Citation: LI Yan-Jiao, YAN Li-Fei, ZHENG Hua-Yan, LI Zhong. Effects of Acid Treatment on Pore Structure and Oxidation Carbonylation Performance of CuY Catalysts[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2315-2323. doi: 10.11862/CJIC.2015.313 shu

Effects of Acid Treatment on Pore Structure and Oxidation Carbonylation Performance of CuY Catalysts

1.
Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024

Corresponding author: LI Zhong,
Received Date: 15 May 2015
Available Online: 19 October 2015
Fund Project: 国家自然科学基金(No.21276169)资助项目。 (No.21276169)

The NaY zeolite with n_Si/n_Al=2.65 was treated by oxalic acid aqueous solutions and used as supports to prepare CuY catalysts by liquid ion exchange for oxidative carbonylation of methanol to dimethyl carbonate (DMC) in atmospheres condition. The NaY zeolites and their corresponding CuY catalysts were characterized intensively by N₂ adsorption-desorption, TEM, XRD, ²⁹Si MAS NMR, NH₃-TPD, Py-FTIR and H₂-TPR. The results revealed that framework aluminum was leached out by acid, resulting in increase of the framework n_Si/n_Al ratio, decrease of the relative crystallinity, and formation of mesopores which are favor for diffusion of the products molecules and significantly affect the catalytic activity. Compared with the untreated sample, CuY catalysts treated by 4 h, 0.2 mol·L^-1 oxalic acid exhibited higher catalytic performance with the increased space-time yield to DMC and conversion of methanol of 184.9 mg·g^-1·h^-1 and 10.2% from 103.6 mg·g^-1 ·h^-1 and 6.3% respectively. It is found the formed mesopores in CuY catalyst enhance the accessibility of Cu active sites by reactants and the diffusion of reactants and products molecules.
- CuY catalysts;oxidative carbonylation;acid treatment;pore structure
1. [1]
  [1] Aricò F, Tundo P. Russ. Chem. Rev., 2010,79(6):479-489
2. [2]
  [2] Selva M, Perosa A. Green Chem., 2008,10(4):457-464
3. [3]
  [3] Keller N, Rebmann G, Keller V. J. Mol. Catal. A: Chem., 2010,317(1/2):1-18
4. [4]
  [4] Zhang Y H, Drake I J, Briggs D N, et al. J. Catal., 2006,244 (2):219-229
5. [5]
  [5] Zhang Y H, Briggs D N, Desmit E, et al. J. Catal., 2007,251 (2):443-452
6. [6]
  [6] Zhang Y H, Bell A T. J. Catal., 2008,255(2):153-161
7. [7]
  [7] Richter M, Fait M J G, Eckelt R, et al. J. Catal., 2007,245 (1):11-24
8. [8]
  [8] Richter M, Fait M J G, Eckelt R, et al. Appl. Catal. A: Envi- ronmental., 2007,73(3/4):269-281
9. [9]
  [9] LI Zhong(李忠), FU Ting-Jun(付廷俊), ZHENG Hua-Yan(郑华艳), et al. Chinese J. Inorg. Chem.(无机化学学报), 2011, 27(08):1483-1490
10. [10]
  [10] Milina M, Mitchell S, Michels N L, et al. J. Catal., 2013,308 (0):398-407
11. [11]
  [11] Cho K, Cho H S, De Ménorval L C, et al. Chem. Mater., 2009, 21(23):5664-5673
12. [12]
  [12] Park D H, Kim S S, Wang H, et al. Angew. Chem., 2009, 121(41):7781-7784
