Citation: LIU Jia-Bin, ZHANG Hui, CUI Yan-Hua, LIU Xiao-Jiang, LIU Jin-Song. Pulsed Laser Deposited NiCo₂S₄ Thin Films and Investigation of Their Electrochemical Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2331-2336. doi: 10.11862/CJIC.2015.306 shu

Pulsed Laser Deposited NiCo₂S₄ Thin Films and Investigation of Their Electrochemical Properties

1.
1 Institute of Electronic Engineering, China Academy of Engineering Physics, Mianyang, Sichuan 621000, China;
2.
2 School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang, Sichuan 621000, China

Corresponding author: CUI Yan-Hua, LIU Xiao-Jiang,
Received Date: 10 March 2015
Available Online: 16 September 2015
Fund Project: 中国工程物理研究院科学技术基金(No.2013A0302014) (No.2013A0302014)中国工程物理研究院超精密加工技术重点实验室基金(No.ZZ13007)资助项目。 (No.ZZ13007)

NiCo₂S₄ thin films have been successfully prepared by pulsed laser deposition. The structural, electrochemical properties and reaction mechanism of the NiCo₂S₄ thin film anodes for lithium ion batteries have been investigated by transmission electron microscopy (TEM), selected-area electron diffraction measurements (SAED), the charge/discharge measurements and cyclic voltammetry (CV). The charge/discharge results suggested that in the range of 0~3.0 V(vs Li⁺/Li), the reversible discharge capacity was 698 mAh·g^-1 at a current density of 3 μA·cm^-2. After 200 cycles, the discharge capacity was 365 mAh·g^-1. Multistep reactions are revealed by the CV data of NiCo₂S₄ thin films. Ex situ TEM results showed that NiCo₂S₄ could react with Li to form Li₂S, Co and Ni during initial discharging and NiS and CoS formed upon charging. The reversible electrochemical reacting occurred between NiS, CoS and Li₂S, Co, Ni during the following cycles. NiCo₂S₄ was believed to be a promising anode material for rechargeable lithium batteries due to its good cycle performance.
- NiCo₂S₄ thin films;pulsed laser deposition;anode;lithium ion batteries
1. [1]
  [1] Tarascon J M, Armand M. Nature, 2001,414:359-367
2. [2]
  [2] Geng H, Kong S F, Wang Y. J. Mater. Chem. A, 2014,2: 15152-15158
3. [3]
  [3] Ruan H C, Li Y F, Qiu H Y, et al. J. Alloys Compd., 2014, 588:357-360
4. [4]
  [4] Mi L W, Chen Y F, Wei W T, et al. RSC Adv., 2013,3: 17431-17439
5. [5]
  [5] Gu Y, Xu Y, Wang Y. ACS Appl. Mater. Inter., 2013,5:801- 806
6. [6]
  [6] Wang Q H, Jiao L F, Du H M, et al. J. Mater. Chem., 2011,2:327-329
7. [7]
  [7] Wang Y, Wu J J, Tang Y F, et al. ACS Appl. Mater. Interfaces, 2012,4:4246-4250
8. [8]
  [8] Sen U K, Mitra S. J. Solid State Electrochem., 2014,18:2701 -2708
9. [9]
  [9] Zhang Z, Zhou C K, Huang L, et al. Electrochim. Acta, 2013,114:88-94
10. [10]
  [10] Liu S Y, Lu X, Xie J, et al. ACS Appl. Mater. Interfaces, 2013,5:1588-1595
11. [11]
  [11] Lee J O, Seo J U, Song J H, et al. Electrochem. Commun., 2013,28:71-74
12. [12]
  [12] Li J J, Shen J, Li Z Q, et al. Mater. Lett., 2013,92:330- 333
13. [13]
  [13] Yang X, Xu J, Xi L J, et al. J. Nanopart. Res., 2012,14:931
14. [14]
  [14] Zhou W H, Zhou Y L, Feng J, et al. Chem. Phys. Lett., 2012,546:115-119
15. [15]
  [15] Yin X S, Tang C H, Chen M H, et al. J. Mater. Chem. A, 2013,1:7927-7932
16. [16]
  [16] Tang X S, Yao X Y, Chen Y, et al. J. Power Sources, 2014,257:90-95
17. [17]
  [17] Wan H Z, Jiang J J, Yu J W, et al. CrystEngComm, 2013, 15:7649-7651
18. [18]
  [18] Yang J Q, Guo W, Li D, et al. Electrochim. Acta, 2014,144: 16-21
19. [19]
  [19] Chen H C, Jiang J J, Zhang L, et al. J. Power Sources, 2014,254:249-257
20. [20]
  [20] ZHANG Hua(张华), ZHOU Yong Ning(周永宁), WU Xiao Jing(吴晓京), et al. Acta Phys.-Chim. Sin.(物理化学学报), 2008,24:1287-1291
21. [21]
  [21] Jamnik J, Maier J. Phys. Chem. Chem. Phys., 2003,5:5215- 5220
22. [22]
  [22] Zhukovskii Y F, Kotomin E A, Balaya P, et al. Solid State Sci., 2008,10:491-495
23. [23]
  [23] Yu X Q, Sun J P, Tang K, et al. Phys. Chem. Chem. Phys., 2009,11:9497-9503
24. [24]
  [24] Dai H Q, Zhou Y N, Sun Q, et al. Electrochim. Acta, 2012,76:145-515
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Pulsed Laser Deposited NiCo₂S₄ Thin Films and Investigation of Their Electrochemical Properties