Citation: ZOU Wei, XIE Peng-Fei, LI Xu-Guang, KONG De-Jin, HUA Wei-Ming, YUE Ying-Hong, GAO Zi. Catalytic Decomposition of N₂O over Cu-ZSM-5 Nanosheets with Different n_Si/n_Al[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 89-95. doi: 10.11862/CJIC.2016.010 shu

Catalytic Decomposition of N₂O over Cu-ZSM-5 Nanosheets with Different n_Si/n_Al

ZOU Wei ^1,2 ,
XIE Peng-Fei ¹ ,
LI Xu-Guang ² ,
KONG De-Jin ² ,
HUA Wei-Ming ¹ ,
YUE Ying-Hong ^1,*,, ,
GAO Zi ¹

1.
Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, China
2.
Shanghai Research Institute of Petrochemical Technology SINOPEC, Shanghai 201208, China

Corresponding author: YUE Ying-Hong, yhyue@fudan.edu.cn
Received Date: 27 July 2015
Revised Date: 28 October 2015

Figures(8)

ZSM-5 nanosheets with Si/Al molar ratios of 18, 26 and 95 have been synthesized hydrothermally using [C₁₈H₃₇-N⁺(CH₃)₂-C₆H₁₂-N⁺(CH₃)₂-C₆H₁₃]Br₂ as a template and then ion-exchanged with Cu²⁺ cations. The obtained Cu-ZSM-5 nanosheets were characterized by XRF, N₂ adsorption-desorption, XRD, SEM, TEM, DRIFTS, H₂-TPR, O₂-TPD and CO-DRIFT. Their catalytic performance for N₂O decomposition was investigated. The catalytic activity in terms of TOF for Cu-ZSM-5 nanosheets increases with the decreasing of the n_Si/n_Al, due to better reducibility of active Cu⁺ species, and better desorption capability of adsorbed oxygen on Cu-ZSM-5 nanosheets with lower n_Si/n_Al.
- Cu-ZSM-5,
- nanosheets,
- n_Si/n_Al,
- N₂O,
- catalytic decomposition
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Catalytic Decomposition of N₂O over Cu-ZSM-5 Nanosheets with Different n_Si/n_Al