Citation: MENG Xian-Wei, YANG Hong-Wei, HU Chang-Yi, MAO Yong-Yun, YANG Yu-Wen, CHEN Jia-Lin, . Flower-like Silver Sphere Catalytic Material:Preparation and Catalytic Activity for the Hydrogenation Reduction of p-Nitrophenol[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(11): 1981-1986. doi: 10.11862/CJIC.2016.249 shu

Flower-like Silver Sphere Catalytic Material:Preparation and Catalytic Activity for the Hydrogenation Reduction of p-Nitrophenol

1.
State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China

Corresponding author: YANG Hong-Wei, ,
Received Date: 4 June 2016
Available Online: 13 September 2016
Fund Project:

The flower-like silver sphere structure has been rapidly synthesized by self-assembly of silver nanoflakes through one-step direct mixing of silver nitrate aqueous solution and an aqueous solution containing ferrous sulfate and citric acid. The influence of dropping speed of silver nitrate aqueous solution and the dosage of citric acid on the morphology and size of product were investigated in details through different characteristic methods including X-ray diffraction (XRD) and scanning electron microscopy (SEM). Furthermore, the possible formation mechanism of flower-like silver sphere was explored. The obtained experimental results indicated that the morphology of silver particles could transform from thin flake into flower-like sphere by simply adjusting the dropping speed of silver nitrate aqueous solution. Additionally, this type of nanomaterial exhibited superior catalytic activity for the hydrogenation reduction of p-nitrophenol.
- silver;ferrous sulfate;flower-like sphere;p-nitrophenol;hydrogenation reduction
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沈阳化工大学材料科学与工程学院沈阳 110142