Citation: LI Jun, WANG Lu-Xiang, CAO Ya-Li, JIA Dian-Zeng. Single Adsorption Capacity of Methylene Blue on ZnO/C Nanosphere:Equilibrium, Kinetics and Mechanism[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(9): 1603-1610. doi: 10.11862/CJIC.2016.213 shu

Single Adsorption Capacity of Methylene Blue on ZnO/C Nanosphere:Equilibrium, Kinetics and Mechanism

Key Laboratory of Energy Materials Chemistry, Ministry of Education, Key Laboratory of Advanced Functional Materials, Autonomous Region, Institute of Applied Chemistry, Xinjiang University, Urumqi 830046, China

Corresponding author: JIA Dian-Zeng, jdz@xju.edu.cn
Received Date: 30 March 2016
Revised Date: 24 August 2016

Figures(7)

Carbon-inorganic ZnO/C nanosphere hybrid materials was simply prepared by arc discharge method. The hybrid materials was characterized by field-emission scanning electron microscopy(FE-SEM), X-ray diffraction(XRD) and BET surface area. The adsorption property of methylene blue (MB) on ZnO/C nanosphere was carried out under the dark conditions. Results showed that the adsorption uptake increased as the increase of initial MB concentration and contact time, and the process reached equilibrium at the time of 150 min. Langmuir, Freundlich and Temkin isotherm were employed to describe the adsorption equilibrium. The isotherm study indicated that Langmuir model fitted well with the adsorption data, and a monolayer saturation capacity of 188.68 mg·g^-1 was obtained. Kinetic models, Webbers pore diffusion model and Boyds equation were applied for the experimental data to study the adsorption mechanism. Results shows that the kinetics followed the pseudo-second order kinetic model and the adsorption process was controlled by film diffusion as opposed intraparticle diffusion mechanism. The results indicate that the ZnO/C nanosphere is also a promising material for the adsorption of MB from aqueous solutions.
- ZnO/C nanosphere,
- carbon,
- nanomaterials,
- methylene blue,
- isotherm,
- kinetics
1. [1]
  Djilani C, Zaghdoudi R, Djazi F, et al. J. Taiwan Inst. Chem. E, 2015, 53:112-121 doi: 10.1016/j.jtice.2015.02.025
2. [2]
  Lin C H, Gung C H, Wu J Y, et al. J. Taiwan Inst. Chem. E, 2015, 51:119-126 doi: 10.1016/j.jtice.2015.01.019
3. [3]
  Islam M A, Benhouria A, Asif M, et al. J. Taiwan Inst. Chem. E, 2015, 52:57-64 doi: 10.1016/j.jtice.2015.02.010
4. [4]
  Jain A, Gupta V, Bhatnagar A. J. Hazard. Mater., 2003, 101: 31-42 doi: 10.1016/S0304-3894(03)00146-8
5. [5]
  Liu X, Niu C, Zhen X, et al. J. Colloid Interface Sci., 2015, 452:116-125 doi: 10.1016/j.jcis.2015.04.037
6. [6]
  LIU Jing-Liang, ZONG En-Min, CHEN Huan, et al. Chinese J. Inorg. Chem., 2015, 31(6):1105-1111
7. [7]
  Hameed B, El-Khaiary M. J. Hazard. Mater., 2008, 157:344-351 doi: 10.1016/j.jhazmat.2007.12.105
8. [8]
  Ahmad M A, Rahman N K. Chem. Eng. J., 2011, 170:154-161 doi: 10.1016/j.cej.2011.03.045
9. [9]
  LIU Hai-Di, LI Wei-Man, YUE Ren-Liang, et al. Chinese J. Inorg. Chem., 2013, 29:1787-1792
10. [10]
  Wang L, Zhang J, Zhao R, et al. Desalination, 2010, 254:68-74 doi: 10.1016/j.desal.2009.12.012
