Citation: LIU Zhen-Xiang, CHEN Yun, LUO Xiao-Hui, DIAO Yin-Jun, WU Chang-Sheng. Syntheses, Crystals and Luminescence of Silver(Ⅰ) Complexes with Metal-Olefin Binding Interactions[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2291-2297. doi: 10.11862/CJIC.2015.304 shu

Syntheses, Crystals and Luminescence of Silver(Ⅰ) Complexes with Metal-Olefin Binding Interactions

1.
College of Pharmaceutics and Materials Engineering, Jinhua Polytechnic, Jinhua, Zhejiang 321017, China

Corresponding author: LIU Zhen-Xiang,
Received Date: 18 June 2015
Available Online: 29 September 2015
Fund Project: 浙江省教育厅项目(No.Y201430862,FX2013215) (No.Y201430862,FX2013215)2014年浙江省大学生科技创新活动计划暨新苗人才计划项目(No.2014R465011)资助。 (No.2014R465011)

One new alkene complexe of silver(Ⅰ), [AgL(NO₃)]_n (1), (L=4-allyl-2-methoxyphenyl nicotinate) has been prepared by self-assembly of AgNO₃ with 4-allyl-2-methoxyphenyl nicotinate (L) in THF/H₂O system. The structures of compounds L and 1 are determined by X-ray diffraction analysis. The crystals of the two compounds belong to the monoclinic space group. Compound L is connected to form a dimer, 2D layer sequentially by the weak C-H…O hydrogen bonds. The structure of 1 consists of 1D left-handed helical chains of [AgL]_∞ in which the allyl arms and N atoms are coordinated to silver atoms, and right-handed helical chains of [AgNO₃]_∞ connecting through the Ag-O weak interactions. Two kinds of helices are connected in …ABAB… fashion to form a 2D achiral layer. Finally, the resulted 2D net extents to the 3D supramolecular architecture by the weak C-H…O interactions. In addition, the photoluminescence of L and 1 has been investigated in detail.
- 4-allyl-2-methoxyphenyl nicotinate;silver-alkene interaction;silver complex,weak interactions;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142