Citation: MIN Hui-Hua, XU Feng, Lü Yi-Nong, YANG Jing, DING Lin-Fei, SU Fan, ZHU Jian-Min. Orientation Relations and Conversion Matrix Between M3 Supercell and Pseudohexagonal Subcell in Tricalcium Silicate Solid Solution[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 145-152. doi: 10.11862/CJIC.2016.014 shu

Orientation Relations and Conversion Matrix Between M3 Supercell and Pseudohexagonal Subcell in Tricalcium Silicate Solid Solution

MIN Hui-Hua ^1,2,*,, ,
XU Feng ² ,
Lü Yi-Nong ³ ,
YANG Jing ¹ ,
DING Lin-Fei ¹ ,
SU Fan ¹ ,
ZHU Jian-Min ⁴

1.
Electron Microscope Lab, Nanjing Forestry University, Nanjing 210037, China
2.
Key Laboratory of MEMS of the Ministry of Education, Southeast University, Nanjing 210096, China
3.
State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, China
4.
State Key Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093, China

Corresponding author: MIN Hui-Hua, hhmin@njfu.edu.cn
Received Date: 1 September 2015
Revised Date: 19 October 2015

Figures(6)

A M3 modification of tricalcium silicate (C₃S) solid solution was investigated using transmission electron microscope (TEM). Selected area electron diffraction (SAED) patterns and high resolution transmission electron microscopy (HRTEM) images were analyzed based on a pseudohexagonal subcell (Space group R3m; a=0.705 9 nm, b=0.705 5 nm, c=2.492 4 nm, α=89.79°, β=90.04°, γ=120.14°). Reflections caused by the superstructure were proven to occur along the modulation wave vector [117]_H^* with one-dimensional type and could be expressed as ha^*+kb^*+lc^*+m/[6(-a^*+b^*+7c^*)], where m=±1, ±2 and±3. SAED patterns and HRTEM images based on the M3 supercell (Space group Cm; a=3.310 8 nm, b=0.703 6 nm, c=1.852 1 nm, β=94.137°) were simulated and finally the orientation relations between M3 supercell and pseudohexagonal subcell were established as follows: (600)_M3, (020)_M3 and (006)_M3 were equivalent to (112)_H, (110)_H and (117)_H respectively, and [100]_M3//[772]_H, [010]_M3//[110]_H, and [001]_M3//[111]_H. Furthermore, the conversion matrix between M3 supercell and pseudohexagonal subcell was established.
- tricalcium silicate,
- modulated structure,
- orientation relations,
- transmission electron microscopy
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