Citation: ZHANG Qian, HAN Yan, JIAO Yuan-Hong. Synthesis, Crystal Structure and Catecholase Activity of the Cobalt (Ⅱ) Complex Containing Benzimidazole Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 131-138. doi: 10.11862/CJIC.2016.031 shu

Synthesis, Crystal Structure and Catecholase Activity of the Cobalt (Ⅱ) Complex Containing Benzimidazole Ligand

ZHANG Qian ¹ ,
HAN Yan ² ,
JIAO Yuan-Hong ^1,*,,

1.
College of Chemistry and Chemical Engineering, Hubei Polytechnic University, Huangshi, Hubei 435003, China
2.
College of Chemistry and Chemical Engineering, Xinxiang University, Xinxiang, Henan 453003, China

Corresponding author: JIAO Yuan-Hong, yhjiao2014@163.com
Received Date: 21 July 2015
Revised Date: 16 November 2015

Figures(8)

A cobalt (Ⅱ) complex, [CoLCl]₂[CoLCl_0.5(H₂O)_0.5]₂ClO₄·10H₂O (1) (LH=(2-(bis ((1H-benzo[d]-imidazol-2-yl) methyl) amino) acetic acid)) has been synthesized and characterized. Its catecholase catalytic activity has been exploited by UV-Vis spectrophotometric study by using 3, 5-di-tert-butylcatechol (3, 5-DTBC) as the substrate. The results showed that two cobalt (Ⅱ) ions of the asymmetric unit were both coordinated by the ligands in a distorted trigonal-bipyramidal geometry in the crystal structure. Complex 1 exhibited pH value dependence for the oxidation of 3, 5-DTBC in the range of pH 5 to 11, and its catecholase catalytic activity increased with increasing temperature. The kinetics of oxidation of 3, 5-DTBC catalyzed by complex 1 accorded with the Michaelis-Mentent equation. CCDC: 950329, 1.
- cobalt (Ⅱ) complex,
- crystal structure,
- catecholase,
- catalytic activity
1. [1]
  Koval I A, Gamez P, Belle C, et al. Chem. Soc. Rev., 2006, 35:814-840 doi: 10.1039/b516250p
2. [2]
  Klabunde T, Eicken C, Sacchettini J C, et al. Nat. Struct. Biol., 1998, 5:1084-1090 doi: 10.1038/4193
3. [3]
  Patra A, Giri G C, Sen T K, et al. Polyhedron, 2014, 67:495-504 doi: 10.1016/j.poly.2013.09.034
4. [4]
  Caglar S, Aydemir I E, Adiguzel E, et al. Inorg. Chim. Acta, 2013, 408:131-138 doi: 10.1016/j.ica.2013.09.013
5. [5]
  Caglar S, Adiguzel E, Caglar B, et al. Inorg. Chim. Acta, 2013, 397:101-109 doi: 10.1016/j.ica.2012.11.028
6. [6]
  Safaei E, Sheykhi H, Wojtczak A, et al. Polyhedron, 2011, 30:1219-1224 doi: 10.1016/j.poly.2011.01.036
7. [7]
  ZHANG Yong, ZHOU Xia, HU Jia-Wei, et al. Chinese J. Struct. Chem., 2013, 32(9): 1291-1296
8. [8]
  Apurba B, Lakshmi K D, Michael G B D, et al. Inorg. Chem., 2012, 51:7993-8001 doi: 10.1021/ic202748m
9. [9]
  陈彦国, 廖展如, 李武客.化学学报, 2000, 58 (10):1191-1195
10. [10]
  Ogawa K, Nakata K, Ichikawa K. Chem. Lett., 1998, 27:797-798 doi: 10.1246/cl.1998.797
11. [11]
  Zhang Y, Meng X G, Liao Z R, et al. J. Coord. Chem., 2009, 62:876-885 doi: 10.1080/00958970802389755
12. [12]
  SAINT, Program for Area Detector Absorption Correction, Siemens Analytical X-Ray Instruments Inc. , Madison, WI 53719, USA, 1994-1996.
13. [13]
  Sheldrick G M. SADABS, Program for Siemens Area Detector Absorption Correction, University of Göttingen, Germany, 1996.
14. [14]
  Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1997.
15. [15]
  Spek A L. Acta Crystallogr., 2009, D65:148-155
16. [16]
  Addison A W, Rao T N, Reedijk J, et al. J. Chem. Soc. Dalton Trans., 1984:1349-1356
17. [17]
  Yi L, Du J Y, Liu S, et al. J. Chem. Res., 2004, 1:29-31
18. [18]
  Rompel A, Fischer H, Meiwes D, et al. FEBS Lett., 1999, 445:103-110 doi: 10.1016/S0014-5793(99)00106-4
19. [19]
  Seneque O, Campion M, Douziech B, et al. Eur. J. Inorg. Chem., 2002, 8:2007-2014
20. [20]
  Chen Z F, Liao Z R, Li D F, et al. J. Inorg. Biochem., 2004, 98:1315-1318 doi: 10.1016/j.jinorgbio.2004.04.006
21. [21]
  Neves A, Rossi L M, Bortoluzzi A J, et al. J. Braz. Chem. Soc., 2001, 12:747-754
22. [22]
  Qiu J H, Liao Z R, Meng X G. Polyhedron, 2005, 24:1617-1623 doi: 10.1016/j.poly.2005.04.027
23. [23]
  Lu L J, Song Y Y, Liu H, et al. J. Coord. Chem., 2012, 65: 1278-1288 doi: 10.1080/00958972.2012.671480
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2. [2]
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沈阳化工大学材料科学与工程学院沈阳 110142