Citation: PAN Deng-Ke. Synthesis and Properties of the Hollow Magnetic Solid Based Catalyst Fe₃O₄@LDO[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 74-80. doi: 10.11862/CJIC.2016.007 shu

Synthesis and Properties of the Hollow Magnetic Solid Based Catalyst Fe₃O₄@LDO

PAN Deng-Ke ^1,2,

1.
Chongqing Municipal Educational Examinations Authority, Chongqing 401174, China
2.
Department of Applied Chemistry, College of Science, Chongqing Jiaotong University, Chongqing 400074, China

Received Date: 24 July 2015
Revised Date: 19 October 2015

Figures(6)

The mixed oxides based on layered double hydroxide (LDO) are novel solid base catalyst, and their modification and functionalization have received more and more interesting in the area of catalysis. In this paper, the hollow magnetic solid base catalyst has been (Fe₃O₄@LDO) synthesized by coating LDO onto the hollow Fe₃O₄ particles. The Fe₃O₄@LDO particles possess well defined core-shell structure with Mg-Al Mixed Oxides as the shell and hollow Fe₃O₄ particle as the core. Owing to its unique hollow structure, the Fe₃O₄@LDO particles possess high colloid stability, and showing promising application in homogeneous catalysis. In the Knoevenagel condensation of benzaldehyde with ethyl acetoacetate under solvent free conditions, the Fe₃O₄@LDO particles gave the highest activity with yield of 62% in 2 h, showing high catalytic activity. In the mean time, the Fe₃O₄@LDO particles have strong magnetic response, can be easily separated and recycled after a catalyst reaction.
- hollow magnetic particles,
- core shell structure,
- Fe₃O₄,
- LDO,
- solid base catalyst
1. [1]
  Fan G, Li F, Evans D G, et al. Chem. Soc. Rev., 2014, 43: 7040-7066 doi: 10.1039/C4CS00160E
2. [2]
  Lü W, Yang L, Fan B, et al. Chem. Eng. J., 2015, 263:309-316 doi: 10.1016/j.cej.2014.11.009
3. [3]
  Zhang Z, Liao M, Zeng H, et al. Fuel Process. Technol., 2014, 128:519-524 doi: 10.1016/j.fuproc.2014.08.015
4. [4]
  Jyothi T M, Raja T, Rao B S. J. Mol. Catal. A: Chem., 2001, 168:187-191 doi: 10.1016/S1381-1169(00)00527-6
5. [5]
  Zhang H, Qi R, Evans D G, et al. J. Solid State Chem., 2004, 177:772-780 doi: 10.1016/j.jssc.2003.09.009
6. [6]
  ZHANG Hui, XU Yan-Hong, EVANS D G, et al. Acta Chim. Sinica, 2004, 62:750-756
7. [7]
  Li L, Feng Y, Li Y, et al. Angew. Chem. Int. Ed., 2009, 48: 5888-5892 doi: 10.1002/anie.v48:32
8. [8]
  PANG Deng-Ke, ZHANG Hui. Chinese J. Inorg. Chem., 2011, 7:1341-1347
9. [9]
  Hu J, Chen M, Fang X, et al. Chem. Soc. Rev., 2011, 40: 5472-5491 doi: 10.1039/c1cs15103g
10. [10]
  Luo B, Xu S, Ma W, et al. J. Mater. Chem., 2010, 20:7107-7113 doi: 10.1039/c0jm00726a
11. [11]
  Sun Q, Ren Z, Wang R, et al. J. Nanopart. Res., 2011, 13: 213-220 doi: 10.1007/s11051-010-0020-5
12. [12]
  Chen Y, Xia H, Lu L, et al. J. Mater. Chem., 2012, 22:5006-5012 doi: 10.1039/c2jm15440d
13. [13]
  Deng H, Li X, Peng Q, et al. Angew. Chem. Int. Ed., 2005, 44:2782-2785 doi: 10.1002/(ISSN)1521-3773
14. [14]
  Gursky J A, Blough S D, Luna C, et al. J. Am. Chem. Soc., 2006, 128:8376-8377 doi: 10.1021/ja0612100
15. [15]
  Ebitani K, Motokura K, Mori K, et al. J. Org. Chem., 2006, 71(15):5440-5447 doi: 10.1021/jo060345l
16. [16]
  XI Yu-Sheng. Thesis for the Master of Beijing University of Chemical Technology. 2010.
17. [17]
  Kong L, Lu X, Bian X, et al. ACS Appl. Mater. Interfaces, 2011, 3:35-42 doi: 10.1021/am101077a
18. [18]
  Zhang H, Pan D, Zou K, et al. J. Mater. Chem., 2009, 19: 3069-3077 doi: 10.1039/b820176e
19. [19]
  Wang Z L, Wang E B, Gao L, et al. J. Solid State Chem., 2005, 178:736-741 doi: 10.1016/j.jssc.2004.11.005
20. [20]
  Gong C, Chen D, Jiao X, et al. J. Mater. Chem., 2002, 12: 1844-1847 doi: 10.1039/b201243j
21. [21]
  Liang X, Wang X, Zhuang J, et al. Adv. Funct. Mater., 2006, 16:1805-1813 doi: 10.1002/(ISSN)1616-3028
22. [22]
  Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. 5th Ed. New York: John Wiley and Sons, 1997.
23. [23]
  Yin Y, Zhou S, Chen M, et al. J. Colloid Interface Sci., 2011, 361:527-533 doi: 10.1016/j.jcis.2011.05.014
24. [24]
  Gunawan P, Xu R. Chem. Mater., 2009, 21:781-783 doi: 10.1021/cm803203x
25. [25]
  Pan D, Zhang H, Fan T, et al. Chem. Commun., 2011, 47: 908-910 doi: 10.1039/C0CC01313G
26. [26]
  SUN Xiao-Ming. Thesis for the Doctorate of Tsinghua University. 2005.
27. [27]
  Wang Z, Wu L, Chen M, et al. J. Am. Chem. Soc., 2009, 131:11276-11277 doi: 10.1021/ja903246e
28. [28]
  Liu S, Xing R, Lu F, et al. J. Phys. Chem. C, 2009, 113: 21042-21047 doi: 10.1021/jp907296n
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Properties of the Hollow Magnetic Solid Based Catalyst Fe₃O₄@LDO