Citation: XU Shuang-Quan, LIU Chun-Xia, SHEN Qing-Feng, ZHANG Tao, NI Yuan, YU Xiao-Hua. Electrodeposition Mechanism of Zn (Ⅱ) on Zinc Electrode[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(3): 386-392. doi: 10.11862/CJIC.2016.061 shu

Electrodeposition Mechanism of Zn (Ⅱ) on Zinc Electrode

1.
Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
2.
Analysis and Test Center, Kunming University of Science and Technology, Kunming 650093, China

Received Date: 14 October 2015
Revised Date: 19 January 2016

Figures(7)

Reaction method of Zn²⁺ on the zinc electrode was researched by cyclic voltammetry (CV). Nucleation mode with Zn²⁺ was studied by chronoammperometry (CA) and impedance′s behavior of the Zn²⁺ in the different overpotential deposition periods was investigated by electrochemical impedance spectroscopy (EIS) in Zn (Ⅱ)-NH₄Cl quasi neutral system. The results showed that the electrodeposition of Zn²⁺ is an irreversible electrode reactions and conducts by continuous two steps of single electron in which the first step is controlled by speed. The electron transfer coefficient of electrode reaction is related to the surface of zinc electrode structure. Under the condition of constant potential, the crystallization of Zn²⁺ is approximate to three-dimensional instantaneous nucleation on zinc electrode in this system. Depositing of Zn²⁺ has experienced the process of covering, adsorption film and the formation of large number of nucleation. The process was controlled by electrochemical polarization firstly and then the electrochemical polarization-concentration polarization mixed control with the control potential negatively shifted. Finally the mechanism of electrodeposition process with Zn²⁺ on the zinc electrode was given.
- Zn (Ⅱ)-NH₄Cl quasi neutral system,
- electrodeposition,
- cyclic voltammetry,
- chronoammperometry,
- electrochemical impedance spectroscopy
1. [1]
  XIA Zhi-Mei, CHEN Yi-Feng, WANG Yu-Fei, et al. J. Hunan Univ. Technol., 2010, 24(6):9-13
2. [2]
  HE Xiao-Feng, LI Yun-Gang, CHEN Jin. China Nonferrous Metall., 2008(2): 55-58
3. [3]
  HAN Yue-Xin, MA Song-Bo, WANG Yu-Bin, et al. Min. Metall. Eng., 2014, 34(6):56-59
4. [4]
  WANG Meng, CAO Hong-Bin, ZHANG Yi, et al. Environ. Sci., 2011, 32(2):596-602
5. [5]
  ZHENG Guo-Qu, ZHENG Li-Feng, ZHANG Zhao, et al. Nonferrous Metals, 2004, 13 (3):45-48
6. [6]
  WANG Yuan, XU Jin-Yong, SANG Shi-Hua, et al. Sichuan Nonferrous Metals, 2013(1):59-62
7. [7]
  Ding Z Y, Chen Q Y, Yin Z L, et al. Trans. Nonferrous Met. Soc. China, 2013, 23(3):832-840 doi: 10.1016/S1003-6326(13)62536-4
8. [8]
  Yang S H, Tang M T, Chen Y F, et al. Trans. Nonferrous Met. Soc. China, 2004, 14(3):626-630
9. [9]
  WANG Rui-Xiang, TANG Mo-Tang, LIU Wei, et al. Chin. J. Process Eng., 2008(S1):219-222
10. [10]
  XIA Zhi-Mei, YANG Sheng-Hai, TANG Mo-Tang, et al. Chin. Nonferrous Metals, 2013, 23(12):3455-3461
11. [11]
  MA Chun, YU Zhong-Xing, WANG Wei. J. Shanghai Univ.: Nat. Sci. Ed., 2002, 8(5):428-432
12. [12]
  DENG Liang-Xun, WU Bao-Qing. Nonfe-rrous Metals (Extr. Metall.), 2011(4): 14-15
13. [13]
  HU Hui-Li, LI Ning. Electrochemical Meas-urement. Beijing: National Defense Industry Press, 2011.
14. [14]
  Thirsk H R, Harrison J A. A Guide to the Study of Electrode Kinetics. London: Academic Press, 1972.
15. [15]
  Scharifker B R, Mostany J. J. Electroanal. Chem. Interfacial Electrochem., 1984, 177(1/2):13-23
16. [16]
  Scharifker B R, Hills G. Electrochim. Acta, 1983, 28(7):879-889 doi: 10.1016/0013-4686(83)85163-9
