Citation: DUAN Hong-Zhen, CHEN Guo-Hong, ZHOU Fang-Ling, LI Qiao-Ling, ZHAO Li-Ping. Preparation and Properties of Nickel Substituted Cobalt Ferrite Hollow Microspheres[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2181-2187. doi: 10.11862/CJIC.2015.296 shu

Preparation and Properties of Nickel Substituted Cobalt Ferrite Hollow Microspheres

1.
Department of Chemistry, School of Science, North University of China, Taiyuan 030051, China

Corresponding author: DUAN Hong-Zhen,
Received Date: 7 June 2015
Available Online: 24 September 2015
Fund Project: 国家自然科学基金(No.20871108,51272239)资助项目。 (No.20871108,51272239)

Nano-structure Ni_xCo_1-xFe₂O₄ (x=0, 0.3, 0.5, 0.7, 1) microspheres were synthesized in ethylene glycol (EG) solution, using FeCl₃·6H₂O, CoCl₂·6H₂O, NiCl₂·H₂O and NH₄Ac as the starting materials through solvothermal method. The influence of the amount of Ni²⁺ on the magnetic and absorbing properties was studied. The structure, morphology, magnetic properties and wave absorbing properties of the products were characterized by XRD, SEM, TEM, Vibration sample magnetometer (VSM) and network vector analyzer. Results show that monodispersed Ni_xCo_1-xFe₂O₄ hollow microsphere ferrites are single-crystal cubic spinel structure with the average diameter of 200 nm． When x=0, the value of maximum saturation magnetization is 81.7 emu·g^-1 and the reflection loss in 1 658.8 MHz has a minimum value of -16.9 dB.
- ferrite;hollow spheres;hydrothermal method;preparation;electromagnetic properties
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沈阳化工大学材料科学与工程学院沈阳 110142