Citation: WANG Zan, MI Xiao-Yun, XIE Ling-Jie, PAN Xiao-Ying, ZHOU Hong-Yan, CHEN Shu-Yi, ZHANG Xi-Yan, BAI Zhao-Hui. Preparation and Luminescent Properties of Ca₉Y(PO₄)₇: Ce³⁺,Tb³⁺ Nano-phosphors[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(12): 2136-2142. doi: 10.11862/CJIC.2016.284 shu

Preparation and Luminescent Properties of Ca₉Y(PO₄)₇: Ce³⁺,Tb³⁺ Nano-phosphors

1.
School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022, China

Corresponding author: MI Xiao-Yun,
Received Date: 7 July 2016
Available Online: 2 November 2016
Fund Project:

Ca₉Y(PO₄)₇:Ce³⁺,Tb³⁺ nano-phosphors were synthesized by hydrothermal method. X-ray diffraction (XRD), Scanning electron microscope (SEM) and Photoluminescence (PL) spectra and so on were used to characterize the samples. The effects of Ce³⁺ and Tb³⁺ on the luminescence properties of Ca₉Y(PO₄)₇:Ce³⁺,Tb³⁺ was studied in detail. The result indicates that the luminescence color of Ca₉Y(PO₄)₇:Tb³⁺ can be tuned through adjusting the concentration of Tb³⁺, which is attributed to the energy cross relaxation of Tb³⁺. And the energy transfer mechanism of Ce³⁺-Tb³⁺ was dipole-quadrupole mechanism of electric multipole interactional, the biggest energy transfer efficiency was 55.6%. The emission color of Ca₉Y(PO₄)₇:Ce³⁺,Tb³⁺ can be tuned by the energy transfer of ions and the total emission of activators. SEM showed that the samples had good dispersion, and the particle size of phosphors was about 100 nm.
- Ca₉Y(PO₄)₇:Ce³⁺,Tb³⁺;hydrothermal method;cross relaxation;energy transfer
1. [1]
  [1] Zhang Y, Geng D L, Kang X J, et al. Inorg. Chem., 2013,52:12986-12994
2. [2]
  [2] Wang T, Hu Y H, Chen L, et al. Appl. Phys. A, 2015,120(1):301-308
3. [3]
  [3] Xu M J, Wang L X, Jia D Z, et al. J. Chem. Phys, 2015,17:28802-28808
4. [4]
  [4] Mi X Y, Shi H, Wang Z, et al. J. Mater. Sci, 2016,51:3545-3554
5. [5]
  [5] Bao A, Yang H, Tao C Y. Curr. Appl. Phys., 2009,9:1252-1256
6. [6]
  [6] Wen D W, Dong Z Y, Shi J S, et al. ECS J. Solid State Sci. Technol., 2013,2(9):R178-R185
7. [7]
  [7] Zhang J, Wang Y H, Huang Y. Opt. Mater., 2011,33:1325-1330
8. [8]
  [8] Wen F S, Chen J S, Moon J H, et al. J. Solid State Chem., 2004,177:3114-3118
9. [9]
  [9] Huang C H, Kuo T W, Chen T M, et al. ACS Appl. Mater. Interfaces, 2010,2(5):1395-1399
10. [10]
  [10] Blasse G, Bril A. Philips Res. Rep., 1967,22:481-504
11. [11]
  [11] Sohn K, Choi Y, Park H, et al. J. Electrochem. Soc., 2000, 147:2375-2379
12. [12]
  [12] Reisfeld R, Greenber E, Velapold R, et al. J. Chem. Phys., 1972,56:1698-1705
13. [13]
  [13] WU Jiang(吴疆), ZHANG Ping(张萍), JIANG Chun-Dong(蒋春东). Chinese J. Inorg. Chem.(无机化学学报), 2015,31(6):1201-1206
14. [14]
  [14] Liu X, Lin J. J. Mater. Chem., 2008,18:221-228
15. [15]
  [15] Xue Y, Xiao F, Zhang Q. Spectrochim. Acta, Part A, 2011, 78:1445-1448
16. [16]
  [16] LUO Yi(罗懿), XIA Zhi-Guo(夏志国). Chinese J. Inorg. Chem.(无机化学学报), 2013,29(4):665-670
17. [17]
  [17] Van U. J. Lumines, 1984,29:1-9
18. [18]
  [18] Zhao C, Yin X, Wang Y, et al. J. Lumin., 2012,132(3):617-621
19. [19]
  [19] Mi X Y, Sun J C, Zhou P, et al. J. Mater. Chem., 2015,3(17):4471-4481
20. [20]
  [20] Li G G, Geng D L, Shang M M, et al. J. Phys. Chem. C, 2011,115:21882-21892
21. [21]
  [21] Li K, Zhang Y, Li X, et al. Dalton Trans, 2015,44(10):4683-4692
22. [22]
  [22] Paulose P I, Jose G, Thomas V, et al. J. Phys. Chem. Solids, 2003,64(5):841-846
23. [23]
  [23] Dexter D L, Schulman J H. J. Chem. Phys., 1954,22(6):1063-1070
24. [24]
  [24] Blasse G. Philips Res. Rep., 1969,24:131-144
25. [25]
  [25] Liu C C, Liu R S, Tang Y S, et al. J. Electronchem. Soc., 2008,155(9):248-251
26. [26]
  [26] Kuo T W, Chen T M. J. Electronchem. Soc., 2010,157(6):216-220
27. [27]
  [27] Shi S K, Li J L, Zhang X J, et al. J. Lumin., 2016,180:214-218
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Luminescent Properties of Ca9Y(PO4)7: Ce3+,Tb3+ Nano-phosphors

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通讯作者: 陈斌, bchen63@163.com

Preparation and Luminescent Properties of Ca₉Y(PO₄)₇: Ce³⁺,Tb³⁺ Nano-phosphors