Citation: HUANG Ting-Hong, YAN Jie, YANG Hu, ZENG Xian-Guang, YANG Yan. Copper(Ⅰ) Coordination Polymers with Extended π…π Interactions: Syntheses, Structures, Characterization and Luminescent Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2393-2400. doi: 10.11862/CJIC.2015.305 shu

Copper(Ⅰ) Coordination Polymers with Extended π…π Interactions: Syntheses, Structures, Characterization and Luminescent Properties

1.
Material Corrosion and Protection Key Laboratory of Sichuan province, College of Materials and Chemical Engineering, Sichuan University of Science & Engineering, Zigong, Sichuan 643000, China

Corresponding author: HUANG Ting-Hong,
Received Date: 29 May 2015
Available Online: 29 September 2015
Fund Project: 四川理工学院人才引进项目(No.2014RC29) (No.2014RC29)四川省教育厅重点项目(No.15ZA0223) (No.15ZA0223)材料腐蚀与防护四川省重点实验室开放基金 (No.2015CL03)资助。 (No.2015CL03)

Two copper(Ⅰ) coordination polymers, {[Cu₂(4-bpo)₂(CH₃CN)₂(PPh₃)₂](BF₄)₂}_n (1), {[Cu(4-bpo)(CH₃CN)(dppe)_0.5]BF₄}_n (2) (PPh₃=triphenylphosphine, dppe=1,2-bis(diphenyl phosphino)ethane, 4-bpo=2,5-bis(4-pyridyl)-1,3,4-oxadiazole), have been synthesized and characterized by IR, ¹H NMR, ¹⁹F NMR, ¹¹B NMR, elemental analysis and X-ray crystal structure analysis. The structural analysis shows that complexes 1 and 2 consist of diverse and interesting 2D supramolecular structures formed by inter-chain interactions. For 1, π-stacking interactions result in the construction of 1D bilayer chain and 2D supramolecular network. Compound 2 exhibits a 1D ladder-like chain and a 1D+1D→2D/3D supramolecular structure formed by π-stacking interactions. Solid-state emission spectra of complexes 1 and 2 have been studied, displaying the existence of ILCT/MLCT excited states.
- copper(Ⅰ) coordination polymers;crystal structures;π…π interaction;luminescent properties 0 Introduction
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沈阳化工大学材料科学与工程学院沈阳 110142