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Citation: LIU Jia-Bin, ZHANG Hui, CUI Yan-Hua, LIU Xiao-Jiang, LIU Jin-Song. Pulsed Laser Deposited NiCo2S4 Thin Films and Investigation of Their Electrochemical Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2331-2336. doi: 10.11862/CJIC.2015.306 shu

Pulsed Laser Deposited NiCo2S4 Thin Films and Investigation of Their Electrochemical Properties

  • 1.

    1 Institute of Electronic Engineering, China Academy of Engineering Physics, Mianyang, Sichuan 621000, China;

  • 2.

    2 School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang, Sichuan 621000, China

  • Corresponding author: CUI Yan-Hua,  LIU Xiao-Jiang, 
  • Received Date: 10 March 2015
    Available Online: 16 September 2015

    Fund Project: 中国工程物理研究院科学技术基金(No.2013A0302014) (No.2013A0302014)中国工程物理研究院超精密加工技术重点实验室基金(No.ZZ13007)资助项目。 (No.ZZ13007)

  • NiCo2S4 thin films have been successfully prepared by pulsed laser deposition. The structural, electrochemical properties and reaction mechanism of the NiCo2S4 thin film anodes for lithium ion batteries have been investigated by transmission electron microscopy (TEM), selected-area electron diffraction measurements (SAED), the charge/discharge measurements and cyclic voltammetry (CV). The charge/discharge results suggested that in the range of 0~3.0 V(vs Li+/Li), the reversible discharge capacity was 698 mAh·g-1 at a current density of 3 μA·cm-2. After 200 cycles, the discharge capacity was 365 mAh·g-1. Multistep reactions are revealed by the CV data of NiCo2S4 thin films. Ex situ TEM results showed that NiCo2S4 could react with Li to form Li2S, Co and Ni during initial discharging and NiS and CoS formed upon charging. The reversible electrochemical reacting occurred between NiS, CoS and Li2S, Co, Ni during the following cycles. NiCo2S4 was believed to be a promising anode material for rechargeable lithium batteries due to its good cycle performance.
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