Citation: PAN Deng-Ke. Synthesis and Properties of the Hollow Magnetic Solid Based Catalyst Fe₃O₄@LDO[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 74-80. doi: 10.11862/CJIC.2016.007 shu

Synthesis and Properties of the Hollow Magnetic Solid Based Catalyst Fe₃O₄@LDO

PAN Deng-Ke ^1,2,

1.
Chongqing Municipal Educational Examinations Authority, Chongqing 401174, China
2.
Department of Applied Chemistry, College of Science, Chongqing Jiaotong University, Chongqing 400074, China

Received Date: 24 July 2015
Revised Date: 19 October 2015

Figures(6)

The mixed oxides based on layered double hydroxide (LDO) are novel solid base catalyst, and their modification and functionalization have received more and more interesting in the area of catalysis. In this paper, the hollow magnetic solid base catalyst has been (Fe₃O₄@LDO) synthesized by coating LDO onto the hollow Fe₃O₄ particles. The Fe₃O₄@LDO particles possess well defined core-shell structure with Mg-Al Mixed Oxides as the shell and hollow Fe₃O₄ particle as the core. Owing to its unique hollow structure, the Fe₃O₄@LDO particles possess high colloid stability, and showing promising application in homogeneous catalysis. In the Knoevenagel condensation of benzaldehyde with ethyl acetoacetate under solvent free conditions, the Fe₃O₄@LDO particles gave the highest activity with yield of 62% in 2 h, showing high catalytic activity. In the mean time, the Fe₃O₄@LDO particles have strong magnetic response, can be easily separated and recycled after a catalyst reaction.
- hollow magnetic particles,
- core shell structure,
- Fe₃O₄,
- LDO,
- solid base catalyst
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Properties of the Hollow Magnetic Solid Based Catalyst Fe₃O₄@LDO