Citation: FANG Zhi-Li, XIONG Shan, LI Kang-Yu, YU Quan-Feng, XU Wen-Yuan. Two Heterometallic 4d-4f Coordination Polymers Based on 4-(1H-1, 2, 4-TriazoL^-1-yl) benzoic Acid: Syntheses, Structures, and Fluorescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(2): 280-288. doi: 10.11862/CJIC.2016.046 shu

Two Heterometallic 4d-4f Coordination Polymers Based on 4-(1H-1, 2, 4-TriazoL^-1-yl) benzoic Acid: Syntheses, Structures, and Fluorescence Properties

School of Science, East China Jiaotong University, Nanchang 330013, China

Corresponding author: FANG Zhi-Li, fangzhili1972@126.com
Received Date: 1 June 2015
Revised Date: 4 December 2015

Fund Project: 国家自然科学基金 21365012

Figures(11)

Two 2D heterometallic 4d-4f coordination polymers, {[EuAg (tbc)₃ (H₂O)]ClO₄·H₂O}_n (1) and {[Eu₂Ag₃(tbc)₆(NO₃)₂(H₂O)₂](ClO₄)₂·2H₂O}_n (2) (Htbc=4-(1H-1, 2, 4-triazoL^-1-yl) benzoic acid) were synthesized under hydro-thermal condition using one-step approach and structurally characterized by elemental analysis, FT-IR, powder X-ray diffraction and single-crystal X-ray diffraction. The single-crystal X-ray diffraction analysis reveals that the two complexes present two different types of two dimensional (2D) structures. Complex 1 crystallized in an orthorhombic manner having a P212121 space group, consisting of 1D triple-stranded helical (PPM) [Eu (μ₃-OCO)₂ (μ₂-OCO)] motif as chain which are further linked by the fragments of tbc-ligands and Ag (Ⅰ). Polymer 2 is crystallized in a triclinic fashion having a P1 space group, consisting of 1D mesomeric chains [Eu (μ₃-OCO)₂] which were further linked by the two different [N-Ag-N] units to form an interesting 2D 4d-4f heterometallic coordination polymer in the ab plane. The solid-state luminescent behaviors of compounds 1 and 2 were investigated at room temperature. CCDC: 1018336, 1; 1024087 2.
- 4-(1H-1, 2, 4-triazoL^-1-yl) benzoic acid ligand,
- heterometallic,
- crystal structure
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Two Heterometallic 4d-4f Coordination Polymers Based on 4-(1H-1, 2, 4-TriazoL-1-yl) benzoic Acid: Syntheses, Structures, and Fluorescence Properties

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通讯作者: 陈斌, bchen63@163.com

Two Heterometallic 4d-4f Coordination Polymers Based on 4-(1H-1, 2, 4-TriazoL^-1-yl) benzoic Acid: Syntheses, Structures, and Fluorescence Properties