Citation: WANG Hui-Gang, ZHANG Qi, ZHANG Ji-Long, YU Feng, LI Rui-Feng. Nano Sulfated Zirconia Synthesis and Its Catalytic Properties in the Transesterification[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(11): 1959-1964. doi: 10.11862/CJIC.2016.264 shu

Nano Sulfated Zirconia Synthesis and Its Catalytic Properties in the Transesterification

1.
College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: YU Feng,
Received Date: 8 April 2016
Available Online: 29 September 2016
Fund Project:

Nano SO₄^2-/ZrO₂ solid acid catalysts were prepared by two-step crystallization-post impregnation method and their catalytic performance in the transesterification of vegetable oil with methanol was investigated. The results of XRD, N₂ adsorption-desorption and TEM showed that the single tetragonal phase catalyst calcined at 600℃ was composed of nano crystals about 5~10 nm and had the specific surface area of 137 m²·g^-1 and the pore size of 3.7 nm. NH₃-TPD data indicated that the calcination temperature could improve the content and intensity of the surface acid, and that more superacid content was favorable to effect the efficient conversion under general conditions. In the transesterification reaction, under the operating conditions of 5%(w/w) of catalyst calcined at 600℃, the molar ratio of methanol to oil 20:1, at 135℃ and for 6 h, vegetable oil could be completely converted to fatty acid methyl esters. Compared with the traditional SO₄^2-/ZrO₂ catalyst, the nano SO₄^2-/ZrO₂ catalyst had a higher catalytic performance and good reuse at low reaction temperature.
- biodiesel;nano material;SO₄^2-/ZrO₂;solid acid catalyst;transesterification
1. [1]
  [1] Talebian-Kiakalaieh A, Amin N A S, Mazaheri H. Appl. Energy, 2013,104(2):683-710
2. [2]
  [2] Helwani Z, Othman M R, Aziz N, et al. Appl. Catal. A:Gen., 2009,363(1):1-10
3. [3]
  [3] Lam M K, Lee K T, Mohamed A R. Biotechnol. Adv., 2010, 28(4):500-518
4. [4]
  [4] YU Hui(于荟), ZHU Yin-hua(朱银华), LIU Chang(刘畅), et al. Chin. J. Catal.(催化学报), 2009,30(3):265-271
5. [5]
  [5] Reddy B M, Patil M K. Chem. Rev., 2009,109(6):2185-2208
6. [6]
  [6] Saravanan K, Tyagi B, Shukla R S, et al. Appl. Catal. B: Environ., 2015,172-173:108-115
7. [7]
  [7] Sharma Y C, Singh B, Korstad J. Biofuel Bioprod. Biorefin., 2011,5(1):69-92
8. [8]
  [8] Deshmane V G, Adewuyi Y G. Appl. Catal. A:Gen., 2013, 462:196-206
9. [9]
  [9] Chen H, Wang J F. Chin. J. Process Eng., 2006,6(4):571-575
10. [10]
  [10] Jitputti J, Kitiyanan B, Rangsunvigit P, et al. Chem. Eng. J., 2006,116(1):61-66
11. [11]
  [11] Rattanaphra D, Harvey A. Top Catal., 2010,53(11/12):773-782
12. [12]
  [12] Garcia C M, Teixeira S, Marciniuk L L, et al. Bioresour. Technol., 2008,99(14):6608-6613
13. [13]
  [13] ZHANG Qi(张琪), ZHANG Ji-Long(张继龙), WANG Hui-Gang(王会刚), et al. Mod. Chem. Ind.(现代化工), 2013,33(8):134-138
14. [14]
  [14] Zhang Q Q, Ming W X, Ma J H, et al. J. Mater. Chem. A, 2014,2(23):8712-8718
15. [15]
  [15] Cristian D M M, Alfonso E R S, et al. J. Mol. Catal. A:Chem., 2015,398:325-335
16. [16]
  [16] Boskovic G C, Zarubica A R, et al. J. Therm. Anal. Calorim., 2008,91:849-854
17. [17]
  [17] Patel A, Brahmkhatri V, Singh N. Renewable Energ., 2013, 51:227-233
18. [18]
  [18] Liao Y, Huang X, Liao X P, et al. J. Mol. Catal. A:Chem., 2011,347(1):46-51
19. [19]
  [19] Yuan Q, Li L L, Lu S L, et al. J. Phys. Chem. C, 2009,113(10):4117-4124
20. [20]
  [20] Yue Z, Wong W T, Yung K F. Appl. Energy, 2014,116(3): 191-198
21. [21]
  [21] Ivanov V K, Baranchikov A Y, et al. J. Solid State Chem., 2013,198(2):496-505
22. [22]
  [22] Velasquez-Orta S B, Lee J G M, Harvey A P. Biochem. Eng. J., 2013,76:83-89
23. [23]
  [23] Fu B, Gao L, Lei N, et al. Energy Fuels, 2009,23(1):569-572
24. [24]
  [24] Furuta S, Matsuhashi H, Arata K. Catal. Commun., 2004,5(12):721-723
25. [25]
  [25] Shu Q, Song Q, Yang B, et al. Catal. Commun., 2007,8(12): 2159-2165
26. [26]
  [26] Suwannakarn K, Lotero E, Goodwin J G, et al. J. Catal., 2008,255(2):279-286
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沈阳化工大学材料科学与工程学院沈阳 110142