Citation: ZHONG Kai-Long, LUO Li. Syntheses, Crystal Structures and Fluorescence Properties of Cadmium Coordination Polymers with 1, 3, 5-Tris (imidazoL^-1-ylmethyl) benzene[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(2): 275-279. doi: 10.11862/CJIC.2016.035 shu

Syntheses, Crystal Structures and Fluorescence Properties of Cadmium Coordination Polymers with 1, 3, 5-Tris (imidazoL^-1-ylmethyl) benzene

ZHONG Kai-Long ^1,*,, ,
LUO Li ²

1.
Department of Applied Chemistry, Nanjing Polytechnic Institute, Nanjing 210048, China
2.
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Corresponding author: ZHONG Kai-Long, zklong76@163.com
Received Date: 8 October 2015
Revised Date: 19 November 2015

Figures(4)

Two new coordination polymers, {[Cd (L)(EG)_0.5(H₂O)(SO₄)]·EG·H₂O}_n (1) and [Cd (L)(EG)(SO₄)]_n (2) (EG=ethylene glycol), were solvothermally synthesized by reactions of flexible imidazole-containing ligand 1, 3, 5-tris (imidazoL^-1-ylmethyl) benzene (L) with cadmium sulfate under different reaction conditions. The complexes were characterized by elemental analysis, IR and single crystal X-ray diffraction. Ligand L links Cd (Ⅱ) to form 1D chain in 1 while in 2 the ligand L coordinates with Cd (Ⅱ) to give 2D network, which is further connected by sulfate anions to generate 3D structure. Interestingly, each EG connects two intra-chain Cd (Ⅱ) atoms in 1 and acts as terminal ligand in 2. The sulfate anion acts as terminal ligand in 1 and bridging one in 2. The fluorescence properties of the complexes was investigated. CCDC: 1430130, 1; 1430131, 2.
- cadmium (Ⅱ) complex,
- coordination polymers,
- crystal structure,
- fluorescence property
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Syntheses, Crystal Structures and Fluorescence Properties of Cadmium Coordination Polymers with 1, 3, 5-Tris (imidazoL-1-ylmethyl) benzene

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通讯作者: 陈斌, bchen63@163.com

Syntheses, Crystal Structures and Fluorescence Properties of Cadmium Coordination Polymers with 1, 3, 5-Tris (imidazoL^-1-ylmethyl) benzene