Citation: ZHANG Xue-Mei, YU Shan-Shan, ZHANG Hui, DUAN Hai-Bao. Magnetic and Relax-like Dielectric Response Behavior in a Charge-Transfer Crystal[J]. Chinese Journal of Inorganic Chemistry, ;2016, 32(1): 25-33. doi: 10.11862/CJIC.2016.002 shu

Magnetic and Relax-like Dielectric Response Behavior in a Charge-Transfer Crystal

1.
School of Chemical and Material Engineering, Anhui Science and Technology University, Bengbu, Anhui 233100, China
2.
School of Environmental Science, Nanjing Xiaozhuang University, Nanjing 211171, China

Corresponding author: DUAN Hai-Bao, duanhaibao4660@163.com
Received Date: 27 July 2015
Revised Date: 16 October 2015

Figures(7)

Molecular rotation and orientation by applied electric field is one of the promising strategies for assembling the potential molecular dielectric rotors and relax-like dielectric. Here, a new charge transfer compound [C₁₀-DMPy][Ni(mnt)₂] (1) (C₁₀-DMPy⁺=1-decanel-N, N-dimethylpyridinium cation, mnt^2-=maleonitriledithiolate), which shows interesting dielectric relaxation process, is synthesized and characterized. The anions and cations of 1 are aligned into segregated stacks. There existed weakly charge-assisted hydrogen bonding interactions between the mobile organic cation and rigid [Ni(mnt)₂]^- anion. Large temperature-dependent dielectric constant values and dielectric relaxation process of 1 can be ascribed to the dynamic orientation motion of alkyl chain of the organic cation and charge transfer between anions and cations. The overall magnetic behavior of 1 corresponds to a paramagnetic system with ferromagnetic coupling interaction. CCDC: 1415204, 1.
- charge-transfer crystal,
- crystal structure,
- dielectric response,
- magnetic properties
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1.
沈阳化工大学材料科学与工程学院沈阳 110142