Citation: HU Peng, WU Yan-Ni, HUANG Qi-Xiao, LIAN Si-Mian, FU Xing-Hui, HE Gao-Peng, CHEN Xia-Min. Gd (Ⅲ), Tb (Ⅲ) and Dy (Ⅲ) Complexes Based on a Nitronyl Nitroxide Radical: Syntheses, Structures and Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(2): 297-304. doi: 10.11862/CJIC.2016.032 shu

Gd (Ⅲ), Tb (Ⅲ) and Dy (Ⅲ) Complexes Based on a Nitronyl Nitroxide Radical: Syntheses, Structures and Magnetic Properties

College of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing, Guangdong 526061, China

Corresponding author: HU Peng, hp8286799@zqu.edu.cn
Received Date: 20 June 2015
Revised Date: 1 December 2015

Figures(9)

One novel nitronyl nitroxide radical and its three mononuclear tri-spin compounds Ln (hfac)₃(NIT-Ph-4-OCHCH₃CH₃)₂ (Ln=Gd (1), Tb (2), Dy (3); hfac=hexafluoroacetylacetonate; NIT-Ph-4-OCHCH₃CH₃=2-(4-isopropoxyphenyl)-4, 4, 5, 5-tetramethyl-imidazoline-1-oxyl-3-oxide) have been successfully prepared and characterized. Single crystal X-ray crystallographic analyses reveal that complexes 1, 2, and 3 shows similar radical-Ln (Ⅲ)-radical structures, which ar composed of one Ln (hfac)₃ units and two NIT-Ph-4-OCHCH₃CH₃ radicals. Magnetic studies reveal that ferromagnetic interactions (between intramolecular Ln and radical) and antiferromagnetic interactions (between the intramolecular radicals) are coexist in these complexes. CCDC: 985443, 1; 1043098, 2; 985444, 3.
- nitronyl nitroxide radical,
- lanthanides,
- crystal structure,
- magnetic properties
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