Citation: HUANG Chao, ZHANG Wen-Long, CHEN Dong-Mei, ZHANG Qi-Long, ZHU Bi-Xue. Syntheses and Crystal Structures of Hg(Ⅱ) Complexes with Hydrazone Schiff Base[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(9): 1579-1584. doi: 10.11862/CJIC.2016.202 shu

Syntheses and Crystal Structures of Hg(Ⅱ) Complexes with Hydrazone Schiff Base

1.
Key laboratory of Macrocycle and Supramolecular Chemistry, Guizhou University, Guiyang 550025, China
2.
Department of Chemistry, Guizhou Medical College, Guiyang 550004, China

Corresponding author: ZHU Bi-Xue, bxzhu@gzu.edu.cn
Received Date: 17 May 2016
Revised Date: 26 July 2016

Figures(4)

Two complexes {[Hg(L¹)Cl₂]·CH₃OH}_n (1) and [Hg(L²)Cl₂]_n (2) were synthesized from the reaction of Schiff base ligand 3-acetylpyridine-o-aminobenzoylhydrazone (L¹) and ligand 4-acetylpyridine-o-aminobenzoylhy-drazone (L²) with HgCl₂, respectively. The compounds are characterized by ¹H NMR, FTIR, and elemental analysis, and their structures are measured via single crystal X-ray diffraction. The results show that the complex 1 crystallize in triclinic system, space group P1; the complex 2 crystallize in monoclinic system, space group P2₁/_n. Further the thermal stabilities of the two complexes were investigated. CCDC: 1496029, 1; 1496028, 2.
- Schiff base,
- Hg(Ⅱ) complex,
- crystal structure
1. [1]
  Seth P, Ghosh S, Figuerola A, et al. Dalton Trans., 2014, 43: 990-998 doi: 10.1039/C3DT52012A
2. [2]
  Tayyebi Sabet Khomami N, Heshmatpour F, Neumüller B. Inorg. Chem. Commun., 2014, 41:14-18 doi: 10.1016/j.inoche.2013.12.011
3. [3]
  Kalita M, Gogoi P, Barman P. Polyhedron, 2014, 74:93-98 doi: 10.1016/j.poly.2014.02.043
4. [4]
  Pitt M A, Johnson D W. Chem. Soc. Rev., 2007, 36:1441-1453 doi: 10.1039/b610405n
5. [5]
  Guzmán-Percástegui E, Zakharov L N, Alvarado-Rodríguez J G, et al. Cryst. Growth Des., 2014, 14:2087-2091 doi: 10.1021/cg401894h
6. [6]
  Beheshti A, Lalegani A, Behvandi F, et al. J. Mol. Struct., 2015, 1082:143-150 doi: 10.1016/j.molstruc.2014.11.008
7. [7]
  Jones C D, Tan J C, Lloyd G O. Chem. Commun., 2012, 48: 2110-2112 doi: 10.1039/c2cc16691g
8. [8]
  Baul T S B, Kundu S, Mitra S, et al. Dalton Trans., 2013, 42: 1905-1920 doi: 10.1039/C2DT32283H
9. [9]
  Khavasi H R, Tahrani A A. CrystEngComm, 2013, 15:5799-5812 doi: 10.1039/c3ce40433a
10. [10]
  Khavasi H R, Sadegh B M M. Dalton Trans., 2015, 44:5488-5502 doi: 10.1039/C4DT03518F
11. [11]
  Chang H Q, Jia L, Xu J, et al. Inorg. Chem. Commun., 2015, 57:8-10 doi: 10.1016/j.inoche.2015.04.010
12. [12]
  Wang J L, Zhao Y Q, Yang B S. Inorg. Chim. Acta, 2014, 409:484-496 doi: 10.1016/j.ica.2013.09.001
13. [13]
  LI Xiao-Jing, WU Wei-Na, XU Zhou-Qing, et al. Chinese J. Inorg. Chem., 2015, 31(11):2265-2271
14. [14]
  Radunsky C, Kösters J, Müller J. Inorg. Chim. Acta, 2015, 428:14-20 doi: 10.1016/j.ica.2015.01.012
15. [15]
  HAN Xue-Feng, CAI Hong Xin, JIA Lei, et al. Chinese J. Inorg. Chem., 2015, 31(7):1453-1459
16. [16]
  HUANG Chao, WU Juan, CHEN Dong-Mei, et al. Chinese J. Inorg. Chem., 2015, 31(1):109-113
17. [17]
  Sheldrick G M. SHELXL-97, Program for X-ray Crystal Structure Solution and Refinement, University of Göttingen, Germany, 1997.
1. [1]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
2. [2]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
3. [3]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
4. [4]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
5. [5]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
6. [6]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
7. [7]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
8. [8]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
9. [9]
  Xiaotong LU , Pan ZHANG , Zijie ZHAO , Lei HUANG , Hongwei ZUO , Lili LIANG . Antitumor and antibacterial activities of pyridyl Schiff base indium and dysprosium complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1523-1532. doi: 10.11862/CJIC.20250073
10. [10]
  Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two Sm^Ⅲ₄ complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258
11. [11]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
12. [12]
  Jia JI , Tengqi YAO , Wenqian DENG , Wenjing SHI , Xuan LÜ , Lin TIAN , Xiaoyan XIN , Yinling HOU . Structures, antibacterial activities, and interactions with DNA of two nickel complexes. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 78-86. doi: 10.11862/CJIC.20250141
13. [13]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
14. [14]
  Lifang HE , Wenjie TANG , Yaoze LUO , Mingsheng LIANG , Jianxin TANG , Yuxuan WU , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two dialkyltin complexes constructed based on 2, 2′-bipyridin-6, 6′-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1601-1609. doi: 10.11862/CJIC.20250012
15. [15]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
16. [16]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
17. [17]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
18. [18]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
19. [19]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
20. [20]
  Xiaoqi LAN , Wei LI , Long JING , Mengyu SU , Xiaoling LUO , Zheng LIU , Qun TANG . Synthesis, crystal structure, and spectral properties of transition-metal-organic frameworks based on thiophene carboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 309-316. doi: 10.11862/CJIC.20250212

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(907)
HTML views(83)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142