11. [11]
  Vargas A M, Cazetta A L, Kunita M H, et al. Chem. Eng. J., 2011, 170:154-161 doi: 10.1016/j.cej.2011.03.045
12. [12]
  Cherifi H, Fatiha B, Salah H. Appl. Surf. Sci., 2013, 282:52 -59 doi: 10.1016/j.apsusc.2013.05.031
13. [13]
  Vadivelan V, Kumar K V. J. Colloid Interface Sci., 2005, 286: 90-100 doi: 10.1016/j.jcis.2005.01.007
14. [14]
  Aboua K N, Yobouet Y A, Yao K B, et al. J. Environ. Manage., 2015, 156:10-14 doi: 10.1016/j.jenvman.2015.03.006
15. [15]
  Mezohegyi G, Van der Zee F P, Font J, et al. J. Environ. Manage., 2012, 102:148-164 doi: 10.1016/j.jenvman.2012.02.021
16. [16]
  Yin Y, Zhou S, Min C, et al. J. Colloid Interface Sci., 2011, 361:527-533 doi: 10.1016/j.jcis.2011.05.014
17. [17]
  Zhai Y, Dou Y, Liu X, et al. J. Mater. Chem., 2009, 19: 3292-3300 doi: 10.1039/b821945a
18. [18]
  Feng Y, Yang W, Wang N, et al. J. Anal. Appl. Pyrolysis, 2014, 107:204-210 doi: 10.1016/j.jaap.2014.02.021
19. [19]
  Dubey S P, Dwivedi A D, Kim I C, et al. Chem. Eng. J., 2014, 244:160-167 doi: 10.1016/j.cej.2014.01.042
20. [20]
  Liu S, Sun J, Huang Z. J. Hazard. Mater., 2010, 173:377-383 doi: 10.1016/j.jhazmat.2009.08.086
21. [21]
  Eder D, Windle A H. Adv. Mater., 2008, 20:1787-1793 doi: 10.1002/(ISSN)1521-4095
22. [22]
  Bu Q, Lei H, Wang L, et al. J. Anal. Appl. Pyrolysis, 2015, 112:74-79 doi: 10.1016/j.jaap.2015.02.019
23. [23]
  Velazquez-Jimenez L H, Hurt R H, Matos J, et al. Environ. Sci. Technol., 2013, 48:1166-1174
24. [24]
  Ahmad M, Ahmed E, Hong Z L, et al. Appl. Surf. Sci., 2013, 274:273-281 doi: 10.1016/j.apsusc.2013.03.035
25. [25]
  Zhou M, Gao X, Hu Y, et al. Appl. Catal. B, 2013, 138:1-8
26. [26]
  Li J, NgD H L, Song P, et al. Mater. Sci. Eng. B, 2015, 194: 1-8 doi: 10.1016/j.mseb.2014.12.007
27. [27]
  Le H A, Linh L T, Chin S, et al. Powder Technol., 2012, 225:167-175 doi: 10.1016/j.powtec.2012.04.004
28. [28]
  Murgolo S, Petronella F, Ciannarella R, et al. Catal. Today, 2015, 240:114-124 doi: 10.1016/j.cattod.2014.04.021
29. [29]
  Matos J, Montaña R, Rivero E. Environ. Sci. Pollut. Res., 2015, 22:784-791 doi: 10.1007/s11356-014-2832-9
30. [30]
  Langmuir I. J. Am. Chem. Soc., 1916, 38:2221-2295 doi: 10.1021/ja02268a002
31. [31]
  Freundlich H M F. J. Phys. Chem., 1906, 57:1100-1107
32. [32]
  Temkin M, Pyzhev V. Acta Physiochim. URSS, 1940, 12:217-222
33. [33]
  Weber T W. Chakravorti R K. AIChE J., 1974, 20:228-238 doi: 10.1002/aic.v20:2
34. [34]
  Kumar K V. J. Hazard. Mater., 2006, 137:1538-1544 doi: 10.1016/j.jhazmat.2006.04.036
35. [35]
  Ho Y S, McKay G. Chem. Eng. J., 1998, 70:115-124 doi: 10.1016/S0923-0467(98)00076-1
36. [36]
  Weber W J, Morris J C. AmSocCivEng, 1963, 89:31-60
37. [37]
  Goswami M, Borah L, Mahanta D, et al. J. Porous Mater., 2014, 21:1025-1034 doi: 10.1007/s10934-014-9852-1
38. [38]
  Hameed B, Ahmad A, Aziz N. Desalination, 2009, 247:551-560 doi: 10.1016/j.desal.2008.08.005
39. [39]
  Xiao H, Peng H, Deng S, et al. Bioresour. Technol., 2012, 111:127-133 doi: 10.1016/j.biortech.2012.02.054
40. [40]
