Citation: LIU Guang-Xiang. Syntheses, Crystal Structures and Luminescent Properties of Zinc (Ⅱ) and Cadmium (Ⅱ) Coordination Polymers Constructed by Aromatic Carboxylates and 1, 3, 5-Tris (imidazol-1-yl) benzene[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 175-183. doi: 10.11862/CJIC.2016.024 shu

Syntheses, Crystal Structures and Luminescent Properties of Zinc (Ⅱ) and Cadmium (Ⅱ) Coordination Polymers Constructed by Aromatic Carboxylates and 1, 3, 5-Tris (imidazol-1-yl) benzene

LIU Guang-Xiang

Key Laboratory of Advanced Functional Materials of Nanjing, Department of Chemistry, Nanjing Xiaozhuang University, Nanjing 211171, China

Received Date: 28 September 2015
Revised Date: 7 November 2015

Figures(9)

Two coordination polymers, namely {[Zn (timb)(BTEC)_0.5]·H₂O}_n (1) and {[Cd (timb)(DPA)] ·H₂O}_n (2), have been obtained by the reaction of metal salt (zinc nitrate or cadmium nitrate), 1, 3, 5-tris (imidazol-1-yl) benzene (timb) with two aromatic carboxylic acids, 1, 2, 4, 5-benzenetetracarboxylic acid (H₄BTEC) and diphenic acid (H₂DPA). They were characterized by IR spectroscopy, elemental analysis and single-crystal X-ray diffraction. Complex 1 crystallizes in triclinic, space group P1 with a=0.991 32(9) nm, b=1.018 23(10) nm, c=1.112 45(11) nm, α=81.479 0(10)°, β=65.613 0(10)°, γ=62.318 0(10)°. Complex 2 belongs to monoclinic, space group C2/c with a=2.633 0(2) nm, b=0.841 96(8) nm, c=2.353 5(2) nm, β=98.027 0(10)°. Structural analyses reveal that complex 1 exhibits a novel three-dimensional (3D) (3, 4, 5)-connected framework with an unusual (4.6³·8⁶)₂(4²·8⁴)(6³)₂ topology, whereas complex 2 possesses a one-dimensional (1D) single-wall metal-organic nanotube based on double helical chains. The results show that the nature of metal ions and the carboxylic building blocks play an important role in the formation of complexes with diverse structures. The luminescent properties of two complexes have also been investigated. CCDC: 1422833, 1; 1422832, 2.
- coordination polymer,
- tris (imidazole) ligands,
- polycarboxylate,
- crystal structure,
- luminescence
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