Citation: YUAN En-Hui, XING Jun-Ling, PANG Jun-Ling, JIANG Shu-Hua, JIANG Jin-Gang, ZHANG Kun. Formation Mechanism of Highly Ordered MCM-48 via Phase Transformation[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2358-2364. doi: 10.11862/CJIC.2015.310 shu

Formation Mechanism of Highly Ordered MCM-48 via Phase Transformation

1.
1 Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China;
2.
2 Key Laboratory of Advanced Energy Materials Chemistry of Ministry Education, College of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: JIANG Jin-Gang, ZHANG Kun,
Received Date: 1 July 2015
Available Online: 10 October 2015
Fund Project: 国家自然科学基金(No.21573074,21373004,21003050)资助项目。 (No.21573074,21373004,21003050)

Highly ordered mesoporous molecular sieve MCM-48 with Ia3d cubic structure was hydrothermally synthesized using new surfactant cetyltrimethylammonium tosylate (CTATos) as template via phase transformation (PT). Structural study by small angle X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HR-TEM) and nitrogen adsorption-desorption shows the time-dependent structural change in M41S mesoporous silica from MCM-41 to MCM-48 and MCM-50. The driving force for this transformation seems to be an increase of the local effective surfactant packing parameter (g), which resulted from the leaching of surfactant counter anions (Tos^-) in the pore with the prolongation of the reaction time. One-dimensional solid state ²⁹Si NMR spectra, X-ray diffraction patterns, and infrared spectra show the progression of molecular organization in the self-assembled mesophases from structures with initially amorphous silica networks into sheets with very high degrees of atomic order when the phase transformation is happening. The finally obtained self-assembled lamellar silica-surfactant mesophase composites with crystal-like ordering in the silica frameworks can be an ideal precursor to fabricate the three-dimensional microporous zeolites with the expanded pore size.
- mesoporous materials;MCM-48;phase transformation;cationic surfactant;sol-gel soft-templating;lamella or layered phase;atomic ordering
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