  Zhong Z Y, Yang Q, Li X M, et al. Ind. Crops Prod., 2012, 37:178-185 doi: 10.1016/j.indcrop.2011.12.015
41. [41]
  Tan I A W, Ahmad A L, Hameed B H. J. Hazard. Mater., 2009, 164:473-482 doi: 10.1016/j.jhazmat.2008.08.025
42. [42]
  Acharya J, Sahu J, Sahoo B, et al. Chem. Eng. J., 2009, 150: 25-39 doi: 10.1016/j.cej.2008.11.035
1. [1]
  Jing JIN , Zhuming GUO , Zhiyin XIAO , Xiujuan JIANG , Yi HE , Xiaoming LIU . Tuning the stability and cytotoxicity of fac-[Fe(CO)₃I₃]^- anion by its counter ions: From aminiums to inorganic cations. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 991-1004. doi: 10.11862/CJIC.20230458
2. [2]
  Yi Zhang , Biao Wang , Chao Hu , Muhammad Humayun , Yaping Huang , Yulin Cao , Mosaad Negem , Yigang Ding , Chundong Wang . Fe–Ni–F electrocatalyst for enhancing reaction kinetics of water oxidation. Chinese Journal of Structural Chemistry, 2024, 43(2): 100243-100243. doi: 10.1016/j.cjsc.2024.100243
3. [3]
  Ningxiang Wu , Huaping Zhao , Yong Lei . Nanomaterials with highly ordered nanostructures: Definition, influence and future challenge. Chinese Journal of Structural Chemistry, 2024, 43(11): 100392-100392. doi: 10.1016/j.cjsc.2024.100392
4. [4]
  Yihao Zhang , Yang Jiao , Xianchao Jia , Qiaojia Guo , Chunying Duan . Highly effective self-assembled porphyrin MOCs nanomaterials for enhanced photodynamic therapy in tumor. Chinese Chemical Letters, 2024, 35(5): 108748-. doi: 10.1016/j.cclet.2023.108748
5. [5]
  Di Wang , Qing-Song Chen , Yi-Ran Lin , Yun-Xin Hou , Wei Han , Juan Yang , Xin Li , Zhen-Hai Wen . Tuning strategies and electrolyzer design for Bi-based nanomaterials towards efficient CO2 reduction to formic acid. Chinese Journal of Structural Chemistry, 2024, 43(8): 100346-100346. doi: 10.1016/j.cjsc.2024.100346
6. [6]
  Yue Zhang , Xiaoya Fan , Xun He , Tingyu Yan , Yongchao Yao , Dongdong Zheng , Jingxiang Zhao , Qinghai Cai , Qian Liu , Luming Li , Wei Chu , Shengjun Sun , Xuping Sun . Ambient electrosynthesis of urea from carbon dioxide and nitrate over Mo₂C nanosheet. Chinese Chemical Letters, 2024, 35(8): 109806-. doi: 10.1016/j.cclet.2024.109806
7. [7]
  Yi Herng Chan , Zhe Phak Chan , Serene Sow Mun Lock , Chung Loong Yiin , Shin Ying Foong , Mee Kee Wong , Muhammad Anwar Ishak , Ven Chian Quek , Shengbo Ge , Su Shiung Lam . Thermal pyrolysis conversion of methane to hydrogen (H₂): A review on process parameters, reaction kinetics and techno-economic analysis. Chinese Chemical Letters, 2024, 35(8): 109329-. doi: 10.1016/j.cclet.2023.109329
8. [8]
  Daheng Wen , Weiwei Fang , Yongmei Liu , Tao Tu . Valorization of carbon dioxide with alcohols. Chinese Chemical Letters, 2024, 35(7): 109394-. doi: 10.1016/j.cclet.2023.109394
9. [9]
  Heng Yang , Zhijie Zhou , Conghui Tang , Feng Chen . Recent advances in heterogeneous hydrosilylation of unsaturated carbon-carbon bonds. Chinese Chemical Letters, 2024, 35(6): 109257-. doi: 10.1016/j.cclet.2023.109257
10. [10]
  Kang Wei , Jiayu Li , Wen Zhang , Bing Yuan , Ming-De Li , Pingwu Du . A strained π-extended [10]cycloparaphenylene carbon nanoring. Chinese Chemical Letters, 2024, 35(5): 109055-. doi: 10.1016/j.cclet.2023.109055
