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Citation: SHENG Shuang, ZHAO Hui, HAO Ju-Hong, SUN Li-Ping, HUO Li-Hua. Preparation and Electrochemical Properties of (Pr0.9La0.1)2(Ni0.74Cu0.21Ga0.05)O4+δ-Ce0.9Gd0.1O2-δComposite Cathode[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(12): 2143-2150. doi: 10.11862/CJIC.2016.275 shu

Preparation and Electrochemical Properties of (Pr0.9La0.1)2(Ni0.74Cu0.21Ga0.05)O4+δ-Ce0.9Gd0.1O2-δComposite Cathode

  • 1.

    1 Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China;

  • 2.

    2 Harbin Far East Institute of Technology, Harbin 150025, China

  • Corresponding author: SUN Li-Ping, 
  • Received Date: 8 July 2016
    Available Online: 14 October 2016

    Fund Project:

  • (Pr0.9La0.1)2(Ni0.74Cu0.21Ga0.05)O4+δ(PLNCG) is prepared by EDTA-citrate process, and forms composite cathode with Ce0.9Gd0.1O2-δ(CGO). XRD and SEM results demonstrate that PLNCG is chemical compatible with CGO at 1 000℃. The electrochemical measurements show that the polarization resistance (Rp) of PLNCG-30%CGO is 0.092 Ω·cm2 at 700℃. When the current density reaches 113.3 mA·cm-2, the cathode overpotential is only 39.3 mV at 700℃ in air. The oxygen partial pressure dependence of Rp indicates that the rate limiting step of the composite cathode is charge transfer process. The maximum power density of anode-support single cell (Ni-CGO/CGO/PLNCG-30%CGO) reaches 569 mW·cm-2 at 700℃ with open circuit voltage (OCV) of 0.76 V.
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