Citation: LIU Yong, LIU Tian-Hui, BI Shu-Xian, An Wei, LI Guo-Bao, TIAN Guang-Shan, JIAO Huan, JING Xi-Ping. Correlation Between the Body Color of YAlO₃ and Its Defect Equilibrium[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(3): 491-498. doi: 10.11862/CJIC.2016.051 shu

Correlation Between the Body Color of YAlO₃ and Its Defect Equilibrium

LIU Yong ¹ ,
LIU Tian-Hui ¹ ,
BI Shu-Xian ² ,
An Wei ³ ,
LI Guo-Bao ⁴ ,
TIAN Guang-Shan ³ ,
JIAO Huan ^1,*,, ,
JING Xi-Ping ^4,*,,

1.
Key Laboratory of Macromolecular Science of Shaanxi Province, College of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi′an 710062, China
2.
College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, China
3.
School of Physics, Peking University, Beijing, 100871, China
4.
State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

Corresponding author: JIAO Huan, jiaohuan@snnu.edu.cn JING Xi-Ping, xpjing@pku.edu.cn
Received Date: 24 July 2015
Revised Date: 15 December 2015

Figures(9)

Powder and pellet samples of YAlO₃ with various defect concentrations were prepared using conventional solid state reactions at 1 450 ℃, followed by annealing in air, O₂ or N₂ atmospheres at various temperatures. The correlation between the body-color of the samples and the defect equilibria was investigated by diffuse-reflection spectra and AC impedance data. The results indicate that YAlO₃ has p-type conduction and its light-brown body-color is caused by the cation vacancies. Annealing YAlO₃ at high temperature in N₂ atmosphere may reduce the defect concentration and the body-color. By the first-principle calculations, it is proposed that the Al vacancies V_Al^× may be the dominant defects in YAlO₃.
- YAlO₃,
- body-color,
- cation vacancy,
- diffuse~reflection spectrum,
- AC
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沈阳化工大学材料科学与工程学院沈阳 110142

Correlation Between the Body Color of YAlO3 and Its Defect Equilibrium

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通讯作者: 陈斌, bchen63@163.com

Correlation Between the Body Color of YAlO₃ and Its Defect Equilibrium