Citation: LI Xiao-Jing, XU Zhou-Qing, XU Jun, WU Wei-Na, FAN Yun-Chang. Cu(Ⅱ), Zn(Ⅱ) and Cd(Ⅱ) Complexes with Picolinamide Azine Derived from 2-Acetyl Pyridine and 2-Picolinamide Hydrazone: Crystal Structures and Fluorescence Properties[J]. Chinese Journal of Inorganic Chemistry, ;2015, (12): 2418-2424. doi: 10.11862/CJIC.2015.292 shu

Cu(Ⅱ), Zn(Ⅱ) and Cd(Ⅱ) Complexes with Picolinamide Azine Derived from 2-Acetyl Pyridine and 2-Picolinamide Hydrazone: Crystal Structures and Fluorescence Properties

1.
Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo, Henan 454000, China

Corresponding author: XU Jun, FAN Yun-Chang,
Received Date: 16 July 2015
Available Online: 13 September 2015
Fund Project: 国家自然科学基金(No.21404033, 21401046, 21001040) (No.21404033, 21401046, 21001040) 河南省教育厅自然科学基金(No.12B150011, 14B150029)资助项目。 (No.12B150011, 14B150029)

Three complexes [(Cu)(L)(Cl)₂](1), [(Zn)(L)(Cl)₂](2) and {[(Cd)₂(L)(I)₄]}_n(3) (L is derived from 2-acetyl pyridine and picolinamide hydrazone) have been synthesized and characterized by single-crystal X-ray diffraction, elemental analysis and IR spectroscopy. X-ray diffraction analysis results show that complexes 1 and 2 are isostructural. The coordination geometry of the metal ion in each complex is a distorted trigonal biyramid with three nitrogen atoms from the ligand L and two chloride anions. However, in complex 3, two adjacent five-coordinated Cd(Ⅱ) ion are connected by two bridged μ₂-I^- anions, resulting in the formation of one-dimensional chain along c axis. In addition, the thermal stability and luminescent properties of the complexes are also studied in detail.
- picolinamide azine;complex ;fluorescence;crystal structure;thermostability
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沈阳化工大学材料科学与工程学院沈阳 110142