Citation: LIN Sen, LI Yue, CUI Yang-Zhe, ZHANG Yan-Ru, WANG Meng-Qin, LI Zhong-Feng, JIN Qiong-Hua. Syntheses and Characterization of Silver(Ⅰ) Complexes of Bis(2-(diphenylphosphino)phenyl)ether[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(12): 2165-2171. doi: 10.11862/CJIC.2016.273 shu

Syntheses and Characterization of Silver(Ⅰ) Complexes of Bis(2-(diphenylphosphino)phenyl)ether

1.
Department of Chemistry, Capital Normal University, Beijing 100048, China

Corresponding author: JIN Qiong-Hua,
Received Date: 12 June 2016
Available Online: 19 October 2016
Fund Project:

Two novel silver(Ⅰ) complexes[Ag(DPEphos)(dppe)]₂SO₄ (1) and[Ag(DPEphos)(SCN)]₂·CH₂Cl₂ (2) (DPEphos=bis(2-(diphenylphosphino)phenyl) ether, dppe=bis(diphenylphosphino)ethane) have been synthesized and characterized by IR, ¹H NMR spectroscopy, elemental analysis, single-crystal X-ray diffraction and fluorescence spectra. Structure analysis shows that complex 1 has simple mono-nuclear structures, and each silver atom is chelated by four phosphines. Complex 2 has a bi-nuclear cluster of Ag(Ⅰ), showing weak argentophilic interactions. The sum of the internal angles of the four-member ring[-Ag-S-Ag-S-] in the Ag₂S₂ core is 360°, demonstrating that the ring is a parallelogram. The luminescent spectra of 1~2 are studied, which show that the emission peaks are assigned to the π-π^* transitions of the diphosphine ligands. Thermogravimetric analysis shows that two complexes begin to decompose at around 340℃, indicating their strong stability.
- bis(2-(diphenylphosphino)phenyl) ether;bis(diphenylphosphino) ethane;silver(Ⅰ) complex;fluorescence;TGA
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沈阳化工大学材料科学与工程学院沈阳 110142