17. [17]
  Smith R M, Martell A E. Critical Stability Constants: Inorg-anic Complexes: Vol.4. New York and London: Springer, 1976.
1. [1]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
2. [2]
  Shanying Chen , Kangning Huo , Ke Qi , Jingyi Li , Shuxin Li , Yunchao Li . A Novel Colloid Electrophoresis Experiment with the Characteristics of Resource Recycling and Inquiry-Driven Experimental Design. University Chemistry, 2024, 39(5): 274-286. doi: 10.3866/PKU.DXHX202311067
3. [3]
  Kun Li , Na Gao , Shuangyan Huan , Yuzhi Wang . Design of Ideological and Political Education for the Experiment of Detecting Cadmium with Anodic Stripping Voltammetry. University Chemistry, 2024, 39(2): 155-161. doi: 10.3866/PKU.DXHX202307068
4. [4]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
5. [5]
  Lei Shi . Nucleophilicity and Electrophilicity of Radicals. University Chemistry, 2024, 39(11): 131-135. doi: 10.3866/PKU.DXHX202402018
6. [6]
  Shicheng Yan . Experimental Teaching Design for the Integration of Scientific Research and Teaching: A Case Study on Organic Electrooxidation. University Chemistry, 2024, 39(11): 350-358. doi: 10.12461/PKU.DXHX202408036
7. [7]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020
8. [8]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
9. [9]
  Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In₂Se₃(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
10. [10]
  Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085
11. [11]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
12. [12]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
13. [13]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
14. [14]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
15. [15]
  Yan Cheng , Hua-Peng Ruan , Yan Peng , Longhe Li , Zhenqiang Xie , Lang Liu , Shiyong Zhang , Hengyun Ye , Zhao-Bo Hu . Magnetic, dielectric and luminescence synergetic switchable effects in molecular material [Et₃NCH₂Cl]₂[MnBr₄]. Chinese Chemical Letters, 2024, 35(4): 108554-. doi: 10.1016/j.cclet.2023.108554
16. [16]
  Zian Lin , Yingxue Jin . Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry (MALDI-MS) for Disease Marker Screening and Identification: A Comprehensive Experiment Teaching Reform in Instrumental Analysis. University Chemistry, 2024, 39(11): 327-334. doi: 10.12461/PKU.DXHX202403066
17. [17]
  Li Lin , Song-Lin Tian , Zhen-Yu Hu , Yu Zhang , Li-Min Chang , Jia-Jun Wang , Wan-Qiang Liu , Qing-Shuang Wang , Fang Wang . Molecular crowding electrolytes for stabilizing Zn metal anode in rechargeable aqueous batteries. Chinese Chemical Letters, 2024, 35(7): 109802-. doi: 10.1016/j.cclet.2024.109802
18. [18]
  Zhao Lu , Hu Lv , Qinzhuang Liu , Zhongliao Wang . Modulating NH₂ Lewis Basicity in CTF-NH₂ through Donor-Acceptor Groups for Optimizing Photocatalytic Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(12): 2405005-. doi: 10.3866/PKU.WHXB202405005
19. [19]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
20. [20]
  Jie Zhou , Quanyu Li , Xiaomeng Hu , Weifeng Wei , Xiaobo Ji , Guichao Kuang , Liangjun Zhou , Libao Chen , Yuejiao Chen . Water molecules regulation for reversible Zn anode in aqueous zinc ion battery: Mini-review. Chinese Chemical Letters, 2024, 35(8): 109143-. doi: 10.1016/j.cclet.2023.109143

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(3947)
HTML views(2160)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142