Citation: WANG Gui-Xian, CAO Ke-Li, CHEN Fei-Yan, FENG Yun-Long. Syntheses and Crystal Structures of Ni(Ⅱ) and Cd(Ⅱ) Coordination Polymers Based on 5-(4-(2,6-Di(pyrizin-2-yl)pyridin-4-yl)phenoxy)isophthalic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 43-48. doi: 10.11862/CJIC.2016.003 shu

Syntheses and Crystal Structures of Ni(Ⅱ) and Cd(Ⅱ) Coordination Polymers Based on 5-(4-(2,6-Di(pyrizin-2-yl)pyridin-4-yl)phenoxy)isophthalic Acid

1.
Department of chemistry and chemical engineering, Lishui University, Lishui, Zhejiang 323000, China
2.
Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, Zhejiang 321004, China

Corresponding author: FENG Yun-Long, sky37@zjnu.cn
Received Date: 12 June 2015
Revised Date: 12 September 2015

Figures(6)

Two new metal-organic coordination polymers {[NiL(H₂O)]·H₂O}_n (1), [CdL(phen)]_n (2) (H₂L=5-(4-(2,6-di(pyrizin-2-yl)pyridin-4-yl)phenoxy)isophthalic acid) have been synthesized under solvothermal conditions and characterized by single crystal X-ray diffraction analysis. Complex 1 features a (4,4)-connected 3D network. The carboxylate groups of the L^2- ligands bridges two Ni(Ⅱ) ions into one 1D chain, then the neighboring chains are further interconnected by the N atoms of the L^2- ligands to generate a 3D net. Complex 2 displays a (3,3)-connected 2D framework and further linked by π…π interactions between aromatic rings with a centroid-centroid distance of 0.365 2 nm into the final 3D net, in which the Cd(Ⅱ) is seven-coordinated in one-capped trigonol prismatic geometry. Thermogravimetric analyses (TGA) have been measured for 1 and 2. Luminescent properties of 2 were investigated. CCDC: 1406238, 1; 1406239, 2.
- coordination polymer,
- 5-(4-(2,6-di(pyrizin-2-yl)pyridin-4-yl)phenoxy)isophthalic acid,
- crystal structure,
- luminescent property
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沈阳化工大学材料科学与工程学院沈阳 110142