Citation: GUO Hai-Fu, LEI Jia-Mei, MA De-Yun. Syntheses, Crystal Structures and Fluorescent Properties of Two 2D Cadmium(Ⅱ) Coordination Polymers[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2385-2392. doi: 10.11862/CJIC.2015.307 shu

Syntheses, Crystal Structures and Fluorescent Properties of Two 2D Cadmium(Ⅱ) Coordination Polymers

GUO Hai-Fu ^1,, ,
LEI Jia-Mei ^1,2 ,
MA De-Yun ¹

1.
1 College of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing, Guangdong 526061, China;
2.
2 Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051, China

Corresponding author: GUO Hai-Fu,
Received Date: 14 July 2015
Available Online: 9 October 2015
Fund Project: 广东省自然科学基金(No.2015A030310407) (No.2015A030310407) 粤西林产化工技术开发与应用研究中心项目(No. 2014KTSPT040)资助。 (No. 2014KTSPT040)

Two new 2D cadmium(Ⅱ) coordination polymers, [Cd₂(FDCA)₂(DMA)₂(DMF)]_n (1) and [Cd₃(FDC)₃(DMF)₄(H₂O)]_n (2) (H₂FDC=2,5-furandicarboxylic acid, DMA=N, N-dimethylacetamide, DMF=N, N-dimethylformamide), have been successfully synthesized under solvothermal conditions and characterized by elemental analysis, IR-spectroscopy, thermogravimetric analysis, and single-crystal X-ray diffraction. The results reveal that both complexes 1 and 2 form 2D net structures, which are further linked to form 3D supramolecular structures via intermolecular C-H…O hydrogen bonding interactions. In solid state, 1 and 2 emit the intensely indigotin photoluminescence (501 and 476 nm) at room temperature.
- solvothermal syntheses;cadmium ions;crystal structure;characterization;photoluminescence
1. [1]
  [1] XUE Ming(薛铭), CHEN Si-Ru(陈思如), GUO Li-Jia (郭莉佳), et al. Chem. J. Chinese Universities(高等学校化学学报), 2012,33(9):1889-1894
2. [2]
  [2] YIN Ming-Cai(尹明彩), LI Ming(李明), YUAN Liang-Jie (袁良杰), et al. Chinese J. Lumin.(发光学报), 2005,26(14): 448-453
3. [3]
  [3] XUE Ming(薛铭), LI Yang-Xue(李阳雪), HUANG Lin (黄麟), et al. Chem. J. Chinese Universities(高等学校化学学报), 2011,32(3):515-518
4. [4]
  [4] YANG Xiao-Jing(杨骁婧), BAO Song-Song(鲍松松), ZHENG Li-Min(郑丽敏). Chinese J. Inorg. Chem.(无机化学学报), 2013,29(3):621-627
5. [5]
  [5] LIU Guang-Xiang(刘光祥). Chinese J. Inorg. Chem.(无机化学学报), 2013,29(9):1914-1920
6. [6]
  [6] NA Li-Yan(那立艳), JIANG Hui-Ming(姜慧明), YANG Bao- Ling(杨宝灵), et al. Chem. J. Chinese Universities(高等学校化学学报), 2007,28(8):1437-1439
7. [7]
  [7] CHEN Chi(陈驰), PANG Jun(庞军), HAN Shuang(韩爽), et al. Acta Phys.-Chim. Sin.(物理化学学报), 2012,28(1): 189-194
8. [8]
  [8] Horcajada P, Chalati T, Serre C, et al. Nat. Mater., 2010,9: 172-178
9. [9]
  [9] Rocca J D, Liu D M, Lin W B. Acc. Chem. Res., 2011,44 (10):957-968
10. [10]
  [10] Du M, Zhang Z H, Wang X G, et al. CrystEngComm, 2008,10:1855-1865
11. [11]
  [11] Ma J F, Liu J F, Xing Y, et al. Dalton Trans., 2000:2403-2407
12. [12]
  [12] Eddaoudi M, Moler D B, Li H L, et al. Acc. Chem. Res., 2001,34:319-330
13. [13]
  [13] Xuan W M, Zhu C F, Liu Y, et al. Chem. Soc. Rev., 2012,41:1677-1695
14. [14]
  [14] LI Xiu-Mei(李秀梅), QU Xiu-Jun(曲秀君), NIU Yan-Ling (牛艳玲), et al. J. Tonghua Teachers College(通化师范学院学报), 2010,31(4): 34-35
15. [15]
  [15] Carlos C C, Adriana E R, Adrián P H, et al. Z. Anorg. Allg. Chem., 2013,639(7):1122-1128
16. [16]
  [16] Sheldrick G M. SHELXL-97, Program for Crystal Structure Determination, University of Göttingen, Germany, 1997.
17. [17]
  [17] You Z L, Zhu H L, Liu W S. Z. Anorg. Allg. Chem., 2004,630:1617-1622
18. [18]
  [18] Michaelides A, Skoulika S, Siskos M G. Chem. Commun., 2004,21:2418-2419
19. [19]
  [19] QIN Liang(覃亮), MA De-Yun(马德运), LU Kuan(路宽). Chinese J. Struct. Chem.(结构化学), 2012,31(9):1235-1240
20. [20]
  [20] Sen R, Mal D, Brandao P, et al. Cryst. Growth Des., 2013,13(12):5272-5281
21. [21]
  [21] Dias A B, Viswanathan S. Chem. Commun., 2004,21:1024- 1025
1. [1]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
2. [2]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
3. [3]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
4. [4]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
5. [5]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
6. [6]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
7. [7]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
8. [8]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
9. [9]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
10. [10]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
11. [11]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
12. [12]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
13. [13]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
14. [14]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
15. [15]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
16. [16]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
17. [17]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
18. [18]
  Zitong Chen , Zipei Su , Jiangfeng Qian . Aromatic Alkali Metal Reagents: Structures, Properties and Applications. University Chemistry, 2024, 39(8): 149-162. doi: 10.3866/PKU.DXHX202311054
19. [19]
  Dongju Zhang . Exploring the Descriptions and Connotations of Basic Concepts of Teaching Crystal Structures. University Chemistry, 2024, 39(3): 18-22. doi: 10.3866/PKU.DXHX202304003
20. [20]
  Hongwei Ma , Hui Li . Three Methods for Structure Determination from Powder Diffraction Data. University Chemistry, 2024, 39(3): 94-102. doi: 10.3866/PKU.DXHX202310035

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(134)
HTML views(2)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142