Citation: YANG Yu-Ting, TU Chang-Zheng, MIAO Jiao-Jiao, LI Jun-Li, CHEN Guang. Two Different Co(Ⅱ) Interpenetrating Networks Based on a Flexible Dicarboxylic Acid and Different Bis(imidazole) Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2111-2118. doi: 10.11862/CJIC.2015.291 shu

Two Different Co(Ⅱ) Interpenetrating Networks Based on a Flexible Dicarboxylic Acid and Different Bis(imidazole) Ligands

1.
College of Chemistry and Chemical Engineering, Qujing Normal University, Qujing, Yunnan 655011, China

Corresponding author: YANG Yu-Ting,
Received Date: 4 August 2015
Available Online: 22 September 2015
Fund Project: 云南省科技厅应用基础研究项目(No.201401CB00299)资助。 (No.201401CB00299)

Two interpenetrating networks, namely {[Co(bimb)(L)]·H₂O}_n(1) and {[Co(bbix)(L)]₂}_n(2) (H₂L=4,4'-(2,2'-oxybis(ethane-2,1-diyl)bis(oxy))dibenzoic acid, bimb=1,1'-(1,4-butanediyl)bis(imidazole), bbix=1,4-bis(benzimidazole-1-ylmethyl)-benzene) have been prepared under hydrothermal condition by varying the bis(imidazole) coligands. Single crystal X-ray diffraction indicates that complex 1 displays 2D→3D 3-fold interpenetrating framework with 4-connected sql topology; 2 shows a 3D 4-connected framework of 6⁶ dia topology with 6-fold interpenetration. The results indicate that the shapes of bis(imidazole) coligands have an important effect on the interpenetrating characters and ultimate frameworks. Moreover, the thermal and magnetic properties of the two complexes have also been studied.
- interpenetration;flexible;bis(imidazole);topology;magnetic properties
1. [1]
  [1] Jiang H L, Makal T A, Zhou H C. Coord. Chem. Rev., 2013,257:2232-2249
2. [2]
  [2] He W W, Li S L, Zang H Y, et al. Coord. Chem. Rev., 2014,279:141-160
3. [3]
  [3] Elsaidi S K, Mohamed M H, Wojtas L, et al. J. Am. Chem. Soc., 2014,136:5072-5077
4. [4]
  [4] (a) Park J H, Lee W R, Kim Y, et al. Cryst. Growth Des., 2014,14:699-704
5. [5]
  (b) Wang Z J, Qin L, Zhang X, et al. Cryst. Growth Des., 2015,15:1303-1310
6. [6]
  (c) Ju P, Jiang L, Lu T B. Inorg. Chem., 2015,54:6291-6295
7. [7]
  [5] (a) Batten S R, Robson R. Angew. Chem. Int. Ed., 1998,37: 1460-1494
8. [8]
  (b) Batten S R. CrystEngComm, 2001,3:67-73
9. [9]
  (c) Carlucci L, Ciani G, Proserpio D M. Coord. Chem. Rev., 2003,246:247-289
10. [10]
  [6] Shi P F, Xiong G, Zhao B, et al. Chem. Commun., 2013,49: 2338-2340
11. [11]
  [7] Rowsell J L C, Yaghi O M. Angew. Chem. Int. Ed., 2005,44: 4670-4679
12. [12]
  [8] Ren C X, Zheng A L, Cai L X, et al. CrystEngComm, 2014,16:1038-1043
13. [13]
  [9] Chen P K, Batten S R, Qi Y, et al. Cryst. Growth Des., 2009, 9:2756-2761
14. [14]
  [10] Miller J S. Adv. Mater., 2001,13:525-527
15. [15]
  [11] Chu Q, Su Z, Fan J, et al. Cryst. Growth Des., 2011,11: 3885-3894
16. [16]
  [12] Sun G M, Luo F, Song Y M, et al. Dalton Trans., 2012,41: 11559-11561
17. [17]
  [13] Qi Y, Che Y X, Batten S R, et al. CrystEngComm, 2008,10: 1027-1030
18. [18]
  [14] Lan Y Q, Li S L, Qin J S, et al. Inorg. Chem., 2008,47: 10600-10610
19. [19]
  [15] Qi Y, Li Y H, Wang Y Z. Anorg. Allg. Chem., 2013,639: 2258-2262
20. [20]
  [16] Wang Y, Qi Y, Li Q, et al. Polyhedron, 2015,87:237-244
21. [21]
  [17] (a) Wen L L, Lu Z D, Lin J G, et al. Cryst. Growth Des., 2007,7:93-99
22. [22]
  (b) Li L L, Li H X, Ren Z G, et al. Dalton Trans., 2009,40: 8567-8573
23. [23]
  [18] Sheldrick G M. SHELXL-97, Programs for the Refinement of Crystal Structure, University of Göttingen, Göttingen, Germany, 1997.
24. [24]
  [19] (a) Wang Y, Zhao F H, Shi A H, et al. Inorg. Chem. Commun., 2012,20:23-26
25. [25]
  (b) Liu Y Y, Ma J F, Yang J, et al. Inorg. Chem., 2007,46: 3027-3037
26. [26]
  (c) Ma L F, Wang L Y, Wang Y Y, et al. Inorg. Chem., 2009,48:915-924
27. [27]
  [20] (a) Zhou H, Liu G X, Wang X F, et al. CrystEngComm, 2013,15:1377-1388
28. [28]
  (b) Mukherjee S, Samanta D, Mukherje P S. Cryst. Growth Des., 2013,13:5335-5343
1. [1]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
2. [2]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
3. [3]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
4. [4]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
5. [5]
  Qiaoqiao BAI , Anqi ZHOU , Xiaowei LI , Tang LIU , Song LIU . Construction of pressure-temperature dual-functional flexible sensors and applications in biomedicine. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2259-2274. doi: 10.11862/CJIC.20240128
6. [6]
  Ning LI , Siyu DU , Xueyi WANG , Hui YANG , Tao ZHOU , Zhimin GUAN , Peng FEI , Hongfang MA , Shang JIANG . Preparation and efficient catalysis for olefins epoxidation of a polyoxovanadate-based hybrid. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 799-808. doi: 10.11862/CJIC.20230372
7. [7]
  Yueyue WEI , Xuehua SUN , Hongmei CHAI , Wanqiao BAI , Yixia REN , Loujun GAO , Gangqiang ZHANG , Jun ZHANG . Two Ln-Co (Ln=Eu, Sm) metal-organic frameworks: Structures, magnetism, and fluorescent sensing sulfasalazine and glutaraldehyde. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2475-2485. doi: 10.11862/CJIC.20240193
8. [8]
  Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269
9. [9]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
10. [10]
  Tengjiao Wang , Tian Cheng , Rongjun Liu , Zeyi Wang , Yuxuan Qiao , An Wang , Peng Li . Conductive Hydrogel-based Flexible Electronic System: Innovative Experimental Design in Flexible Electronics. University Chemistry, 2024, 39(4): 286-295. doi: 10.3866/PKU.DXHX202309094
11. [11]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
12. [12]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
13. [13]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
14. [14]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
15. [15]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
16. [16]
  Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013
17. [17]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
18. [18]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
19. [19]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
20. [20]
  Wenjie SHI , Fan LU , Mengwei CHEN , Jin WANG , Yingfeng HAN . Synthesis and host-guest properties of imidazolium-functionalized zirconium metal-organic cage. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 105-113. doi: 10.11862/CJIC.20240360

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(308)
HTML views(46)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142