Citation: WEN Xiao-Ling, DING Yi-Ming, OUYANG Jian-Ming. Differences in Adsorption of Anionic, Cationic and Nonionic Surfactant on Micron/nano Calcium Oxalate Monohydrate and Dihydrate Crystals[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(12): 2102-2108. doi: 10.11862/CJIC.2016.269 shu

Differences in Adsorption of Anionic, Cationic and Nonionic Surfactant on Micron/nano Calcium Oxalate Monohydrate and Dihydrate Crystals

1.
Institute of Biomineralization and Lithiasis Research, Jinan University, Guangzhou 510632, China

Corresponding author: OUYANG Jian-Ming,
Received Date: 16 April 2016
Available Online: 9 September 2016
Fund Project:

In order to explore the effect of urine components with different charges on micron/nano urinary crystallites, the adsorption difference of three surfactants with different charges onto micron/nano calcium oxalate monohydrate (COM) and dihydrate (COD) was studied, including anionic surfactant sodium diisooctyl sulfosuccinate (AOT), cationic surfactant cetyltrimethylammonium bromide (CTAB), and nonionic surfactant nonylphenol ethoxylate (NP-40). The adsorption quantity of surfactants on COM and COD was ranked in the following order:AOT > CTAB > NP-40, that is, the absorption quantity of anionic surfactant is the maximum, and absorption quantity of nonionic surfactant is the minimum. The adsorption quantity of COM was greater than COD with the same size; the absolute value of ζ potential on surface of COM and COD was increased after adsorption of surfactants, it was conducive to inhibit crystal aggregation and sedimentation. The molecular models of surfactants adsorbed on crystal surface were proposed. There are different interactions between micro/nano COM, COD crystal and anionic, cationic, nonionic surfactants. The larger the adsorption quantity of surfactants is, the slower the sedimentation rate is, so the stabilizing effect on crystal suspension is more obvious.
- crystal size;anionic surfactant;cationic surfactant;nonionic surfactant;adsorption model;calcium oxalate
1. [1]
  [1] Zhang D, Qi L, Ma J, et al. Chem. Mater., 2002,14(6):2450-2457
2. [2]
  [2] Zhang G N, Ouyang J M, Xue J F, et al. Mater. Sci. Eng. C, 2013,33(7):4039-4045
3. [3]
  [3] Sürer H, Ozgün T, Yilmaz F M, et al. Clin. Chem. Lab. Med., 2014,52(4):e71-e73
4. [4]
  [4] Poon N W, Gohel M D I. Carbohyd. Res., 2012,347:64-68
5. [5]
  [5] Sikiric M, Filipovi-Vincekovic N, Babic-Ivancic V, et al. J. Colloid Interface Sci., 1999,212(2):384-389
6. [6]
  [6] Saso L, Grippa E, Gatto M T, et al. Int. J. Urol., 2001,8(3):124-127
7. [7]
  [7] Wei X X, Yang J, Li Z Y, et al. Colloids Surf. A, 2012,401:107-115
8. [8]
  [8] Dong R, Weng R, Dou Y, et al. J. Phys. Chem. B, 2010,114(6):2131-2139
9. [9]
  [9] Sikiric M D, Füredi-Milhofer H. Adv. Colloid Interface Sci., 2006,128:135-158
10. [10]
  [10] Elliot J S, Rabinowitz I N. J. Urol., 1980,123(3):324-327
11. [11]
  [11] Gao J, Xue J F, Xu M, et al. Int. J. Nanomed., 2014,9:4399-4409
12. [12]
  [12] LIU Yi-Ming(柳一鸣), XIA Zhi-Yue(夏志月), OUYANG Jing-Ming(欧阳健明), et al. Chinese J. Inorg. Chem.(无机化学学报), 2013,29(5):903-909
13. [13]
  [13] Suttiponparnit K, Jiang J, Sahu M, et al. Nanoscale Res. Lett., 2011,6,1-8
14. [14]
  [14] Patila S, Sandbergb A, Heckertc E, et al. Biomaterials, 2007,28(31):4600-4607
15. [15]
  [15] Sun X Y, Ouyang J M, Liu A J, et al. Mater. Sci. Eng. C, 2015,57:147-156
16. [16]
  [16] WEN Xiao-Ling(温小玲), GAN Qiong-Zhi(甘琼枝), OUYANG Jing-Ming(欧阳健明). Chinese J. Inorg. Chem. (无机化学学报), 2015,31(10):2021-2029
17. [17]
  [17] Tunik L, Furedi-Milhofer H, Garti N. Langmuir, 1998,14:3351-3355
18. [18]
  [18] Chebotarev A N, Paladenko T V, Shcherbakova T M. J. Anal. Chem., 2004,59(4):309-313
19. [19]
  [19] Brown D G, Jaffe P R. Environ. Sci. Technol., 2001,35:2022-2025
20. [20]
  [20] Tunik L, Addadi L, Garti N, et al. J. Cryst. Growth, 1996, 167(3):748-755
21. [21]
  [21] Mandal A B, Nair B U. J. Phys. Chem., 1991,95(22):9008-9013
22. [22]
  [22] Calvo E, Bravo R, Amigo A, et al. Fluid Phase Equilib., 2009,282(1):14-19
23. [23]
  [23] Kulaksizoglu S, Sofikerim M, Cevik C. Int. J. Urol., 2007,14(3):214-218
24. [24]
  [24] Christmas K G, Gower L B, Khan S R, et al. J. Colloid Interface Sci., 2002,256(1):168-174
25. [25]
  [25] Sheng X, Jung T, Wesson J A, et al. Proc. Natl. Acad. Sci. U.S.A., 2005,102(2):267-272
26. [26]
  [26] Farmanesh S, Chung J, Sosa R D. J. Am. Chem. Soc., 2014, 136(36):12648-12657
27. [27]
  [27] Zhang R, Somasundaran P. Adv. Colloid Interface Sci., 2006, 123:213-229
28. [28]
  [28] Wang X, Jiang Z Y, Xie Z X, et al. Acc. Chem. Res., 2014, 42(7):308-318
29. [29]
  [29] Rosen M J. J. Am. Oil Chem. Soc., 1975,52(11):431-435
30. [30]
  [30] Paria S, Yuet P K. Ind. Eng. Chem. Res., 2007,46(1):108-113
31. [31]
  [31] WEN Xiao-Ling(温小玲), OUYANG Jing-Ming(欧阳健明). Chinese J. Inorg. Chem.(无机化学学报), 2016,32(1):103-110
32. [32]
  [32] Ofir E, Oren Y, Adin A. Desalination, 2007,204(1):33-38
33. [33]
  [33] Finlayson B, Reid S. Invest. Urol., 1978,15:442448
34. [34]
  [34] Kok D J, Khan S R. Kidney Int., 1994,46:847
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