Citation: LIN Sen, LI Yue, CUI Yang-Zhe, ZHANG Yan-Ru, WANG Meng-Qin, LI Zhong-Feng, JIN Qiong-Hua. Syntheses and Characterization of Silver(Ⅰ) Complexes of Bis(2-(diphenylphosphino)phenyl)ether[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(12): 2165-2171. doi: 10.11862/CJIC.2016.273 shu

Syntheses and Characterization of Silver(Ⅰ) Complexes of Bis(2-(diphenylphosphino)phenyl)ether

1.
Department of Chemistry, Capital Normal University, Beijing 100048, China

Corresponding author: JIN Qiong-Hua,
Received Date: 12 June 2016
Available Online: 19 October 2016
Fund Project:

Two novel silver(Ⅰ) complexes[Ag(DPEphos)(dppe)]₂SO₄ (1) and[Ag(DPEphos)(SCN)]₂·CH₂Cl₂ (2) (DPEphos=bis(2-(diphenylphosphino)phenyl) ether, dppe=bis(diphenylphosphino)ethane) have been synthesized and characterized by IR, ¹H NMR spectroscopy, elemental analysis, single-crystal X-ray diffraction and fluorescence spectra. Structure analysis shows that complex 1 has simple mono-nuclear structures, and each silver atom is chelated by four phosphines. Complex 2 has a bi-nuclear cluster of Ag(Ⅰ), showing weak argentophilic interactions. The sum of the internal angles of the four-member ring[-Ag-S-Ag-S-] in the Ag₂S₂ core is 360°, demonstrating that the ring is a parallelogram. The luminescent spectra of 1~2 are studied, which show that the emission peaks are assigned to the π-π^* transitions of the diphosphine ligands. Thermogravimetric analysis shows that two complexes begin to decompose at around 340℃, indicating their strong stability.
- bis(2-(diphenylphosphino)phenyl) ether;bis(diphenylphosphino) ethane;silver(Ⅰ) complex;fluorescence;TGA
1. [1]
  [1] Yue C Y, Yan C F, Feng R, et al. Inorg. Chem., 2009,48:2873-2879
2. [2]
  [2] Wu J Y, Chao T C, Zhong M S. Cryst. Growth Des., 2013, 13:2953-2964
3. [3]
  [3] Li X X, Gong Y Q, Zhao H X, et al. Inorg. Chem., 2014,53:12127-12134
4. [4]
  [4] Pallavicini P, Dacarroa G, Diaz-Fernandez Y A, et al. Coord. Chem. Rev., 2014,275:37-53
5. [5]
  [5] Minaev B, Jansson E,Ågren H. J. Chem. Phys., 2006,125:234704(18 pages)
6. [6]
  [6] Wang X X, Liu Y G, Hecke K V, et al. Z. Anorg. Allg. Chem., 2015,641:903-910
7. [7]
  [7] Ming C L, Li Y H, Li G Y, et al. Transition Met. Chem., 2014,39:477-485
8. [8]
  [8] Kranenburg M, Vander Burgt Y, Kamer P, et al. Organome-tallics, 1995,14:3081-3089
9. [9]
  [9] Venkateswaran R, Balakrishna M S, Mobin S M, et al. Inorg. Chem., 2007:720-731
10. [10]
  [10] Kaeser A, Moudam O, Accorsi G, et al. Eur. J. Inorg. Chem., 2014:1345-1355
11. [11]
  [11] Liu X Q, Liu Y Y, Hao Y J, et al. Inorg. Chem. Commun., 2010,13:511-513
12. [12]
  [12] Aslanidis P, Cox P J, Divanidis S, et al. Inorg. Chim. Acta, 2004,357:2677-2686
13. [13]
  [13] Gao S, Li Z F, Liu M, et al. Polyhedron, 2014,83:10-15
14. [14]
  [14] Rajput G, Yadav M K, Drew M G, et al. Inorg. Chem., 2015,54:2572-2579
15. [15]
  [15] Young A G, Hanton L R. Coord. Chem. Rev., 2008,252:1346-1386
16. [16]
  [16] SADABS, Siemens Analytical X-ray Instrument Inc., Madison, WI, 1996.
17. [17]
  [17] Sheldrick G M. SHELXS-97 and SHELXL-97, University of Göttingen, Germany, 1997.
18. [18]
  [18] Huang X, Lu Z F, Jin Q H, et al. Polyhedron, 2013,65:129-135
19. [19]
  [19] Bosch E, Matheny J, BrownA E, et al. CrystEngComm, 2011, 13:5755-5762
20. [20]
  [20] Song L L, Jin Q H, Cui L N, et al. Inorg. Chim. Acta, 2010, 363:2425-2429
21. [21]
  [21] Qiu Q M, Jin Q H, Sun J J, et al. Polyhedron, 2012,44:215-220
22. [22]
  [22] Balakrishna M S, Venkateswaran R, Mobin S M. Polyhedron, 2008,27:899-904
23. [23]
  [23] Christofidis G, Cox P J, Aslanidis P. Polyhedron, 2012,31:502-505
24. [24]
  [24] Freudenmann D, Feldmann C. Inorg. Chim. Acta, 2011,375:311-313
25. [25]
  [25] Jin Q H, Yuan Y, Yang Y P, et al. Polyhedron, 2015,101:56-64
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沈阳化工大学材料科学与工程学院沈阳 110142