Citation: CUI Yu, LI Ye-Xin, YANG Xiao-Feng, YANG Hong-Xiao, CHEN Guo-Zhu, SUN Guo-Xin. Extraction of U (Ⅵ) from Nitric Acid Media with Asymmetric N-methyl-N-decyl Alkylamide in n-octane[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(2): 211-215. doi: 10.11862/CJIC.2016.050 shu

Extraction of U (Ⅵ) from Nitric Acid Media with Asymmetric N-methyl-N-decyl Alkylamide in n-octane

School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China

Corresponding author: SUN Guo-Xin, chm_sungx@ujn.edu.cn
Received Date: 9 June 2015
Revised Date: 26 December 2015

Figures(6)

The extraction of uranium from high level liquid waste is important. In this paper, a series of structural related asymmetric amide extractant bearing methyl on N atom, such as N-methyl-N-decyloctanamide (MDOA), N-methyl-N-decyl-decanamide (MDDA) and N-methyl-N-decyldodecanamide (MDDOA) was designed and synthesized. The extraction thermodynamics of U (Ⅵ) from nitric acid solutions with the aforementioned extractants in n-octane was investigated in detail and the various factors affected extraction properties were studied.
- uranium,
- extraction,
- alkylamide,
- n-octane
1. [1]
  CHEN Jing, JIAO Rong-Zhou, ZHU Yong-Bei-Rui. At. Energ Sci. Technol., 1998, 32(5):471-480
2. [2]
  ZHANG Ping, LIANG Jun-Fu, XIN Ren-Xuan, et al. Nucl. Technol., 2003, 26(12):940-945 doi: 10.3321/j.issn:0253-3219.2003.12.009
3. [3]
  Gujar R B, Ansari S A, Mohapatra P K. Sep. Purif. Technol., 2015, 141:229-234 doi: 10.1016/j.seppur.2014.11.038
4. [4]
  Huang H, Ding S D, Liu N, et al. Sep. Purif. Technol., 2014, 123:235-240 doi: 10.1016/j.seppur.2013.12.039
5. [5]
  Mahanty B N, Raut D R, Mohapatra P K, et al. J. Hazard.Mater., 2014, 275:146-153
6. [6]
  Zhang Y, Zheng S L, Wang X H, et al. Hydrometallurgy, 2015, 154:47-55 doi: 10.1016/j.hydromet.2015.03.013
7. [7]
  Mowafy E A, Mohamed D. Sep. Purific. Technol., 2014, 128:18-24 doi: 10.1016/j.seppur.2014.03.005
8. [8]
  Carrott M, Geist A, Hères X, et al. Hydrometallurgy, 2015, 152:139-148 doi: 10.1016/j.hydromet.2014.12.019
9. [9]
  WU Yu-Xuan, DING Song-Dong, LIU Ning. Chem. J. Chinese Universities, 2014, 35(2):257-261 doi: 10.7503/cjcu20130635
10. [10]
  YANG Jin-Hong, CUI Yu, XIA Guang-Ming, et al. Chinese J. Inorg. Chem., 2012, 28(7):1372-1376
11. [11]
  Cui Y, Sun G X, Zhang Z W, et al. Radiochim. Acta, 2005, 93:287-290
12. [12]
  Ren P, Yue Y Z, Wang K, et al. J. Radioanal. Nucl. Chem., 2014, 300(3):1099-1103 doi: 10.1007/s10967-014-3069-2
13. [13]
  Liu X L, Sun G X, Cai X C, et al. J. Radioanal. Nucl.Chem., 2015, 306:549-553
14. [14]
  Condamines N, Musikas C. Solvent Extr. Ion Exch., 1992, 10(1):69-100 doi: 10.1080/07366299208918093
15. [15]
  SUN Guo-Xin, HAN Jing-Tian, ZHU Jian-Kang et al. Chinese J. Inorg. Chem., 1999, 15(2):191-195
16. [16]
  CUI Yu, SUN Guo-Xin, BAO Meng, et al. Chinese J. Inorg. Chem., 2003, 19(11):1175-1178 doi: 10.3321/j.issn:1001-4861.2003.11.005
17. [17]
  Condamines N, Musikas C. Solvent Extr. Ion Exch., 1993, 11(2):187-192 doi: 10.1080/07366299308918152
18. [18]
  LI Yi-Gui. Metal Solvent Extraction Thermodynam-ics. Beijing: Tsinghua UniversityPress, 1988:285
19. [19]
  Hu P Z, Qian L J, Wang H L, et al. Sep. Sci. Technol., 2014, 49(10):1521-1526 doi: 10.1080/01496395.2014.885531
20. [20]
  ZHANG Zhen-Wei, CUI Yu, SUN Guo-Xin. Chinese J. Inorg. Chem., 2005, 21:885-888 doi: 10.3321/j.issn:1001-4861.2005.06.021
21. [21]
  Mowafy E A, Aly H F.. Solvent Extr. Ion Exch., 2002, 20(2):177-194
22. [22]
  Hu P Z, Qian L J, Zhou X, et al. J. Radioanal. Nucl. Chem., 2013, 295(2):1209-1213 doi: 10.1007/s10967-012-1904-x
23. [23]
