Advanced Search

Citation: FAN Ting-Ting, QU Xiang-Long, LI Jia-Jia, DONG Gao-Yun, LI Rui, GONG Jia-Li, LI Xia. Lanthanide Complexes with 2,5-Thiophenedicarboxylate and 1,10-Phenanthroline: Crystal Structures,Fluorescence Properties and Luminescence Sensing for Cu2+Ion[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(11): 1911-1918. doi: 10.11862/CJIC.2016.221 shu

Lanthanide Complexes with 2,5-Thiophenedicarboxylate and 1,10-Phenanthroline: Crystal Structures,Fluorescence Properties and Luminescence Sensing for Cu2+Ion

  • 1.

    Department of Chemistry, Capital Normal University, Beijing 100048, China

  • Corresponding author: LI Xia, 
  • Received Date: 22 June 2016
    Available Online: 8 August 2016

    Fund Project:

  • Three lanthanide-organic frameworks[Ln(2,5-tdc)1.5(phen)(H2O)]n (Ln=Gd (1), Tb (2), Dy (3); 2,5-tdc=2,5-thiophenedicarboxylate and phen=1,10-phenanthroline) have been synthesized and characterized by X-ray single-crystal diffraction. Complexes 1~3 feature isostructural 2D structures. The luminescence properties of 1~3 were investigated. Under the excitation of 340 nm, the emission spectrum of complex 1 shows a broad band centre at 366 and 387 nm, which plausibly arises from ligand-centered π*-π transition within the ligands. Complex 2 displays green emission and shows four emission peaks at 491, 545, 588 and 620 nm, corresponding to 5D4→7FJ (J=6~3) transitions of Tb3+ under the excitation of 310 nm. The 5D4 emission decay curve reveals a monoexponential behavior with the lifetime value of (0.123±0.005) ms. The emission spectrum of complex 3 records two peaks of 482 and 575 nm, corresponding to the 4F5/2→6H15/2 and 4F5/2→6H13/2 transition of Dy3+, respectively, under the excitation of 330 nm. Moreover, the fluorescence sensing ability of complex 2 was investigated, revealing that it can be used as a fluorescence probe to detect Cu2+ in aqueous solution. CCDC:1036885, 1; 1036884, 2; 1036886, 3.
  • 加载中
    1. [1]

      [1] Maspoch D, Ruiz-Molinaa D, Veciana J. Chem. Soc. Rev., 2007,36(5):770-818

    2. [2]

      [2] Aulakh D, Pyser J B, Zhang X, et al. J. Am. Chem. Soc., 2015,137(29):9254-9257

    3. [3]

      [3] Bloch E D, Queen W L, Krishna R, et al. Science, 2012,335(6076):1606-1610

    4. [4]

      [4] Deng H X, Grunder S, Cordova K E, et al. Science, 2012, 336(6084):1018-1023

    5. [5]

      [5] Beyzavi M H, Vermeulen N A, Howarth A J, et al. J. Am. Chem. Soc., 2015,137(42):13624-13631

    6. [6]

      [6] Hu Z C, Deibert B J, Li J. Chem. Soc. Rev., 2014,43(16): 5815-5840

    7. [7]

      [7] LI Jia-Jia(李佳佳), SONG Shuang(宋爽), MA Dou(马豆), et al. Chinese J. Inorg. Chem(无机化学学报), 2015,31(4): 717-724

    8. [8]

      [8] Wang S J, Tian Y W, You L X, et al. Dalton Trans., 2014, 43(9):3462-3470

    9. [9]

      [9] MAO Pan-Dong(毛盼东), CHEN Liang(陈亮), WU Wei-Na (吴伟娜), et al. Chinese J. Inorg. Chem.(无机化学学报), 2015,31(2):336-342

    10. [10]

      [10] Sun Y G, Jiang B, Cui T F, et al. Dalton Trans., 2011,40(43):11581-11590

    11. [11]

      [11] Xu J, Cheng J W, Su W P, et al. Cryst. Growth Des., 2011,11(6):2294-2301

    12. [12]

