Citation: LI Tian-Tian, Yuan YUAN, ZHOU An-Nan, XU Qing-Hong. A π-Conjugated Organic Molecule: BDOBC16 Assembly in Silylated SBA-15 and Luminescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(3): 508-516. doi: 10.11862/CJIC.2016.067 shu

A π-Conjugated Organic Molecule: BDOBC16 Assembly in Silylated SBA-15 and Luminescent Properties

1.
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
2.
Petrochemical Research Institute, PetroChina Company Limited, Beijing 100083, China

Corresponding author: XU Qing-Hong,
Received Date: 13 September 2015
Revised Date: 14 January 2016

Figures(12)

4, 4-(9-(n-Hexadecyl) carbazole-3, 6-diyl) di (6-(4-(diphenylamino) phenyl)-2, 2-difluoro-1, 3, 2(2H)-diox-aborine) (named as BDOBC16), a kind of π-conjugated organic molecule containing β-diketone-boron difluoride groups, was assembled in SBA-15 modified with (3-aminopropyl) triethoxysilane (APTES), and fluorine-boron groups in molecule of BDOBC16 was found to be remained in the assembly. Results indicate that the organic compound in silylated SBA-15 emits green light while itself emits red light. The energy of 0.45 eV is found changeable in emission of the guest before and after assembly, and luminescent intensity of BDOBC16 increases 75 times after it was assembled. Strong H-bond existed between the host and the guest, which is regarded as main reason to result tremendous change in luminescence of the guest. Molecular aggregation is also found harmful while high dispersion is benefit to luminescence of the guest.
- conjugation,
- mesoporous material,
- silicates,
- self-assembly,
- luminescence
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沈阳化工大学材料科学与工程学院沈阳 110142