Citation: ZHANG Xue-Mei, YU Shan-Shan, ZHANG Hui, DUAN Hai-Bao. Magnetic and Relax-like Dielectric Response Behavior in a Charge-Transfer Crystal[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 25-33. doi: 10.11862/CJIC.2016.002 shu

Magnetic and Relax-like Dielectric Response Behavior in a Charge-Transfer Crystal

1.
School of Chemical and Material Engineering, Anhui Science and Technology University, Bengbu, Anhui 233100, China
2.
School of Environmental Science, Nanjing Xiaozhuang University, Nanjing 211171, China

Corresponding author: DUAN Hai-Bao, duanhaibao4660@163.com
Received Date: 27 July 2015
Revised Date: 16 October 2015

Figures(7)

Molecular rotation and orientation by applied electric field is one of the promising strategies for assembling the potential molecular dielectric rotors and relax-like dielectric. Here, a new charge transfer compound [C₁₀-DMPy][Ni(mnt)₂] (1) (C₁₀-DMPy⁺=1-decanel-N, N-dimethylpyridinium cation, mnt^2-=maleonitriledithiolate), which shows interesting dielectric relaxation process, is synthesized and characterized. The anions and cations of 1 are aligned into segregated stacks. There existed weakly charge-assisted hydrogen bonding interactions between the mobile organic cation and rigid [Ni(mnt)₂]^- anion. Large temperature-dependent dielectric constant values and dielectric relaxation process of 1 can be ascribed to the dynamic orientation motion of alkyl chain of the organic cation and charge transfer between anions and cations. The overall magnetic behavior of 1 corresponds to a paramagnetic system with ferromagnetic coupling interaction. CCDC: 1415204, 1.
- charge-transfer crystal,
- crystal structure,
- dielectric response,
- magnetic properties
1. [1]
  Wojnarowska Z, Knapik J, Diaz M, et al. Macromolecules, 2014,47:4056-4065 doi: 10.1021/ma5003479
2. [2]
  Arik E, Altan H, Esenturk O. J. Phys. Chem. A, 2014,118: 3081-3089 doi: 10.1021/jp500760t
3. [3]
  Xiao B, Zheng W, Dong Y L, et al. J. Phys. Chem. C, 2014, 118:5802-5809 doi: 10.1021/jp411167g
4. [4]
  Moynihan C T. Solid State Ionics, 1998,105:175-180 doi: 10.1016/S0167-2738(97)00462-1
5. [5]
  Petrovsky V, Manohar A, Dogan F. J. Appl. Phys., 2006,100: 014102(2 pages) doi: 10.1063/1.2206411
6. [6]
  Sheoran A, Sanghi S, Rani S, et al. J. Alloys Compd., 2009, 475:804-809 doi: 10.1016/j.jallcom.2008.08.006
7. [7]
  Roling B, Happe A, Funke K, et al. Phys. Rev. Lett., 1997, 78:2160-2163 doi: 10.1103/PhysRevLett.78.2160
8. [8]
  Ang C, Yu Z, Jing Z, et al. Phys. Rev. B, 2000,61:3922-3926 doi: 10.1103/PhysRevB.61.3922
9. [9]
  Thongbai P, Yamwong T, Maensiri S. Solid State Commun., 2008,147:385-387 doi: 10.1016/j.ssc.2008.06.020
10. [10]
  Pradhan D K, Choudhary R N P, Samantaray B K. Int. J. Electrochem. Sci., 2008,3:597-608
11. [11]
  Xu G C, Ma X M, Zhang L, et al. J. Am. Chem. Soc., 2010,132:9588-9590 doi: 10.1021/ja104263m
12. [12]
  ZHOU Qin-Qin, FU Da-Wei . Chinese J. Inorg. Chem., 2013,29(8):1696-1702
13. [13]
  Akutagawa T, Koshinaka H, Sato D, et al. Nat. Mater., 2009,8:342-347 doi: 10.1038/nmat2377
14. [14]
  Fu D W, Cai H L, Liu Y M, et al. Science, 2013,339:425-428 doi: 10.1126/science.1229675
15. [15]
  Fu D W, Song Y M, Wang G X, et al. J. Am. Chem. Soc., 2007,129:5346-5347 doi: 10.1021/ja0701816
16. [16]
  Fu D W, Dai J, Ge J Z, et al. Inorg. Chem. Commun., 2010, 13:282-285 doi: 10.1016/j.inoche.2009.12.003
17. [17]
  Rodríguez-Molina B, Pérez-Estrada S, Garcia-Garibay M A, J. Am. Chem. Soc., 2013,135:10388-10395 doi: 10.1021/ja4024463
18. [18]
  Jiang X, Rodríguez-Molina B, Nazarian N, et al. J. Am. Chem. Soc., 2014,136:8871-8874 doi: 10.1021/ja503467e
19. [19]
  Kottas G S, Clarke L I, Horinek D, et al. Chem. Rev., 2005, 105:1281-1376 doi: 10.1021/cr0300993
20. [20]
  Kaszynski P, Friedli A C, Michl J. J. Am. Chem. Soc., 1992,114:601-620 doi: 10.1021/ja00028a029
21. [21]
  Winston E B, Lowell P J, Vacek J, et al. Phys. Chem. Chem. Phys., 2008,10:5188-5191 doi: 10.1039/b808104b
22. [22]
  Duan H B, Chen X R, Yang H, et al. Inorg. Chem., 2013,52:3870-3877 doi: 10.1021/ic302571p
23. [23]
  ZHOU Hong, YU Shan-Shan, DUAN Hai-Bao, et al. Chinese J. Inorg. Chem., 2013,29(7):1-10
24. [24]
  Duan H B, Ren X M, Meng Q J. Coord. Chem. Rev., 2010, 254:1509-1522 doi: 10.1016/j.ccr.2009.12.021
25. [25]
  Daun H B, Ren X M, Shen L J, et al. Dalton Trans., 2011,40:3622-3630 doi: 10.1039/c0dt01704c
26. [26]
  Davison A, Holm H R. Inorg. Synth., 1967,10:8-26
27. [27]
  XU Duo-Hui, SHENG Xiao-Li, LU Chang-Sheng, et al. Chinese J. Inorg. Chem. , 2012,28(5):888-892
28. [28]
  SMART and SAINT, Siemens Analytical X-ray Instrument Inc., Madison, WI, 1996.
29. [29]
  Sheldrick G M. SHELX-97, Program for the Refinement of Crystal Structure, University of G?ttingen[J]. Germany, 1997.
30. [30]
  wiergiel J, Jadzyn J. Ind. Eng. Chem. Res., 2011,50:11935-11941 doi: 10.1021/ie201172t
31. [31]
  Duan H B, Zhang X M, Zhou H. Synth. Met., 2014,15:294-298
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1.
沈阳化工大学材料科学与工程学院沈阳 110142