Citation: SU Xiu-Mei, JIANG Li, YI Yong-Ling. Syntheses, Structures, and Properties of Transition Metal Complexes Constructed from 6-Methyl-2, 3, 5-pyridinetricarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(2): 320-326. doi: 10.11862/CJIC.2016.027 shu

Syntheses, Structures, and Properties of Transition Metal Complexes Constructed from 6-Methyl-2, 3, 5-pyridinetricarboxylic Acid

SU Xiu-Mei ^1,*,, ,
JIANG Li ² ,
YI Yong-Ling ²

1.
College of Chemistry, Tianjin Normal University, Tianjin 300387, China
2.
Department of Chemistry, Tianjin University, Tianjin 300072, China

Corresponding author: SU Xiu-Mei, hxxysxm@mail.tjnu.edu.cn
Received Date: 20 August 2015
Revised Date: 27 November 2015

Figures(5)

Two new transition metal coordination polymers, {[Cu (Hmptc)(H₂O)]·2H₂O}_n (1) and {Cd (Hmptc)(H₂O)}_n (2), were successfully constructed from transition metal salts with 6-methyl-2, 3, 5-pyridinetricarboxylic acid (H₃mptc). Complex 1 exhibits a 2D coordination network, in which rectangle channels are shown to exist. In complex 2, Cd (Ⅱ) centers are linked by Hmptc^2- ligands into 2D grid-like layers, which are further linked by hydrogen bonding interactions to form a 3D supramolecular network. In addition, complex 2 exhibits blue/green luminescence in the solid state at room temperature. CCDC: 906071, 1; 906072, 2.
- 6-methyl-2, 3, 5-pyridinetricarboxylic acid,
- coordination polymers,
- luminescence properties
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