Citation: ZHAO Ming-Xia, XIONG Li-Qin, CAI Yong-Le, CHANG Jin, REN Hong-Yu, ZHANG Hua-Bei, QI Chuan-Min. Syntheses,Crystal Structures and Spectral Properties of Two Pd(Ⅱ)Complexes Containing Furan-3-one Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(11): 2017-2024. doi: 10.11862/CJIC.2016.220
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Two compounds, Pd(L1)2 (1) and Pd(L2)2 (2) (L1=(Z)-4-((p-toluidino)methylene)-2,2,5,5-tetramethyl-dihydrofuran-3(2H)-one, L2=(Z)-4-((o-toluidino)methylene)-2,2,5,5-tetramethyl-dihydrofuran-3(2H)-one)), have been synthesized and characterized by elemental analyses, IR spectra, 1H NMR spectra, UV-Vis spectral and single-crystal X-ray diffraction. The crystal structures of compounds are shown to contain a variety of weak interactions. In 1, the C-H…O interactions between the furan O atom and methyl H atom of phenyl ring bridge molecules forming an infinite chain along the c axis, which is interconnected via the weak C-H…H-C interactions and C-H…C interactions, giving rise to a 3D network. In 2, molecules are held together by weak C-H…H-C interactions and C-H…C interactions into a 2D layered framework. CCDC:289373, 1; 629001, 2.
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