Citation: YANG Yu-Ting, TU Chang-Zheng, MIAO Jiao-Jiao, LI Jun-Li, CHEN Guang. Two Different Co(Ⅱ) Interpenetrating Networks Based on a Flexible Dicarboxylic Acid and Different Bis(imidazole) Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2015, (11): 2111-2118. doi: 10.11862/CJIC.2015.291 shu

Two Different Co(Ⅱ) Interpenetrating Networks Based on a Flexible Dicarboxylic Acid and Different Bis(imidazole) Ligands

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College of Chemistry and Chemical Engineering, Qujing Normal University, Qujing, Yunnan 655011, China

Corresponding author: YANG Yu-Ting,
Received Date: 4 August 2015
Available Online: 22 September 2015
Fund Project: 云南省科技厅应用基础研究项目(No.201401CB00299)资助。 (No.201401CB00299)

Two interpenetrating networks, namely {[Co(bimb)(L)]·H₂O}_n(1) and {[Co(bbix)(L)]₂}_n(2) (H₂L=4,4'-(2,2'-oxybis(ethane-2,1-diyl)bis(oxy))dibenzoic acid, bimb=1,1'-(1,4-butanediyl)bis(imidazole), bbix=1,4-bis(benzimidazole-1-ylmethyl)-benzene) have been prepared under hydrothermal condition by varying the bis(imidazole) coligands. Single crystal X-ray diffraction indicates that complex 1 displays 2D→3D 3-fold interpenetrating framework with 4-connected sql topology; 2 shows a 3D 4-connected framework of 6⁶ dia topology with 6-fold interpenetration. The results indicate that the shapes of bis(imidazole) coligands have an important effect on the interpenetrating characters and ultimate frameworks. Moreover, the thermal and magnetic properties of the two complexes have also been studied.
- interpenetration;flexible;bis(imidazole);topology;magnetic properties
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沈阳化工大学材料科学与工程学院沈阳 110142