Citation: JIAO Cheng-Qi, JIANG Wen-Jing, Wen WEN, REN Yi, WANG Jia-Liang, LIU Tao, HE Cheng. Tuning Assembly and Magnetic Interactions of Cyano-bridged Fe(Ⅲ)-Mn(Ⅱ) Bimetallic Chains[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(9): 1637-1646. doi: 10.11862/CJIC.2016.210 shu

Tuning Assembly and Magnetic Interactions of Cyano-bridged Fe(Ⅲ)-Mn(Ⅱ) Bimetallic Chains

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: LIU Tao, liutao@dlut.edu.cn
Received Date: 25 May 2016
Revised Date: 4 August 2016

Figures(7)

Two cyano-bridged Fe(Ⅲ)-Mn(Ⅱ) chains were synthesized via using bidentate ligands and cyanometallate building blocks with different steric hindrance. The magnetic interactions were adjusted by the structural distortions of the two compounds. Compound {[Fe(Ⅲ)(PzTp)(CN)₃][Mn(Ⅱ)(5,5′-dmbpy)₂]ClO₄}_n (1; PzTp=tetrakis(pyrazolyl)borate; 5,5′-dmbpy=5,5′-dimethyl-2, 2′-bipyridine) shows a 1D 2, 2-CC chain-like structure with a left-and right-handed helices chains and exhibits the ferrimagnetic behavior. Compound {[Fe(Ⅲ)(Tp^*)(CN)₃]₂[Mn(Ⅱ)(dpqc)]·CH₃OH·H₂O}_n (2; Tp^*=hydridotris(3, 5-dimethylpyrazolyl)borate; dpqc=dipyrido[3, 2-a:2′, 3′-c]-(6, 7, 8, 9-tetrahydro)phenazine) has a novel 1D 4, 2-ribbon double chain-like structure with dominant antiferromagnetic interactions. CCDC: 1449127, 1; 1449128, 2.
- cyano-bridged,
- chain,
- ferrimagnetic,
- antiferromagnetic
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