Citation: WU Xiao-Shuo, WANG Peng-Fei, LU Peng-Peng, XU Si-Yuan. Three Transition Metal Coordination Complexes Based on the Substituted Benzenecarboxylic Acid and Flexible N-donor Co-ligands: Syntheses, Crystal Structures, and Physical Properties[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(9): 1667-1675. doi: 10.11862/CJIC.2016.191 shu

Three Transition Metal Coordination Complexes Based on the Substituted Benzenecarboxylic Acid and Flexible N-donor Co-ligands: Syntheses, Crystal Structures, and Physical Properties

School of Chemistry and Material Engineering, Chizhou College, Chizhou, Anhui 247000, China

Corresponding author: WANG Peng-Fei, njuwangpf@163.com
Received Date: 9 May 2016
Revised Date: 21 June 2016

Figures(8)

The hydrothermal reactions of 3,5-dinitrobenzoic acid (3,5-DNBH), 1,2-bis(imidazol-1-ylmethyl)benzene (1,2-bimb) and transition metal salts result in three new transition metal coordination complexes, namely, [M(3,5-DNB)₂(1,2-bimb)] (M=Co(Ⅱ) (1), Cd(Ⅱ) (3)) and [Zn(3,5-DNB)₂(1,2-bimb)]_n (2). These complexes were characterized by IR spectra, elemental analyses, single-crystal and powder X-ray diffraction analyses. Complexes 1 and 3 are isostructural and contain a dinuclear [M₂(COO)₂] (M=Co(Ⅱ) (1), Cd(Ⅱ) (3)) unit made up of metal ions, 3,5-DNB-and 1,2-bimb ligands, which further form the supramolecular structures by the O…π interactions between the nitro group oxygen atom of 3,5-DNB^- anions and the benzene ring of 1,2-bimb molecules. Complex 2 features a 1D chain structure, which further packs to the supramolecular structure by the π…π interactions between the benzene rings from the 3,5-DNB^- anions. The fluorescence properties of the dispersion methanol solution of complexes 2 and 3 have been investigated at room temperature. Relatively high thermal stabilities are found in the three complexes according to the TGA curves. Photocatalytic studies of 1 indicate good degradation ability over rhodamine B (RhB) under visible light irradiation. Furthermore, the dc magnetic susceptibility measurement of 1 reveals that dominant antiferromagnetic interactions are propagated between the Co(Ⅱ) ions in 1. CCDC: 1476334, 1; 1476335, 2; 1476336, 3.
- transition metal complexes,
- magnetic property,
- photocatalytic activity
1. [1]
  Halder R, Matsuda R, Kitagawa S, et al. Angew. Chem., Int. Ed., 2014, 53:11772-11777 doi: 10.1002/anie.201405619
2. [2]
  Cui Y, Yue Y, Chen B L, et al. Chem. Rev., 2012, 112:1126-1162 doi: 10.1021/cr200101d
3. [3]
  Wang C, Liu D, Lin W B, et al. J. Am. Chem. Soc., 2013, 135: 13222-13234 doi: 10.1021/ja308229p
4. [4]
  Wen T, Zhang D X, Zhang J. Inorg. Chem., 2013, 52:12-14 doi: 10.1021/ic302273h
5. [5]
  Zhao S S, Yang J, Ma J F, et al. Inorg. Chem., 2016, 55: 2261-2273 doi: 10.1021/acs.inorgchem.5b02666
6. [6]
  Sarma D, Natarajan S, Drillon M, et al. Inorg. Chem., 2012, 51: 4495-4501 doi: 10.1021/ic2020989
7. [7]
  Tahmasebi E, Masoomi M Y, Morsali A, et al. Inorg. Chem., 2015, 54:425-433 doi: 10.1021/ic5015384
8. [8]
  Khan N A, Jun J W, Jeong J H, et al. Chem. Commun., 2011, 47:1306-1308 doi: 10.1039/C0CC04759G
9. [9]
  Lü L L, Yang J, Ma J F. Inorg. Chem., 2015, 54:1744-1755 doi: 10.1021/ic502686b
10. [10]
  Gong Y N, He C T, Lu T B, et al. Chem. Sci., 2016, 7:1070-1075 doi: 10.1039/C5SC02679B
11. [11]
  Wang C C, Jing H P, Zhang Y Q, et al. Transition Met. Chem., 2015, 40:573-584 doi: 10.1007/s11243-015-9950-1
12. [12]
  Zhang T, Lin W B. Chem. Soc. Rev., 2014, 43:5982-5993 doi: 10.1039/C4CS00103F
13. [13]
  Wen L L, Zhao J B, Li D F, et al. Cryst. Growth Des., 2012, 12:1603-1612 doi: 10.1021/cg2016512
14. [14]
  Wang C C, Li J R, Guo G S, et al. Energy Environ. Sci., 2014, 7:2831-2867 doi: 10.1039/C4EE01299B
15. [15]
  Shen L J, Liang S J, Wu W M, et al. Dalton Trans., 2013, 42:13649-13657 doi: 10.1039/c3dt51479j
16. [16]
  Shen L J, Wu W M, Liang R W, et al. Nanoscale, 2013, 5: 9374-9382 doi: 10.1039/c3nr03153e
17. [17]
  HU Chun-Yan, XIAO Wei, YUAN Hou-Qun, et al. Chinese J. Inorg. Chem., 2014, 30(2):257-263
18. [18]
  NIE Xue, CHEN Man-Sheng, YU Jiang-Xi, et al. Chinese J. Inorg. Chem., 2013, 29(12):2704-2708
19. [19]
  Jin S W, Huang Y F, Wang D Q, et al. Polyhedron, 2013, 60:10-22 doi: 10.1016/j.poly.2013.04.056
20. [20]
  Kaur Jassal A, Sharma S, Hundal G, et al. Cryst. Growth Des., 2015, 15:79-93 doi: 10.1021/cg500883w
21. [21]
  Hoskins B F, Robson R, Slizys D A. J. Am. Chem. Soc., 1997, 119:2952-2953 doi: 10.1021/ja9642626
22. [22]
  SAINT, Program for Data Extraction and Reduction, Siemens Analytical X-ray Instruments, Madison, WI, 1994-1996.
23. [23]
  Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, Göttingen, Germany, 1997.
24. [24]
  Sheldrick G M. SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Göttingen, Germany, 1997.
25. [25]
  Janiak C. J. Chem. Soc., Dalton Trans., 2000:3885-3896
26. [26]
  Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. 6th Ed. New Jersey: Wiley, 2009: 64-67
27. [27]
  Wang P F, Duan Y, Zheng L M, et al. Dalton Trans., 2010, 39: 4559-4565 doi: 10.1039/b927100g
28. [28]
  Allendorf M D, Bauer C A, Houk R J T, et al. Chem. Soc. Rev., 2009, 38:1330-1352 doi: 10.1039/b802352m
29. [29]
  Kahn O. Molecular Magnetism. New York: VCH Publishers, 1993:38-39
30. [30]
  Carling C L, Translated by WAN Chun-Di(万纯娣), ZANG Yan(臧焰), HU Yong-Zhu(胡永珠), et al. Magnetochemistry(磁化学). Nanjing: Nanjing University Press, 1990: 33-35
31. [31]
  Fabelo O, Pasán J, Ruiz-Pérez C, et al. Inorg. Chem., 2009, 48:6086-6095 doi: 10.1021/ic9004483
32. [32]
  Díaz-Gallifa P, Fabelo O, Ruiz-Pérez C. Inorg. Chem., 2014, 53:5674-5683 doi: 10.1021/ic500443t
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