Citation: YANG Fang, DONG Bao-Xia, TANG Meng, LIU Wen-Long. Syntheses, Crystal Structures and Photoluminescence of Two Metal Coordination Polymers Constructed from 2-Mercaptobenzoic Acid and Its in situ Oxidized Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 1-8. doi: 10.11862/CJIC.2016.017 shu

Syntheses, Crystal Structures and Photoluminescence of Two Metal Coordination Polymers Constructed from 2-Mercaptobenzoic Acid and Its in situ Oxidized Ligand

College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, China

Corresponding author: LIU Wen-Long, liuwl@yzu.edu.cn
Received Date: 27 September 2015
Revised Date: 13 November 2015

Figures(5)

Two novel coordination polymers, [Cd(2-mba)(bimb)]_n(1) and [Pb(2-sb)]_n(2) [H₂(2-mba)=2-mercaptobenzoic acid, bimb=4,4-bis(1-imidazolyl)bibenzene, sb^2-=2-sulfinobenzoate] have been solvothermal synthesized and characterized by elemental analysis, IR, powder X-ray diffraction and single crystal X-ray diffraction. Complex 1 features a two-dimensional (2D) net structure in which 1D [Cd(2-mba)]_n chains are interconnected by bimb ligands. In complex 1, the ligand 2-mercaptobenzoic acid was oxidized into 2-sulfinobenzoate under solvothermal conditions via in situ ligand reactions. Complex 2 exhibits a 2D(4, 4)-connected framework bridged with carboxylate and sulfinate groups of 2-sulfinobenzoate ligands. The thermal stabilities and solid state photoluminescent properties of two compounds were also investigated. CCDC: 1056796, 1; 1056797, 2.
- cadmium(Ⅱ),
- lead(Ⅱ),
- coordination polymer,
- solvothermal synthesis in situ,
- crystal structure,
- luminescence
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