13. [13]
  [13] García-Martínez J, Johnson M, Valla J, et al. Catal. Sci. Technol., 2012,2(5):987-994
14. [14]
  [14] Dimitrijevic R, Lutz W,Ritzmann A. J. Phys. Chem. Solids, 2006,67(8):1741-1748
15. [15]
  [15] Cairon O. Chemphyschem, 2013,14(1):244-251
16. [16]
  [16] Matias P, Lopes J M, Ayrault P, et al. Appl. Catal. A: Gen., 2009,365(2):207-213
17. [17]
  [17] Baran R, Millot Y, Onfroy T, et al. Microporous Mesoporous Mater., 2012,163:122-130
18. [18]
  [18] Kao H M, Chang P C. J. Phys. Chem. B, 2006,110(39):19104 -19107
19. [19]
  [19] Lónyi F, Valyon J, Pál-Borbély G. Microporous Mesoporous Mater., 2003,66(2/3):273-282
20. [20]
  [20] López-Fonseca R, De Rivas B, Gutiérrez-Ortiz J I, et al. Appl. Catal. B: Environ., 2003,41(1/2):31-42
21. [21]
  [21] Bottari E, Ciavatta L. Gazz. Chim. Ital., 1968,98:1004-1013
22. [22]
  [22] Beyerlein R A, Choi-Feng C, Hall J B, et al. Top Catal., 1997,4(1/2):27-42
23. [23]
  [23] Huang S Y, Chen P Z, Yan, B, et al. Ind. Eng. Chem. Res., 2013,52(19):6349-6356
24. [24]
  [24] Qin Z X, Shen B J, Gao X H, et al. J Catal., 2011,278(2): 266-275
25. [25]
  [25] Gao Z, Tang Y, Zhu Y G. Appl. Catal., 1989,56(1):83-94
26. [26]
  [26] Schroeder K P, Sauer J. J. Phys. Chem., 1993,97(25):6579- 6581
27. [27]
  [27] Lippmaa E, Maegi M, Samoson A, et al. J. Am. Chem. Soc., 1981,103(17):4992-4996
28. [28]
  [28] Lutz W, Heidemann D, Hübert C, et al. Z. Anorg. Allg. Chem., 2001,627(11):2559-2564
29. [29]
  [29] Yan Z M, Ma D, Zhuang J Q, et al. J. Mol. Catal. A: Chem., 2003,194(1/2):153-167
30. [30]
  [30] Gore K U, Abraham A, Hegde S G, et al. J. Phys. Chem. B, 2002,106(23):6115-6120
31. [31]
  [31] Engelhardt G, Michel D. High-Resolution Solid-State NMR of Silicates and Zeolites. NewYork: John Wiley and Sons., 1987:499
32. [32]
  [32] Jin D, Hou Z, Zhang L, et al. Catal. Today, 2008,131(1/2/3/ 4):378-384
33. [33]
  [33] Barzetti T, Selli E, Moscotti D, et al. J. Chem. Soc. Faraday Trans., 1996,92(8):1401-1407
34. [34]
  [34] Emeis C A. J. Catal., 1993,141(2):347-354
35. [35]
  [35] Kieger S, Delahay G, Coq B, et al. J. Catal., 1999,183(2): 267-280
36. [36]
  [36] Herman R G, Lunsford J H, Beyer H, et al. J. Phys. Chem., 1975,79(22):2388-2394
37. [37]
  [37] Berthomieu D, Delahay G. Catal. Rev., 2006,48(3):269-313
38. [38]
  [38] Afzal M, Yasmeen G, Saleem M, et al. J. Therm. Anal. Calorim., 2000,62(1):277-284
39. [39]
  [39] Sato K, Nishimura Y, Matsubayashi N, et al. Microporous Mesoporous Mater., 2003,59(2/3):133-146
40. [40]
  [40] Maeda H, Kinoshita Y, Reddy K R, et al. Appl. Catal. A: Gen., 1997,163(1/2):59-69
41. [41]
  [41] Zhang P B, Huang S Y, Yang Y, et al. Catal. Today, 2010, 149(1/2):202/206
42. [42]
  [42] Hartmann M. Angew. Chem. Int. Ed., 2004,43(44):5880- 5882
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沈阳化工大学材料科学与工程学院沈阳 110142