Citation: ZHAO Ming-Xia, XIONG Li-Qin, CAI Yong-Le, CHANG Jin, REN Hong-Yu, ZHANG Hua-Bei, QI Chuan-Min. Syntheses,Crystal Structures and Spectral Properties of Two Pd(Ⅱ)Complexes Containing Furan-3-one Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(11): 2017-2024. doi: 10.11862/CJIC.2016.220 shu

Syntheses,Crystal Structures and Spectral Properties of Two Pd(Ⅱ)Complexes Containing Furan-3-one Ligands

1.
1 Department of Mining Engineering, Shanxi Institute of Technology, Yangquan, Shanxi 045000, China;
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2 School of Biomedical Engineering, Shanghai Jiao Tong University, Shanghai 200025, China;
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3 Key Laboratory of Radiopharmaceuticals, Ministry of Education, College of Chemistry, Beijing Normal University, Beijing 100875, China

Corresponding author: QI Chuan-Min,
Received Date: 9 January 2016
Available Online: 8 August 2016
Fund Project:

Two compounds, Pd(L¹)₂ (1) and Pd(L²)₂ (2) (L¹=(Z)-4-((p-toluidino)methylene)-2,2,5,5-tetramethyl-dihydrofuran-3(2H)-one, L²=(Z)-4-((o-toluidino)methylene)-2,2,5,5-tetramethyl-dihydrofuran-3(2H)-one)), have been synthesized and characterized by elemental analyses, IR spectra, ¹H NMR spectra, UV-Vis spectral and single-crystal X-ray diffraction. The crystal structures of compounds are shown to contain a variety of weak interactions. In 1, the C-H…O interactions between the furan O atom and methyl H atom of phenyl ring bridge molecules forming an infinite chain along the c axis, which is interconnected via the weak C-H…H-C interactions and C-H…C interactions, giving rise to a 3D network. In 2, molecules are held together by weak C-H…H-C interactions and C-H…C interactions into a 2D layered framework. CCDC:289373, 1; 629001, 2.
- syntheses;Pd(Ⅱ);furan-3-one;crystal structure;weak interactionsntroduction
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