Citation: CHEN Xiao-Li, ZHANG Xiao-Ge, GAO Lou-Jun, MA Hong-Yan. Syntheses, Crystal Structures and Properties of Two Lanthanide-Metal Complexes Based on Flexible 3′, 4′-Bis (terazol-5′-yl) phenoxy) isophthalic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 167-174. doi: 10.11862/CJIC.2016.009 shu

Syntheses, Crystal Structures and Properties of Two Lanthanide-Metal Complexes Based on Flexible 3′, 4′-Bis (terazol-5′-yl) phenoxy) isophthalic Acid

School of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan′an University, Yan′an, Shaanxi 716000, China

Corresponding author: CHEN Xiao-Li, chenxiaoli003@163.com
Received Date: 21 September 2015
Revised Date: 30 October 2015

Figures(7)

Two novel lanthanide metal complexes based on H₂btpa ligand, namely {[Ln (btpa)(H₂O)(OH)]·bpy}_n (Ln=Tb (1), Pr (2), H₂btpa=3′, 4′-bis (terazol-5′-yl) phenoxy) isophthalic acid, bpy=4, 4′-pyridine), have been synthesized and structurally characterized by elemental analyses, IR spectroscopy, powder X-ray diffraction and single-crystal X-ray diffraction analyses. They possess the same 2D network, which is constructed from binuclear lanthanide units cross-linked by btpa^2- ligands via μ₄:η¹, η², η¹, η² coordination mode with guest molecule bpy existing in the structure to form intermolecular hydrogen bond. Interestingly, the adjacent 2D networks are intercalated in a zipper fashion generating a 3D supramolecular structure through intermolecular hydrogen bonding. The luminescence experiments show that complex 1 exhibits typical Tb^Ⅲ-centered emissions in the visible region. CCDC: 1417525, 1; 1417526, 2.
- lanthanide,
- 3′, 4′-bis (terazol-5′-yl) phenoxy) isophthalic acid,
- crystal structure,
- luminescence
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