Citation: LI Meng-Yun, FU Ting-Jun, WANG Yu-Chun, YAN Li-Fei, LI Zhong. Influence of H⁺ Contents of Support on CuY Catalyst for Catalytic Performances of Oxidative Carbonylation of Methanol[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(11): 1951-1958. doi: 10.11862/CJIC.2016.258 shu

Influence of H⁺ Contents of Support on CuY Catalyst for Catalytic Performances of Oxidative Carbonylation of Methanol

1.
Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, China

Corresponding author: LI Zhong,
Received Date: 5 March 2016
Available Online: 30 August 2016
Fund Project:

A series of Y zeolite supported Cu catalysts (CuY) with Cu loading of 6.4% were prepared by wet impregnation method and investigated in oxidative carbonylation of methanol. The microstructure and surface properties of the catalysts were characterized by X-ray diffraction (XRD), H₂-temperature program reduction (H₂-TPR), NH₃-temperature program desorption (NH₃-TPD), transmission electron microscope(TEM) techniques. With the increase of H⁺ content, the Y zeolite supports were more conductive to the cation exchangment with Cu²⁺, leading to well dispersed Cu species in cages. Above all, the non-exchanged Na⁺ of Y zeolite resulted in more Cu species located in the super cages. After calcination, the copper species converted into Cu+, which enhanced the catalytic activity of oxidative carbonylation of methanol. The introduction of Cu species into Y zeolite produced moderate acid sites and the amount of acid was also increased with the increase of Cu species located in the cages, As a result, the reaction product distribution varied and the selectivity of DMC decreased with the increase of H⁺ content. The CuY catalyst prepared by incipient-wetness impregnation method gave 92.3% selectivity of DMC, whereas the Cu catalyst supported on NaY zeolite by wet impregnation method gave 82.4% selectivity of DMC and high space-time yield (STY) of DMC, 109.1 mg·g^-1·h^-1.
- methanol oxidative carbonylation;Y zeolite;copper catalyst;acidity;product selectivity
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Influence of H+ Contents of Support on CuY Catalyst for Catalytic Performances of Oxidative Carbonylation of Methanol

References

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通讯作者: 陈斌, bchen63@163.com

Influence of H⁺ Contents of Support on CuY Catalyst for Catalytic Performances of Oxidative Carbonylation of Methanol