Citation: YING Jun, NING Ya-Li, HOU Xue, TIAN Ai-Xiang. Syntheses, Structures and Properties of Three Tri-nuclear Copper Clusters Based on Wells-Dawson Polyoxometalate[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(2): 267-274. doi: 10.11862/CJIC.2016.036 shu

Syntheses, Structures and Properties of Three Tri-nuclear Copper Clusters Based on Wells-Dawson Polyoxometalate

Department of Chemistry, Bohai University, Jinzhou, Liaoning 121013, China

Corresponding author: YING Jun, ying@bhu.edu.cn
Received Date: 15 September 2015
Revised Date: 28 November 2015

Figures(8)

Through using Wells-Dawson type anion [As₂W₁₈O₆₂]^6-, CuCl₂·2H₂O and 5-(4-pyridyl)-1H-tetrazole (4-ptz), two different POM-based compounds containing tri-nuclear copper clusters were synthesized in one-pot under hydrothermal conditions, namely [Cu₃(4-ptz)₄(H₂O)₇(As₂W₁₈O₆₂)]·42H₂O (1) and [Cu₃(4-ptz)₅(H₂O)₅(As₂W₁₈O₆₂)]·47H₂O (2). When we used another Wells-Dawson anion [P₂W₁₈O₆₂]^6-, CuCl₂·2H₂O and 5-(3-pyridyl)-1H-tetrazole (3-ptz), another POM-based tri-nuclear copper cluster was also obtained, namely [Cu₃(3-ptz)₄(H₂O)₈(P₂W₁₈O₆₂)]·33H₂O (3). Single crystal X-ray diffraction shows that compound 1 is a tri-nuclear copper cluster supporting pendent structure, and compound 2 is a one dimensional chain with anions and tri-nuclear copper clusters arranging alternately, while compound 3 is a discrete structure containing anions and tri-nuclear copper clusters. 3-ptz and 4-ptz are important structural factors for constructing tri-nuclear copper clusters in compounds 1~3. The electrochemical and photocatalytic activities of the title compounds have been studied. CCDC: 1416806, 1; 1406807, 2; 1406808, 3.
- Wells-Dawson polyoxometalate,
- multi-nuclear copper cluster,
- hydrothermal synthesis,
- electrochemistry,
- photocatalysis
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