Citation: ZHAO Ming-Xia, XIONG Li-Qin, CAI Yong-Le, CHANG Jin, REN Hong-Yu, ZHANG Hua-Bei, QI Chuan-Min. Syntheses,Crystal Structures and Spectral Properties of Two Pd(Ⅱ)Complexes Containing Furan-3-one Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(11): 2017-2024. doi: 10.11862/CJIC.2016.220 shu

Syntheses,Crystal Structures and Spectral Properties of Two Pd(Ⅱ)Complexes Containing Furan-3-one Ligands

  • Corresponding author: QI Chuan-Min, 
  • Received Date: 9 January 2016
    Available Online: 8 August 2016

    Fund Project:

  • Two compounds, Pd(L1)2 (1) and Pd(L2)2 (2) (L1=(Z)-4-((p-toluidino)methylene)-2,2,5,5-tetramethyl-dihydrofuran-3(2H)-one, L2=(Z)-4-((o-toluidino)methylene)-2,2,5,5-tetramethyl-dihydrofuran-3(2H)-one)), have been synthesized and characterized by elemental analyses, IR spectra, 1H NMR spectra, UV-Vis spectral and single-crystal X-ray diffraction. The crystal structures of compounds are shown to contain a variety of weak interactions. In 1, the C-H…O interactions between the furan O atom and methyl H atom of phenyl ring bridge molecules forming an infinite chain along the c axis, which is interconnected via the weak C-H…H-C interactions and C-H…C interactions, giving rise to a 3D network. In 2, molecules are held together by weak C-H…H-C interactions and C-H…C interactions into a 2D layered framework. CCDC:289373, 1; 629001, 2.
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    1. [1]

      [1] Dethlefs K M, Hobza P. Chem. Rev., 2000,100(1):143-168

    2. [2]

      [2] GUO Hui-Rui(郭辉瑞), TAO Zhu(陶朱), ZHU Qian-Jiang(祝黔江), et al. Chinese J. Inorg. Chem.(无机化学学报), 2002, 18:435-441

    3. [3]

      [3] Aakeroy C B. Acta Crystallogr. B, 1997,53:569-586

    4. [4]

      [4] Guru Row T N. Coord. Chem. Rev., 1999,183:81-100

    5. [5]

      [5] Nangia A. J. Chem. Sci., 2010,122(3):295-310

    6. [6]

      [6] Jeffrey G A, Saenger W. Science, 1992,257:1774-1775

    7. [7]

      [7] Hunter C A. Chem. Soc. Rev., 1994,23:101-109

    8. [8]

      [8] Miao X H, Zhu L G. CrystEngComm, 2009,11:2500-2509

    9. [9]

      [9] TANG Li-Zhi-Peng(唐李志鹏), YANG Ming-Wei(杨明炜), CHENG Mei-Ling(程美令), et al. Chinese J. Inorg. Chem. (无机化学学报), 2015,31:603-610

    10. [10]

      [10] Yang G P, Hou L, Luan X J, et al. Chem. Soc. Rev., 2012, 41:6992-7000

    11. [11]

      [11] Hunter C A. Angew. Chem. Int. Ed. Engl., 1993,32:1584-1587

    12. [12]

      [12] LIU Xiu-Xiu(刘秀秀), CHENG Mei-Ling(程美令), REN Yan-Qiu(任艳秋), et al. Chinese J. Inorg. Chem.(无机化学学报), 2015,31:611-618

    13. [13]

      [13] Subramanian S, Zawarotko M J. Coord. Chem. Rev., 1994, 137(12):357-401

    14. [14]

      [14] Aakeroy C B, Nieuwenhuyzen M. J. Am. Chem. Soc., 1994, 116:10983-10991

    15. [15]

      [15] Weissbuch I, Popovitz-Biro R, Lahav M, et al. Acta Crystallogr. B, 1995,51(12):115-148

    16. [16]

      [16] Kadirvelraj R, Umarji A M, Robinson W T, et al. Chem. Mater., 1996,8(9):2313-2323

    17. [17]

      [17] Fuji K, Furuta T, Otsubo T, et al. Tetrahedron Lett., 1999, 40:3001-3004

    18. [18]

      [18] Dai C Y, Nguyen P, Marder T B, et al. Chem. Commun., 1999,24(24):2493-2494

    19. [19]

      [19] Coates G W, Dunn A R, Henling L M, et al. Angew. Chem. Int. Ed., 1997,36:248-251

    20. [20]

      [20] Crabtree R H. Science, 1998,282:2000-2001

    21. [21]

      [21] Crabtree R H, Siegbahn P E M, Eisenstein O, et al. Acc. Chem. Res., 1996,29:348-354

    22. [22]

      [22] Richardson T B, Gala S, Crabtree R H. J. Am. Chem. Soc., 1995,117:12875-12876

    23. [23]

      [23] Alkorta I, Rozas I, Elguero J. Chem. Soc. Rev., 1998,27:163-170

    24. [24]

      [24] Campbell J P, Hwang J W, Young V G, et al. J. Am. Chem. Soc., 1998,120(3):521-531

    25. [25]

      [25] Sini G, Eisenstein O, Yao W, et al. Inorg. Chim. Acta, 1998, 280:26-29

    26. [26]

      [26] Braga D, Leonardis P D, Grepioni F, et al. Inorg. Chem., 1998,37:3337-3348

    27. [27]

      [27] Klooster W T, Koetzle T F, Siegbahn P E M, et al. J. Am. Chem. Soc., 1999,121:6337-6343

    28. [28]

      [28] Wolstenholme D J, Cameron T S. J. Phys. Chem. A, 2006, 110:8970-8978

    29. [29]

      [29] Yilmaz V T, Degirmencioglu I, Andac O, et al. J. Mol. Struct., 2003,654:125-129

    30. [30]

      [30] Nimz O, Gessler K, Usón I, et al. Carbohydr. Res., 2004, 339:1427-1437

    31. [31]

      [31] Georg S F, Laurent P, Aline M F, et al. J. Organomet. Chem., 2000,609:196-203

    32. [32]

      [32] YU Zhen-Hua(于振华), YIN Cheng-Lie(尹承烈). Chem. J. Chinese Universities(高等学校化学学报), 1982,2:210-216

    33. [33]

      [33] Sheldrick G M. SHELXS-97 and SHELEXL-97, Program for the Solution and Refinement of Crystal Structures, University of Göttingen, Göttingen, Germany, 1997.

    34. [34]

      [34] Budzisz E, Keppler B K, Giester G, et al. Eur. J. Inorg. Chem., 2004,22:4412-4419

    35. [35]

      [35] Stromnova T A, Paschenko D V, Boganova L I, et al. Inorg. Chim. Acta, 2003,350:283-288

    36. [36]

      [36] Ma L, Smith R C, Protasiewicz J D. Inorg. Chim. Acta, 2005, 358:3478-3482

    37. [37]

      [37] Qin Z Q, Jennings M C, Puddephatt R J. Inorg. Chem., 2002,41:5174-5186

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