      [12] Zhou L, Wang C G, Zheng X F, et al. Dalton Trans., 2013,42(46):16375-16386

    13. [13]

      [13] Ma D, Li X, Huo R. J. Mater. Chem. C, 2014,2(43):9073-9076

    14. [14]

      [14] Huo R, Li X, Ma D. CrystEngComm, 2015,17(20):3838-3844

    15. [15]

      [15] Hao J N, Yan B. Chem. Commun., 2015,51(77):14509-14512

    16. [16]

      [16] Hao J N, Yan B. J. Mater. Chem. A, 2015,3(9):4788-4792

    17. [17]

      [17] Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, Germany, 1997.

    18. [18]

      [18] Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Germany, 1997.

    19. [19]

      [19] Liu B, Hou L, Wu W P, et al. Dalton Trans., 2015,44(10), 4423-4427

  • 加载中
    1. [1]

      Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158

    2. [2]

      Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two LnⅢ3 complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188

    3. [3]

      Feng Lu ,  Tao Wang ,  Qi Wang . Preparation and Characterization of Water-Soluble Silver Nanoclusters: A New Design and Teaching Practice in Materials Chemistry Experiment. University Chemistry, 2025, 40(4): 375-381. doi: 10.12461/PKU.DXHX202406005

    4. [4]

      YanYuan Jia ,  Rong Rong ,  Jie Liu ,  Jing Guo ,  GuoYu Jiang ,  Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035

    5. [5]

      Qin Li ,  Kexin Yang ,  Qinglin Yang ,  Xiangjin Zhu ,  Xiaole Han ,  Tao Huang . Illuminating Chlorophyll: Innovative Chemistry Popularization Experiment. University Chemistry, 2024, 39(9): 359-368. doi: 10.3866/PKU.DXHX202309059

    6. [6]

      Zehua Zhang ,  Haitao Yu ,  Yanyu Qi . 多重共振TADF分子的设计策略. Acta Physico-Chimica Sinica, 2025, 41(1): 2309042-. doi: 10.3866/PKU.WHXB202309042

    7. [7]

      Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407

    8. [8]

      Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb2 complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357

    9. [9]

      Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114

    10. [10]

      Shiyi WANG , Chaolong CHEN , Xiangjian KONG , Lansun ZHENG , Lasheng LONG . Polynuclear lanthanide compound [Ce4ⅢCe6Ⅳ(μ3-O)4(μ4-O)4(acac)14(CH3O)6]·2CH3OH for the hydroboration of amides to amine. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 88-96. doi: 10.11862/CJIC.20240342

    11. [11]

      Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079

    12. [12]

      Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu3+ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355

    13. [13]

      Tianyun Chen ,  Ruilin Xiao ,  Xinsheng Gu ,  Yunyi Shao ,  Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017

    14. [14]

      Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368

    15. [15]

      Dongdong YANG , Jianhua XUE , Yuanyu YANG , Meixia WU , Yujia BAI , Zongxuan WANG , Qi MA . Design and synthesis of two coordination polymers for the rapid detection of ciprofloxacin based on triphenylpolycarboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2466-2474. doi: 10.11862/CJIC.20240266

    16. [16]

      Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139

    17. [17]

      Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192

    18. [18]

      Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304

    19. [19]

      Yongpo Zhang ,  Xinfeng Li ,  Yafei Song ,  Mengyao Sun ,  Congcong Yin ,  Chunyan Gao ,  Jinzhong Zhao . Synthesis of Chlorine-Bridged Binuclear Cu(I) Complexes Based on Conjugation-Driven Cu(II) Oxidized Secondary Amines. University Chemistry, 2024, 39(5): 44-51. doi: 10.3866/PKU.DXHX202309092

    20. [20]

      Lina Guo ,  Ruizhe Li ,  Chuang Sun ,  Xiaoli Luo ,  Yiqiu Shi ,  Hong Yuan ,  Shuxin Ouyang ,  Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al2O3催化剂光热催化CO2甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002

Get Citation
PDF
XML
Metrics
  • PDF Downloads(1)
  • Abstract views(291)
  • HTML views(13)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return