong-lifespan and low-temperature sodium-ion batteries. Chinese Chemical Letters, 2025, 36(10): 110390-. doi: 10.1016/j.cclet.2024.110390
7. [7]
  Ruofan Yin , Zhaoxin Guo , Rui Liu , Xian-Sen Tao . Ultrafast synthesis of Na₃V₂(PO₄)₃ cathode for high performance sodium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109643-. doi: 10.1016/j.cclet.2024.109643
8. [8]
  Tong Su , Yue Wang , Qizhen Zhu , Mengyao Xu , Ning Qiao , Bin Xu . Multiple conductive network for KTi₂(PO₄)₃ anode based on MXene as a binder for high-performance potassium storage. Chinese Chemical Letters, 2024, 35(8): 109191-. doi: 10.1016/j.cclet.2023.109191
9. [9]
  Débora Ferreira dos Santos Morais , José Luis Tirado , Carlos Pérez-Vicente , Fabiana Villela da Motta , Pedro Lavela , Mauricio Bomio , Sergio Lavela . Unlocking the performance of sodium-ion batteries by coating Na₃V₂(PO₄)₃ with Nb₂O₅. Acta Physico-Chimica Sinica, 2026, 42(2): 100180-0. doi: 10.1016/j.actphy.2025.100180
10. [10]
  Xingyuan Lu , Yutao Yao , Junjing Gu , Peifeng Su . Energy Decomposition Analysis and Its Application in the Many-Body Effect of Water Clusters. University Chemistry, 2025, 40(3): 100-107. doi: 10.12461/PKU.DXHX202405074
11. [11]
  Xiaodong Wang , Miaomiao Zhou , Yirui Deng , Zijun Liu , Huiyou Dong , Peng Yan , Ruiping Liu . Dual functional Ti₃(PO₄)₄-coated NCM811 cathode enables highly stable sulfide-based all-solid-state lithium batteries. Chinese Chemical Letters, 2025, 36(9): 110307-. doi: 10.1016/j.cclet.2024.110307
12. [12]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5−xMn_0.5V_1.5−xZr_x (PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-0. doi: 10.3866/PKU.WHXB202407023
13. [13]
  Piao Tang , Xin Wen , Jindong Chen , Ning Ye , Guang Peng . Ag(Te2O3)(PO4): The first Ag-containing phosphate-tellurite non-linear optical crystal featuring novel zigzag layered structure. Chinese Journal of Structural Chemistry, 2026, 45(1): 100763-100763. doi: 10.1016/j.cjsc.2025.100763
14. [14]
  Qiang Zhou , Pingping Zhu , Wei Shao , Wanqun Hu , Xuan Lei , Haiyang Yang . Innovative Experimental Teaching Design for 3D Printing High-Strength Hydrogel Experiments. University Chemistry, 2024, 39(6): 264-270. doi: 10.3866/PKU.DXHX202310064
15. [15]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
16. [16]
  Mengxiu Li , Jiahui Mao , Jiangfeng Ni , Liang Li . Three birds with one stone: modification of Li₅FeO₄ with thermal induction of Lewis acid. Acta Physico-Chimica Sinica, 2026, 42(4): 100189-0. doi: 10.1016/j.actphy.2025.100189
17. [17]
  Tong WANG , Xuefang ZHU , Qi GAO , Hongbo ZHANG , Chao REN , Lixia GE . Luminescence and thermal stability of Tb³⁺-Eu³⁺ doped glass-ceramics containing Na_8.12Y_1.293Si₆O₁₈ crystal phase. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2237-2250. doi: 10.11862/CJIC.20250137
18. [18]
  Fan Liu , Pifu Gong , Zheshuai Lin , Lei Kang . REXCO3 (RE = La, Ce, Y; X = OH, F) with circular alignment of anionic motifs induced extraordinary nonlinear optical effects. Chinese Journal of Structural Chemistry, 2026, 45(3): 100844-100844. doi: 10.1016/j.cjsc.2025.100844
19. [19]
  Tao Long , Peng Chen , Bin Feng , Caili Yang , Kairong Wang , Yulei Wang , Can Chen , Yaping Wang , Ruotong Li , Meng Wu , Minhuan Lan , Wei Kong Pang , Jian-Fang Wu , Yuan-Li Ding . Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode. Chinese Chemical Letters, 2024, 35(4): 109267-. doi: 10.1016/j.cclet.2023.109267
20. [20]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(856)
HTML views(67)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Luminescent Properties of Ca9Y(PO4)7: Ce3+,Tb3+ Nano-phosphors

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Luminescent Properties of Ca₉Y(PO₄)₇: Ce³⁺,Tb³⁺ Nano-phosphors