Citation: CHEN Yan-Min, WANG Jing-Mei, CHEN Fei-Peng, CHEN Ya-Xin, ZENG Qian-Ru, XIE Qing-Fan. Hydrothermal Syntheses, Crystal Structures and Properties of Cadmium (Ⅱ)/Copper (Ⅱ) Complexes with Acylhydrazone and Phenanthroline Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(3): 434-440. doi: 10.11862/CJIC.2016.043 shu

Hydrothermal Syntheses, Crystal Structures and Properties of Cadmium (Ⅱ)/Copper (Ⅱ) Complexes with Acylhydrazone and Phenanthroline Ligands

College of Chemistry and Life Science, Quanzhou Normal University, Quanzhou, Fujian 362000, China

Corresponding author: XIE Qing-Fan, xqf360@163.com
Received Date: 23 September 2015
Revised Date: 30 November 2015

Figures(10)

Newly designed [ONO] tridentate hydrazone Schiff base ligand H₂Brsth, derived from the condensation of 5-bromosalicylaldehyde and thiophene-2-formyl hydrazine, hydrothermally reacted with metal acetates and phenanthroline as co-ligand yielding two complexes [Cd₂(μ-Brsth)₂(Phen)₂] (1) and [Cu (Brsth)(Phen)] (2), which were characterized by elemental analyses, FT-IR, electronic spectra, fluorescence spectra, TGA and single crystal X-ray diffraction. The X-ray diffraction analyses reveal that complex 1 crystallizes in monoclinic space group C2/c with a=2.116 36(13) nm, b=1.163 35(7) nm, c=1.872 43(12) nm, β=100.981(2)°, V=4.525 6(5) nm³ and Z=4, while 2 crystallizes in the triclinic space group P1 with a=0.911 7(2) nm, b=1.089 4(3) nm, c=1.272 9(3) nm, α=64.923(4)°, β=82.006(5)°, γ=67.768(5)°, V=1.059 6(5) nm³ and Z=2. The complex 1 is a binuclear ternary complex, in which Cd atoms locate in distorted coordination octahedron. The complex 2 is a mononuclear ternary complex with Cu atom in distorted square pyramidal coordination. The complex 1 exhibits strong green fluorescence with emission maximum of 525 nm at the excitation wavelength of 443 nm, while the ligand shows emission at 475 nm. CCDC: 1062986, 1; 1046224, 2.
- complexes,
- Schiff base,
- crystal structure,
- hydrothermal synthesis
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沈阳化工大学材料科学与工程学院沈阳 110142