Citation: XIONG Le-Yan, ZHANG Nan, LI Xue-Ni, GUO Zan-Ru, ZHENG Long-Zhen. An Electrocatalyst Based on Carbon Nanotubes with a High Sensitivity for Detection of Reduced Glutathione[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(11): 1942-1950. doi: 10.11862/CJIC.2016.225 shu

An Electrocatalyst Based on Carbon Nanotubes with a High Sensitivity for Detection of Reduced Glutathione

1.
Department of Chemistry and Chemical Engineering, East China Jiaotong University, Nanchang 330013, China

Corresponding author: GUO Zan-Ru, ZHENG Long-Zhen,
Received Date: 7 January 2016
Available Online: 7 September 2016
Fund Project:

10-Methylphenothiazine/2-hydroxypropyl-β-cyclodextrin guest-host compounds were mixed with single-walled carbon nanotubes to give composite materials MPT-HP-β-CD/MWNT by a two-step method, which were characterized by FT-IR, UV-Vis, fluorescence spectroscopy, Raman spectrum and TEM. The applications of these composite materials toward the catalytic oxidation of glutathione (GSH) were demonstrated by cyclic voltammetry measurements. These results proved that the presence of MWNT could improve the electrical conductivity and catalytic activity of the composite material. The influences of the pH value, temperature, and scan rate on the catalyst activity were examined. These studies suggest that the MPT-HP-β-CD/MWNT composite materials could be used for the electrochemical detection of GSH with good stability and reproducibility and high sensitivity. The optimal detection concentration is 5×10^-7~4.95×10^-5 mol·L^-1 and the detection limit is 3.96×10^-8 mol·L^-1 (S/N=3).
- glutathione;2-hydroxypropyl-β-cyclodextrin;10-methylphenothiazine;multi-walled carbon nanotubes;electrochemical detection
1. [1]
  [1] Ookhtens M, Kaplowitz N. Semin. Liver Dis., 1997,18(4):313-329
2. [2]
  [2] Hwang C, Sinskey A J, Lodish H F. Science, 1992,257(5076): 1496-1502
3. [3]
  [3] Devi G S, Prasad M H, Saraswathi I, et al. Clin. Chim. Acta, 2000,293(1):53-62
4. [4]
  [4] McDonagh M, Ali L, Kahn A, et al. Biochem. Soc. Trans., 1997,25(1):146S-146S
5. [5]
  [5] Halliwell B. Free Radical Res., 1998,29(6):469-486
6. [6]
  [6] Singh S V, Xu B H, Tkalcevic G T, et al. Cancer Lett., 1994, 77(1):15-24
7. [7]
  [7] Nagendra P, Yathirajan H S, Rangappa K S, et al. J. Indian Chem. Soc., 2002,79(7):602-604
8. [8]
  [8] Tabor C W, Tabor H. Anal. Biochem., 1977,78(2):543-553
9. [9]
  [9] LIN Li(林丽), CAO Xu-Ni(曹旭妮), ZHANG Wen(张文), et al. Chin. J. Anal. Chem.(分析化学), 2003,31(3):261-265
10. [10]
  [10] WANG Qing-Jiang(王清江), CHEN Xiang(陈相), DING Fei (丁飞), et al. Chin. J. Anal. Chem.(分析化学), 2005,33(7): 969-971
11. [11]
  [11] Kim G J, Yoon D H, Yun M Y, et al. RSC Adv., 2014,4(36):18731-18736
12. [12]
  [12] Redegeld F A M, Van Opstal M A J, Houdkamp E, et al. Anal. Biochem., 1988,174(2):489-495
13. [13]
  [13] Satoh I, Arakawa S, Okamoto A. Sens. Actuators B, 1991,5(1):245-247
14. [14]
  [14] Raoof J B, Ojani R, Karimi-Maleh H, et al. Anal. Methods, 2011,3(11):2637-2643
15. [15]
  [15] Ndamanisha J C, Bai J, Qi B, et al. Anal. Biochem., 2009, 386(1):79-84
16. [16]
  [16] Budnikov G K, Ziyatdinova G K, Valitova Y R. J. Anal. Chem., 2004,59(6):573-576
17. [17]
  [17] Wang Y, Lu J, Tang L, et al. Anal. Chem., 2009,81(23):9710-9715
18. [18]
  [18] Domelsmith L N, Munchausen L L, Houk K N. J. Am. Chem. Soc., 1977,99(20):6506-6514
19. [19]
  [19] Domelsmith L N, Munchausen L L, Houk K N. J. Am. Chem. Soc., 1977,99(13):4311-4321
20. [20]
  [20] Fan S, Chapline M G, Franklin N R, et al. Science, 1999, 283(5401):512-514
21. [21]
  [21] Wang Z, Xiao S, Chen Y. J. Electroanal. Chem., 2006,589(2):237-242
22. [22]
  [22] Zhang Y, Wen Y, Liu Y, et al. Electrochem. Commun., 2004, 6(11):1180-1184
23. [23]
  [23] Liu Y, Liu Y, Feng H, et al. Biosens. Bioelectron., 2012,35(1):63-68
24. [24]
  [24] CHEN Chuan-Sheng(陈传盛), LIU Tian-Gui(刘天贵), CHEN Xiao-Hua(陈小华), et al. Rare Metal Mater. Eng.(稀有金属材料与工程), 2009,S1:477-480
25. [25]
  [25] Guo Z, Feng Y, Zhu D, et al. Adv. Funct. Mater., 2013,23(40):5010-5018
26. [26]
  [26] WANG Guang-Hui(王光辉), HUANG Lei(黄磊), YU Rong (于荣). J. Yunnan University:Nat. Sci. Ed.(云南大学学报: 自然科学版), 2008,30(6):606-610
27. [27]
  [27] Guo Z, Yin H, Feng Y, et al. RSC Adv., 2016,6(44):37953-37964
28. [28]
  [28] Jiang C M,Lin X Q. J. Power Sources, 2007,164(1):49-55
29. [29]
  [29] Kang Y, Yuan J, Yan Q, et al. Polym. Adv. Technol., 2012, 23(2):255-261
30. [30]
  [30] Tian X, Cheng C, Yuan H, et al. Talanta, 2012,93:79-85
31. [31]
  [31] Zheng L Z, Xiong L Y, Liu Q, et al. Electrochim. Acta, 2011,56(27):9860-9867
32. [32]
  [32] Li X N, Zheng L Z, Wang Y M, et al. RSC Adv., 2015,5(88):71749-71755
33. [33]
  [33] Fajerwerg K, Foussard J N, Perrard A, et al. Water Sci. Technol., 1997,35(4):103-110
34. [34]
  [34] Gong X, Li H. J. Electrochem. Soc., 2000,147(1):238-241
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