Citation: ZOU Xiao-Yan, MA Hui-Yuan, PANG Hai-Jun, ZHANG Feng-Ming, LI Guang-Ming. Crystal Structures and Luminescent Properties of Salen-Type and β-Diketonate Lanthanide Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(9): 1647-1652. doi: 10.11862/CJIC.2016.217 shu

Crystal Structures and Luminescent Properties of Salen-Type and β-Diketonate Lanthanide Complexes

1.
College of Chemical and Environmental Engineering, Harbin University of Science and Technology, Harbin 150080, China
2.
School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China

Corresponding author: MA Hui-Yuan, mahy017@163.com LI Guang-Ming, gmli_2000@163.com
Received Date: 3 June 2016
Revised Date: 5 August 2016

Figures(5)

Two dinuclear lanthanide complexes [Ln₂L(acac)₄(CH₃OH)]₂·2CH₂Cl₂ (Ln=Ce (1), Eu (2)) prepared by salen-type (H₂L=N, N'-bis(2-oxy-3-methoxybenzylidene)-1,2-phenylenediamine) ligand and Ln(acac)₃·H₂O (acac=acetylacetonate) were structurally characterized. X-ray crystallographic analysis reveals that the two Ln(Ⅲ) ions adopt same coordination environments that octa-coordinated Ln(Ⅲ) atoms form square antiprism geometry. Luminescent analysis reveals the Eu(Ⅲ) ion and ligand-centered co-luminescence for complex 2, which is attributed to the incomplete energy transfer from the triplet state of H₂L to the resonance energy level of the corresponding Eu(Ⅲ) ion. CCDC: 1482355, 1; 1449142, 2.
- N, N'-bis(2-oxy-3-methoxybenzylidene)-1,2-phenylenediamine,
- β-diketonate,
- lanthanide complexes,
- coordination
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沈阳化工大学材料科学与工程学院沈阳 110142