Citation: HUANG Chao, ZHANG Wen-Long, CHEN Dong-Mei, ZHANG Qi-Long, ZHU Bi-Xue. Syntheses and Crystal Structures of Hg(Ⅱ) Complexes with Hydrazone Schiff Base[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(9): 1579-1584. doi: 10.11862/CJIC.2016.202 shu

Syntheses and Crystal Structures of Hg(Ⅱ) Complexes with Hydrazone Schiff Base

1.
Key laboratory of Macrocycle and Supramolecular Chemistry, Guizhou University, Guiyang 550025, China
2.
Department of Chemistry, Guizhou Medical College, Guiyang 550004, China

Corresponding author: ZHU Bi-Xue, bxzhu@gzu.edu.cn
Received Date: 17 May 2016
Revised Date: 26 July 2016

Figures(4)

Two complexes {[Hg(L¹)Cl₂]·CH₃OH}_n (1) and [Hg(L²)Cl₂]_n (2) were synthesized from the reaction of Schiff base ligand 3-acetylpyridine-o-aminobenzoylhydrazone (L¹) and ligand 4-acetylpyridine-o-aminobenzoylhy-drazone (L²) with HgCl₂, respectively. The compounds are characterized by ¹H NMR, FTIR, and elemental analysis, and their structures are measured via single crystal X-ray diffraction. The results show that the complex 1 crystallize in triclinic system, space group P1; the complex 2 crystallize in monoclinic system, space group P2₁/_n. Further the thermal stabilities of the two complexes were investigated. CCDC: 1496029, 1; 1496028, 2.
- Schiff base,
- Hg(Ⅱ) complex,
- crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142