  Ferraro J R. J. Inorg. Nucl. Chem., 1959, 10:319-324 doi: 10.1016/0022-1902(59)80124-X
24. [24]
  Ferraro J R, Walker A. J. Chem. Phys., 1966, 45(2):550-553 doi: 10.1063/1.1727603
25. [25]
  XU Guang-Xian(徐光宪), WANG Wen-Qing(王文清), WU Jin-Guang(吴谨光). Extraction Chemistry Principles(萃取化学原理). Shanghai: Shanghai Science and TechnologyPress, 1984:160
26. [26]
  WANG Han-Zhang, CUI Li, DAI Jie-Jun. Chinese J. Inorg. Chem., 1995, 11(2):120-125
27. [27]
  SUN Guo-Xin, BAO Bo-Rong, CUI Yu. J. Nucl. Chem. Radiochem., 1999, 21(2):119-123
28. [28]
  SUN Guo-Xin, LI Yu-Lan, BAO Bo-Rong. J. Nuclear Chem. Radiochem., 1998, 20(2):103-108
29. [29]
  HAN Jing-Tian, BAO Bo-Rong, SUN Guo-Xin, et al. Acta Chim. Sinica, 2000, 58(10):1286-1290 doi: 10.3321/j.issn:0567-7351.2000.10.021
30. [30]
  Ruikar P B, Nagar M S, Subramanian M S. J. Radioanal. Nucl. Chem., 1993, 176(2):103-111 doi: 10.1007/BF02163190
31. [31]
  Nair G M, Mahajan G R, Prabhu D R. J. Radioanal. Nucl.Chem., 1995, 191(2):323-330
1. [1]
  Lihui Jiang , Wanrong Dong , Hua Yang , Yongqing Xia , Hongjian Peng , Jun Yuan , Xiaoqian Hu , Zihan Zeng , Yingping Zou , Yiming Luo . Study on Extraction of p-Hydroxyacetophenone. University Chemistry, 2024, 39(11): 259-268. doi: 10.12461/PKU.DXHX202402056
2. [2]
  Guoze Yan , Bin Zuo , Shaoqing Liu , Tao Wang , Ruoyu Wang , Jinyang Bao , Zhongzhou Zhao , Feifei Chu , Zhengtong Li , Yusuke Yamauchi , Saad Melhi , Xingtao Xu . Opportunities and Challenges of Capacitive Deionization for Uranium Extraction from Seawater. Acta Physico-Chimica Sinica, 2025, 41(4): 100032-. doi: 10.3866/PKU.WHXB202404006
3. [3]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
4. [4]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
5. [5]
  Shiyan Cheng , Yonghong Ruan , Lei Gong , Yumei Lin . Research Advances in Friedel-Crafts Alkylation Reaction. University Chemistry, 2024, 39(10): 408-415. doi: 10.12461/PKU.DXHX202403024
6. [6]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020
7. [7]
  Ruming Yuan , Pingping Wu , Laiying Zhang , Xiaoming Xu , Gang Fu . Patriotic Devotion, Upholding Integrity and Innovation, Wholeheartedly Nurturing the New: The Ideological and Political Design of the Experiment on Determining the Thermodynamic Functions of Chemical Reactions by Electromotive Force Method. University Chemistry, 2024, 39(4): 125-132. doi: 10.3866/PKU.DXHX202311057
8. [8]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
9. [9]
  Meijin Li , Xirong Fu , Xue Zheng , Yuhan Liu , Bao Li . The Marvel of NAD⁺: Nicotinamide Adenine Dinucleotide. University Chemistry, 2024, 39(9): 35-39. doi: 10.12461/PKU.DXHX202401027
10. [10]
  Hong Zheng , Xin Peng , Chunwang Yi . The Tale of Caprolactam Cyclic Oligomers: The Ever-changing Life of “Princess Cyclo”. University Chemistry, 2024, 39(9): 40-47. doi: 10.12461/PKU.DXHX202403058
11. [11]
  Yuena Yu , Fang Fang . Microwave-Assisted Synthesis of Safinamide Methanesulfonate. University Chemistry, 2024, 39(11): 210-216. doi: 10.3866/PKU.DXHX202401076
12. [12]
  Xinghai Li , Zhisen Wu , Lijing Zhang , Shengyang Tao . Machine Learning Enables the Prediction of Amide Bond Synthesis Based on Small Datasets. Acta Physico-Chimica Sinica, 2025, 41(2): 100010-. doi: 10.3866/PKU.WHXB202309041
13. [13]
  Shiyi WANG , Chaolong CHEN , Xiangjian KONG , Lansun ZHENG , Lasheng LONG . Polynuclear lanthanide compound [Ce₄^ⅢCe₆^Ⅳ(μ₃-O)₄(μ₄-O)₄(acac)₁₄(CH₃O)₆]·2CH₃OH for the hydroboration of amides to amine. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 88-96. doi: 10.11862/CJIC.20240342

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(552)
HTML views(85)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142