Citation: LIU Bing, FU Rong-Rong, GAO Shan-Min, HUANG Bai-Biao, DAI Ying. Preparation of Ti³⁺ Self-Doped TiO₂(A)/TiO₂(R)/In₂O₃ Nanoheterojunctions with Enhanced Visible-Light-Driven Photocatalytic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(2): 223-232. doi: 10.11862/CJIC.2016.045 shu

Preparation of Ti³⁺ Self-Doped TiO₂(A)/TiO₂(R)/In₂O₃ Nanoheterojunctions with Enhanced Visible-Light-Driven Photocatalytic Properties

LIU Bing ¹ ,
FU Rong-Rong ¹ ,
GAO Shan-Min ^1,2,*,, ,
HUANG Bai-Biao ^2,*,, ,
DAI Ying ²

1.
College of Chemistry and Materials Science, Ludong University, Yantai, Shandong 264025, China
2.
State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China

Corresponding author: GAO Shan-Min, gaosm@ustc.edu HUANG Bai-Biao, gaosm@ustc.edu
Received Date: 27 July 2015
Revised Date: 12 November 2015

Figures(10)

Ti³⁺ self-doped TiO₂(A)/TiO₂(R)/In₂O₃ nanoheterojunctions were synthesized by hydrothermal treatment of the precursor obtained using TiCl₃ and InCl₃ as the Ti and In source without the exist of reductant. The effects of hydrothermal treatment temperature on the properties of the samples were studied. The structure, crystallinity, morphology, chemical state and optical properties of the obtained samples were characterized by X-ray diffraction, transmission electron microscopy, high-resolution transmission electron microscopy, X-ray photoelectron spectroscopy, and UV-Vis diffuse reflectance spectroscopy. Rhodamine B (RhB) and phenol solutions were used as simulated wastewater to evaluate the visible-light photocatalytic activity of the nanoheterojunctions. The Ti³⁺ self-doped TiO₂(A)/TiO₂(R)/In₂O₃ nanoheterojunctions exhibited extended visible light absorption and higher photocatalytic activity than that of pure TiO₂, In₂O₃ and Ti³⁺ self-doped TiO₂. The sample obtained after hydrothermal treatment at 200 ℃ for 24 h exhibited the best visible light photocatalytic activity with a reaction rate constant of 0.044 4 min^-1, 17.76 and 8.71 times than that of pure TiO₂ and In₂O₃. Photocurrent density results indicated that the improved visible-light photocatalytic properties which could be attributed to the enhanced photogenerated charge separation of the nanoheterojunction.
- Ti³⁺ self-doped,
- TiO₂,
- In₂O₃,
- nanoheterojunctions,
- visible-light photocatalysis
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通讯作者: 陈斌, bchen63@163.com

Preparation of Ti³⁺ Self-Doped TiO₂(A)/TiO₂(R)/In₂O₃ Nanoheterojunctions with Enhanced Visible-Light-Driven Photocatalytic Properties