Citation: LIN Sen, LI Yue, CUI Yang-Zhe, ZHANG Yan-Ru, WANG Meng-Qin, LI Zhong-Feng, JIN Qiong-Hua. Syntheses and Characterization of Silver(Ⅰ) Complexes of Bis(2-(diphenylphosphino)phenyl)ether[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(12): 2165-2171. doi: 10.11862/CJIC.2016.273 shu

Syntheses and Characterization of Silver(Ⅰ) Complexes of Bis(2-(diphenylphosphino)phenyl)ether

1.
Department of Chemistry, Capital Normal University, Beijing 100048, China

Corresponding author: JIN Qiong-Hua,
Received Date: 12 June 2016
Available Online: 19 October 2016
Fund Project:

Two novel silver(Ⅰ) complexes[Ag(DPEphos)(dppe)]₂SO₄ (1) and[Ag(DPEphos)(SCN)]₂·CH₂Cl₂ (2) (DPEphos=bis(2-(diphenylphosphino)phenyl) ether, dppe=bis(diphenylphosphino)ethane) have been synthesized and characterized by IR, ¹H NMR spectroscopy, elemental analysis, single-crystal X-ray diffraction and fluorescence spectra. Structure analysis shows that complex 1 has simple mono-nuclear structures, and each silver atom is chelated by four phosphines. Complex 2 has a bi-nuclear cluster of Ag(Ⅰ), showing weak argentophilic interactions. The sum of the internal angles of the four-member ring[-Ag-S-Ag-S-] in the Ag₂S₂ core is 360°, demonstrating that the ring is a parallelogram. The luminescent spectra of 1~2 are studied, which show that the emission peaks are assigned to the π-π^* transitions of the diphosphine ligands. Thermogravimetric analysis shows that two complexes begin to decompose at around 340℃, indicating their strong stability.
- bis(2-(diphenylphosphino)phenyl) ether;bis(diphenylphosphino) ethane;silver(Ⅰ) complex;fluorescence;TGA
1. [1]
  [1] Yue C Y, Yan C F, Feng R, et al. Inorg. Chem., 2009,48:2873-2879
2. [2]
  [2] Wu J Y, Chao T C, Zhong M S. Cryst. Growth Des., 2013, 13:2953-2964
3. [3]
  [3] Li X X, Gong Y Q, Zhao H X, et al. Inorg. Chem., 2014,53:12127-12134
4. [4]
  [4] Pallavicini P, Dacarroa G, Diaz-Fernandez Y A, et al. Coord. Chem. Rev., 2014,275:37-53
5. [5]
  [5] Minaev B, Jansson E,Ågren H. J. Chem. Phys., 2006,125:234704(18 pages)
6. [6]
  [6] Wang X X, Liu Y G, Hecke K V, et al. Z. Anorg. Allg. Chem., 2015,641:903-910
7. [7]
  [7] Ming C L, Li Y H, Li G Y, et al. Transition Met. Chem., 2014,39:477-485
8. [8]
  [8] Kranenburg M, Vander Burgt Y, Kamer P, et al. Organome-tallics, 1995,14:3081-3089
9. [9]
  [9] Venkateswaran R, Balakrishna M S, Mobin S M, et al. Inorg. Chem., 2007:720-731
10. [10]
  [10] Kaeser A, Moudam O, Accorsi G, et al. Eur. J. Inorg. Chem., 2014:1345-1355
11. [11]
  [11] Liu X Q, Liu Y Y, Hao Y J, et al. Inorg. Chem. Commun., 2010,13:511-513
12. [12]
  [12] Aslanidis P, Cox P J, Divanidis S, et al. Inorg. Chim. Acta, 2004,357:2677-2686
13. [13]
  [13] Gao S, Li Z F, Liu M, et al. Polyhedron, 2014,83:10-15
14. [14]
  [14] Rajput G, Yadav M K, Drew M G, et al. Inorg. Chem., 2015,54:2572-2579
15. [15]
  [15] Young A G, Hanton L R. Coord. Chem. Rev., 2008,252:1346-1386
16. [16]
  [16] SADABS, Siemens Analytical X-ray Instrument Inc., Madison, WI, 1996.
17. [17]
  [17] Sheldrick G M. SHELXS-97 and SHELXL-97, University of Göttingen, Germany, 1997.
18. [18]
  [18] Huang X, Lu Z F, Jin Q H, et al. Polyhedron, 2013,65:129-135
19. [19]
  [19] Bosch E, Matheny J, BrownA E, et al. CrystEngComm, 2011, 13:5755-5762
20. [20]
  [20] Song L L, Jin Q H, Cui L N, et al. Inorg. Chim. Acta, 2010, 363:2425-2429
21. [21]
  [21] Qiu Q M, Jin Q H, Sun J J, et al. Polyhedron, 2012,44:215-220
22. [22]