11. [11]
  Wenda WANG , Jinku MA , Yuzhu WEI , Shuaishuai MA . Waste biomass-derived carbon modified porous graphite carbon nitride heterojunction for efficient photodegradation of oxytetracycline in seawater. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 809-822. doi: 10.11862/CJIC.20230353
12. [12]
  Hui Liu , Xiangyang Tang , Zhuang Cheng , Yin Hu , Yan Yan , Yangze Xu , Zihan Su , Futong Liu , Ping Lu . Constructing multifunctional deep-blue emitters with weak charge transfer excited state for high-performance non-doped blue OLEDs and single-emissive-layer hybrid white OLEDs. Chinese Chemical Letters, 2024, 35(10): 109809-. doi: 10.1016/j.cclet.2024.109809
13. [13]
  Jiayu Xu , Meng Li , Baoxia Dong , Ligang Feng . Fully fluorinated hybrid zeolite imidazole/Prussian blue analogs with combined advantages for efficient oxygen evolution reaction. Chinese Chemical Letters, 2024, 35(6): 108798-. doi: 10.1016/j.cclet.2023.108798
14. [14]
  Pingping Wang , Huixian Miao , Kechuan Sheng , Bin Wang , Fan Feng , Xuankun Cai , Wei Huang , Dayu Wu . Efficient blue-light-excitable copper(Ⅰ) coordination network phosphors for high-performance white LEDs. Chinese Chemical Letters, 2024, 35(4): 108600-. doi: 10.1016/j.cclet.2023.108600
15. [15]
  Rui PAN , Yuting MENG , Ruigang XIE , Daixiang CHEN , Jiefa SHEN , Shenghu YAN , Jianwu LIU , Yue ZHANG . Selective electrocatalytic reduction of Sn(Ⅳ) by carbon nitrogen materials prepared with different precursors. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1015-1024. doi: 10.11862/CJIC.20230433
16. [16]
  Yue WANG , Zhizhi GU , Jingyi DONG , Jie ZHU , Cunguang LIU , Guohan LI , Meichen LU , Jian HAN , Shengnan CAO , Wei WANG . Effects of kelp-derived carbon dots on embryonic development of zebrafish. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1209-1217. doi: 10.11862/CJIC.20230423
17. [17]
  Uttam Pandurang Patil . Porous carbon catalysis in sustainable synthesis of functional heterocycles: An overview. Chinese Chemical Letters, 2024, 35(8): 109472-. doi: 10.1016/j.cclet.2023.109472
18. [18]
  Pei Cao , Yilan Wang , Lejian Yu , Miao Wang , Liming Zhao , Xu Hou . Dynamic asymmetric mechanical responsive carbon nanotube fiber for ionic logic gate. Chinese Chemical Letters, 2024, 35(6): 109421-. doi: 10.1016/j.cclet.2023.109421
19. [19]
  Qiang Fu , Shouhong Sun , Kangzhi Lu , Ning Li , Zhanhua Dong . Boron-doped carbon dots: Doping strategies, performance effects, and applications. Chinese Chemical Letters, 2024, 35(7): 109136-. doi: 10.1016/j.cclet.2023.109136
20. [20]
  Yuan Dong , Mutian Ma , Zhenyang Jiao , Sheng Han , Likun Xiong , Zhao Deng , Yang Peng . Effect of electrolyte cation-mediated mechanism on electrocatalytic carbon dioxide reduction. Chinese Chemical Letters, 2024, 35(7): 109049-. doi: 10.1016/j.cclet.2023.109049

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(558)
HTML views(87)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142