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Citation: FAN Ting-Ting, QU Xiang-Long, LI Jia-Jia, DONG Gao-Yun, LI Rui, GONG Jia-Li, LI Xia. Lanthanide Complexes with 2,5-Thiophenedicarboxylate and 1,10-Phenanthroline: Crystal Structures,Fluorescence Properties and Luminescence Sensing for Cu2+Ion[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(11): 1911-1918. doi: 10.11862/CJIC.2016.221 shu

Lanthanide Complexes with 2,5-Thiophenedicarboxylate and 1,10-Phenanthroline: Crystal Structures,Fluorescence Properties and Luminescence Sensing for Cu2+Ion

  • 1.

    Department of Chemistry, Capital Normal University, Beijing 100048, China

  • Corresponding author: LI Xia, 
  • Received Date: 22 June 2016
    Available Online: 8 August 2016

    Fund Project:

  • Three lanthanide-organic frameworks[Ln(2,5-tdc)1.5(phen)(H2O)]n (Ln=Gd (1), Tb (2), Dy (3); 2,5-tdc=2,5-thiophenedicarboxylate and phen=1,10-phenanthroline) have been synthesized and characterized by X-ray single-crystal diffraction. Complexes 1~3 feature isostructural 2D structures. The luminescence properties of 1~3 were investigated. Under the excitation of 340 nm, the emission spectrum of complex 1 shows a broad band centre at 366 and 387 nm, which plausibly arises from ligand-centered π*-π transition within the ligands. Complex 2 displays green emission and shows four emission peaks at 491, 545, 588 and 620 nm, corresponding to 5D4→7FJ (J=6~3) transitions of Tb3+ under the excitation of 310 nm. The 5D4 emission decay curve reveals a monoexponential behavior with the lifetime value of (0.123±0.005) ms. The emission spectrum of complex 3 records two peaks of 482 and 575 nm, corresponding to the 4F5/2→6H15/2 and 4F5/2→6H13/2 transition of Dy3+, respectively, under the excitation of 330 nm. Moreover, the fluorescence sensing ability of complex 2 was investigated, revealing that it can be used as a fluorescence probe to detect Cu2+ in aqueous solution. CCDC:1036885, 1; 1036884, 2; 1036886, 3.
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