  [22] Balakrishna M S, Venkateswaran R, Mobin S M. Polyhedron, 2008,27:899-904
23. [23]
  [23] Christofidis G, Cox P J, Aslanidis P. Polyhedron, 2012,31:502-505
24. [24]
  [24] Freudenmann D, Feldmann C. Inorg. Chim. Acta, 2011,375:311-313
25. [25]
  [25] Jin Q H, Yuan Y, Yang Y P, et al. Polyhedron, 2015,101:56-64
1. [1]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
2. [2]
  YanYuan Jia , Rong Rong , Jie Liu , Jing Guo , GuoYu Jiang , Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035
3. [3]
  Qin Li , Kexin Yang , Qinglin Yang , Xiangjin Zhu , Xiaole Han , Tao Huang . Illuminating Chlorophyll: Innovative Chemistry Popularization Experiment. University Chemistry, 2024, 39(9): 359-368. doi: 10.3866/PKU.DXHX202309059
4. [4]
  Zehua Zhang , Haitao Yu , Yanyu Qi . 多重共振TADF分子的设计策略. Acta Physico-Chimica Sinica, 2025, 41(1): 2309042-. doi: 10.3866/PKU.WHXB202309042
5. [5]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
6. [6]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
7. [7]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
8. [8]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
9. [9]
  Qiaowen CHANG , Ke ZHANG , Guangying HUANG , Nuonan LI , Weiping LIU , Fuquan BAI , Caixian YAN , Yangyang FENG , Chuan ZUO . Syntheses, structures, and photo-physical properties of iridium phosphorescent complexes with phenylpyridine derivatives bearing different substituting groups. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 235-244. doi: 10.11862/CJIC.20240311
10. [10]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
11. [11]
  Yihao Zhao , Jitian Rao , Jie Han . Synthesis and Photochromic Properties of 3,3-Diphenyl-3H-Naphthopyran: Design and Teaching Practice of a Comprehensive Organic Experiment. University Chemistry, 2024, 39(10): 149-155. doi: 10.3866/PKU.DXHX202402050
12. [12]
  Jianfeng Yan , Yating Xiao , Xin Zuo , Caixia Lin , Yaofeng Yuan . Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives. University Chemistry, 2024, 39(4): 329-337. doi: 10.3866/PKU.DXHX202310005
13. [13]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
14. [14]
  Cheng Zheng , Shiying Zheng , Yanping Zhang , Shoutian Zheng , Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, 2024, 39(7): 322-329. doi: 10.3866/PKU.DXHX202310131
15. [15]
  Tingbo Wang , Yao Luo , Bingyan Hu , Ruiyuan Liu , Jing Miao , Huizhe Lu . Quantitative Computational Study on the Claisen Rearrangement Reaction of Allyl Phenyl Ethers: An Introduction to a Computational Chemistry Experiment. University Chemistry, 2024, 39(11): 278-285. doi: 10.12461/PKU.DXHX202403082
16. [16]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
17. [17]
  Yongpo Zhang , Xinfeng Li , Yafei Song , Mengyao Sun , Congcong Yin , Chunyan Gao , Jinzhong Zhao . Synthesis of Chlorine-Bridged Binuclear Cu(I) Complexes Based on Conjugation-Driven Cu(II) Oxidized Secondary Amines. University Chemistry, 2024, 39(5): 44-51. doi: 10.3866/PKU.DXHX202309092
18. [18]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
19. [19]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
20. [20]
  Dongdong YANG , Jianhua XUE , Yuanyu YANG , Meixia WU , Yujia BAI , Zongxuan WANG , Qi MA . Design and synthesis of two coordination polymers for the rapid detection of ciprofloxacin based on triphenylpolycarboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2466-2474. doi: 10.11862/CJIC.20240266

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(327)
HTML views(42)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142