Citation: WEN Xiao-Ling, DING Yi-Ming, OUYANG Jian-Ming. Differences in Adsorption of Anionic, Cationic and Nonionic Surfactant on Micron/nano Calcium Oxalate Monohydrate and Dihydrate Crystals[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(12): 2102-2108. doi: 10.11862/CJIC.2016.269 shu

Differences in Adsorption of Anionic, Cationic and Nonionic Surfactant on Micron/nano Calcium Oxalate Monohydrate and Dihydrate Crystals

1.
Institute of Biomineralization and Lithiasis Research, Jinan University, Guangzhou 510632, China

Corresponding author: OUYANG Jian-Ming,
Received Date: 16 April 2016
Available Online: 9 September 2016
Fund Project:

In order to explore the effect of urine components with different charges on micron/nano urinary crystallites, the adsorption difference of three surfactants with different charges onto micron/nano calcium oxalate monohydrate (COM) and dihydrate (COD) was studied, including anionic surfactant sodium diisooctyl sulfosuccinate (AOT), cationic surfactant cetyltrimethylammonium bromide (CTAB), and nonionic surfactant nonylphenol ethoxylate (NP-40). The adsorption quantity of surfactants on COM and COD was ranked in the following order:AOT > CTAB > NP-40, that is, the absorption quantity of anionic surfactant is the maximum, and absorption quantity of nonionic surfactant is the minimum. The adsorption quantity of COM was greater than COD with the same size; the absolute value of ζ potential on surface of COM and COD was increased after adsorption of surfactants, it was conducive to inhibit crystal aggregation and sedimentation. The molecular models of surfactants adsorbed on crystal surface were proposed. There are different interactions between micro/nano COM, COD crystal and anionic, cationic, nonionic surfactants. The larger the adsorption quantity of surfactants is, the slower the sedimentation rate is, so the stabilizing effect on crystal suspension is more obvious.
- crystal size;anionic surfactant;cationic surfactant;nonionic surfactant;adsorption model;calcium oxalate
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沈阳化工大学材料科学与工程学院沈阳 110142